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Boron Hydride Chemistry.

Author: Earl Muetterties
Publisher: Oxford : Elsevier Science, 1975.
Edition/Format:   eBook : Document : EnglishView all editions and formats
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Genre/Form: Electronic books
Additional Physical Format: Print version:
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Earl Muetterties
ISBN: 9780323146494 032314649X
OCLC Number: 841914141
Notes: Boron Hydride Chemistry.
Description: 1 online resource (545 pages)
Contents: Front Cover; Boron Hydride Chemistry; Copyright Page; Table of Contents; List of Contributors; Preface; Chapter 1. Introduction; I. Reflections; II. The Three-Center Bonding Concept; III. The Generalized Three-Center Concept; IV. Precis of Structural Data for Clusters, Boron Hydrides and Coordination Compounds; V. Dynamic Stereochemistry; References; Chapter 2. Advances in Theoretical Studies of Boron Hydrides and Carboranes; I. Introduction; II. Self-Consistent Field (SCF) Theory; III. SCF Results and Localization in Borane and Carboranes. IV. Localized Orbitals and Three-Center Bond TheoriesV. Appendix I; VI. Appendix II; References; Chapter 3. Nido- and Arachno-Boron Hydrides; I. Introduction; II. Historical Background; III. Structures and Structural Relationships; IV. Application of nmr Spectroscopy to Structural Problems; V. Chemical Relationships; Acknowledgment; References; Chapter 4. Gas Phase Reactions of Borane; I. Introduction; II. Chemical Reactivity and Active Intermediates; III. Some Elementary Reactions of Borane; IV. Reinterpretation of Some Selected Complex Systems. V. The Role of Borane in Some Ligand Displacement Reactions of the Type L' + LBH3₂!L'BH3 + LAcknowledgment; References; Chapter 5. Solution Reactions of Borane and Substituted Boranes; I. Introduction; II. Preparation and Reactions of Borane; III. Alkylboranes; IV. Hydroboration of Alkadienes and Alkynes; V. Reactions of Boranes with Other Functional Groups; VI. Heterosubstituted Boranes; References; Chapter 6. Boron Cations; I. Introduction; II. Singly Charged Cations; III. Doubly and Triply Charged Cations; References; Chapter 7. Borazines; I. Introduction. II. Structures, Bonding, and Spectroscopic Properties of BorazinesIII. Syntheses of Borazines; IV. Chemistry of the Borazines; References; Chapter 8. Closo-Boron Hydrides; I. Introduction; II. Bonding and Electronic Structure; III. Syntheses; IV. Some Primary Reactions and Properties; V. Substitution Reactions; References; Chapter 9. Icosahedral Carboranes; I. Introduction; II. Structure and Bonding; III. Synthesis; IV. Metalation Reactions of the Icosahedral Carboranes; V. Halogenation of the C2B10H12 Carboranes; VI. Organic Chemistry of the C2B10H12 Carboranes. VII. Inorganic Chemistry of the C2B10H12 CarboranesVIII. Carborane-Based Polymers; IX. Icosahedral Cage Degradation; Acknowledgment; References; Chapter 10. Carboranes; I. Introduction; II. Structure and Bonding; III. Spectroscopic Properties; IV. General Methods of Preparation; V. Chemical Properties; References; Chapter 11. Close-Heteroboranes Exclusive of Carboranes; I. Introduction; II. Icosahedral Systems; III. Nonicosahedral Complexes; IV. Polyhedral Expansion Reactions; References; Chapter 12. Nido-Heteroboranes; I. Introduction; II. Covalent Compounds of BH4- and BH3.

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