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Atomic and molecular spectroscopy : basic concepts and applications

Author: Rita Kakkar
Publisher: New York : Cambridge University Press, 2015.
Edition/Format:   Print book : EnglishView all editions and formats
Summary:
"Elucidates various spectroscopic techniques including atomic spectroscopy, pure rotational spectroscopy, vibrational spectroscopy of diatomic and polyatomic molecules, Raman spectroscopy and electronic spectroscopy"--
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Document Type: Book
All Authors / Contributors: Rita Kakkar
ISBN: 9781107063884 1107063884
OCLC Number: 880960139
Description: xx, 415 pages : illustrations ; 25 cm
Contents: Fundamentals of Spectroscopy: Introduction; Some properties of waves; Electromagnetic radiation; Electromagnetic spectrum; Blackbody radiation; Boltzmann's population distribution; Einstein's coefficients; Line broadening; Lambert-Beer's law; Fourier transform spectroscopy --
Theoretical principles: Introduction; The postulates of quantum mechanics explained; Time-dependent perturbation; Einstein's coefficient of induced absorption; Einstein's coefficients of induced and spontaneous emission; The basis of selection rules; Overview of selection rules --
Atomic spectroscopy: Introduction; The Bohr theory of the hydrogen atom; Hydrogen and hydrogen-like Ion spectra; Multi-electron atoms; Photoelectron spectroscopy --
Pure rotational spectroscopy: Overview of molecular spectra; The rigid Diatomic Molecule (The rigid rotor); Rotation of polyatomic molecules-Classification of molecules; The effect of electric fields-The stark effect --
Vibrational spectroscopy of Diatomics: Introduction; Oscillations of systems with one degree of freedom; The Diatomic molecule; Quantum mechanical treatment; The potential energy function for a chemical bond --
Vibrational spectroscopy of polyatomic molecules: Introduction; Normal modes of vibration of carbon dioxide --
The Raman effect: Introduction; Classical treatment of the Raman effect; Quantum theory; Rule of mutual exclusion; Polarization of Raman lines; Fermi resonance; Influence of nuclear spin; Structure determination using combined infrared and Raman data; Group frequencies; Comparison of IR and Raman spectroscopies; Advanced Raman techniques --
Electronic spectroscopy of Diatomic molecules: Introduction; The Born-Oppenheimer approximation; Vibrational coarse structure; Franck-Condon principle; Dissociation energy; Electronic structure of Diatomic molecules; Electronic angular momentum in diatomic molecules; Selection rules; Rotational fine structure of electronic-vibrational transitions; Photoelectron spectroscopy (PES) --
Electronic spectroscopy of Polyatomic molecules: Introduction; Intensities of electronic transitions; Types of electronic transitions; Theories of Pi-Pi transitions; Free electron model of Linear Polyenes; Change of molecular shape on absorption; Vibronic coupling; Re-emission of energy by an excited molecule; Kinetics of photochemistry.
Responsibility: Rita Kakkar.

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The book offers detailed coverage of the basic concepts and applications of spectroscopy.  Read more...

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