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Advances in theoretically interesting molecules. Volume 2 : a research annual

Author: Randolph P Thummel; William C Herndon
Publisher: Greenwich, Connecticut ; London : JAI Press, Inc., 1992. ©1992
Series: Advances in theoretically interesting molecules, vols 1-2
Edition/Format:   eBook : Document : EnglishView all editions and formats
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Advances in Theoretically Interesting Molecules.
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Genre/Form: Electronic books
Additional Physical Format: Print version:
Advances in theoretically interesting molecules. Volume 2.
Greenwich, Connecticut ; London : JAI Press, Inc., ©1992
xii, 223 pages
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Randolph P Thummel; William C Herndon
ISBN: 9781483285009 1483285006
OCLC Number: 896845982
Description: 1 online resource (241 pages) : illustrations.
Contents: 6. isolation of shelf-stable bond shift isomers7. synthesis of alkyl/aryl substituted cyclooctatetraenes; 8. resolution of chiral cyclooctatetraenes and absolute configurational assignments; 9. racemization and its relationship to isodynamical behavior; 10. independent measurement of bond shifting rates; 11. ring inversion energetics; 12. untoward consequences of high peripheral steric congestion; 13. synthesis of annulated cyclooctatetraenes; 14. electroanalytical and chemical reducibility of select cyclooctatetraenophanes. 15. BOND SHIFTING AND RING INVERSION ENERGETICS EXHIBITED BYCYCLOOCTATETRAENOPHANES16. THE HEPTALENE ANALOGY; 17. DYNAMIC BEHAVIOR IN OCTALENES; 18. NONPLANAR AND CONFORMATIONALLY MOBILE CYCLOOCTATETRAENYL DIANIONS; 19. PHANES POSSESSING TWO CYCLOOCTATETRAENE DECKS; 20. CONCLUDING REMARKS; ACKNOWLEDGMENTS; REFERENCES AND FOOTNOTES; CHAPTER 2. A COMPILATION AND ANALYSIS OF STRUCTURAL DATA OF DISTORTED BRIDGEHEAD OLEFINS AND AMIDES; 1. INTRODUCTION; 2. ANALYSIS OF DISTORTIONS FROM X-RAY CRYSTAL STRUCTURES OF [n.3.1]BRIDGEHEAD OLEFINS; 3. COMPARISON OF MM2 CALCULATED GEOMETRIES WITH X-RAY DATA. CHAPTER 4. THE DEWAR FURAN STORY: A NEW CHAPTER IN THE DEVELOPMENT OF SYNTHETIC PROTOCOLS FOR UNSATURATED CYCLIC COMPOUNDS INVOLVING ACETYLENE STACKING AND TRANSFER TECHNOLOGYPREAMBLE; 1. THE DEWAR FAMILY OF VALENCE-ISOMERS; 2. SYNTHETIC APPROACHES TO DEWAR FURANS; 3. THE 1,2-PHOTOAROMATIZATION ROUTE; 4. REACTIONS OF DEWAR FURANS; 5. APPENDICES; REFERENCES AND FOOTNOTES; AUTHOR INDEX; SUBJECT INDEX; Advances in Theoretically Interesting Molecules; Advances in Electron Transfer Chemistry; Advances in Molecular Vibrations and Collision Dynamics; Advances in Classical Trajectory Methods.
Series Title: Advances in theoretically interesting molecules, vols 1-2
Responsibility: editor, Randolph P. Thummel ; contributors, William C. Herndon [and five others].

Abstract:

Advances in Theoretically Interesting Molecules.

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