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Calixarenes and beyond

Author: Placido Neri; Jonathan L Sessler; Mei-Xiang Wang
Publisher: Switzerland : Springer, 2016.
Edition/Format:   eBook : Document : EnglishView all editions and formats
Summary:
Contributions featuring the chemistry and applications of a family of macrocyclic compounds collectively known as 'calixarenes' are presented in this edited volume. The arsenal of structures based on calixarenes provides tools which are effective in numerous areas of supramolecular chemistry. The Editors have compiled a timely volume which contains up to date, high calibre contributions from a large number of  Read more...
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Genre/Form: Electronic books
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Placido Neri; Jonathan L Sessler; Mei-Xiang Wang
ISBN: 9783319318677 3319318675 3319318659 9783319318653
OCLC Number: 956730939
Description: 1 online resource (xi, 1062 pages) : illustrations (some color)
Contents: Foreword; Preface; Contents; Chapter 1: Introduction and History; References; Chapter 2: Chiral Calixarenes and Resorcinarenes; 2.1 Introduction; 2.2 Chiral Substituents; 2.2.1 Amino Acid Derivatives and Peptides; 2.2.1.1 Cavitands and Semi-Open Structures; 2.2.1.2 Capsules; 2.2.2 Carbohydrates; 2.2.3 Amines and Derivatives; 2.2.4 Groups with Axial Chirality; 2.2.5 Modifications of the Bridges; 2.3 Inherent Chirality; 2.4 Non-covalent Chirality and Supramolecular Chirality; 2.5 Conclusions and Outlook; References; Chapter 3: Meta Substitution of Calixarenes; 3.1 Foreword 3.2 Basic Strategies for Meta-substituted Calixarenes3.3 Fragment Condensation Method; 3.4 Introduction of Ortho-orienting Group into the Para Position; 3.5 Bromodienone Route; 3.6 Intramolecular Ring-Closure of Para Substituent; 3.7 Direct Meta-substitution; 3.8 Conclusions and Outlook; References; Chapter 4: Preparation of Methylene-Substituted Calixarenes; 4.1 Introduction; 4.2 Configurational Stereoisomerism; 4.3 Cyclization of Fragments; 4.4 Ring Contraction; 4.5 Direct Modification of the Methylene Groups of a Calix[n]arene Derivative. Modification of One or Two Bridges 4.6 Preparation of Ketocalixarenes4.7 Reaction of Ketocalixarenes with Nucleophiles; 4.8 Preparation of Bromocalixarenes; 4.9 Reaction of Bromocalixarenes with Nucleophiles; 4.10 Calixarenes with Two Types of Modified Bridges; References; Chapter 5: Calix[5]arene: from Capsules to Polymers; 5.1 Introduction; 5.2 The Calix[5]arene Scaffold; 5.2.1 The Calix[5]arene/Fullerene ``AA/BB-type ́́Motif; 5.2.2 The Calix[5]arene/Alkanedyldiammonium Ion ``AA/BB-type ́́Motif; 5.2.3 The Calix[5]arene/Alkylammonium Ion ``AB-type ́́Motif; 5.2.4 The p-Sulfonatocalix[5]arene/Organic Cation Motif 5.3 Conclusions and OutlookReferences; Chapter 6: Calix[6]azacryptand-Based Receptors; 6.1 Introduction; 6.2 Synthesis of the Calix[6]azacryptands; 6.3 Calix[6]azacryptands as Selective Anion Receptors; 6.4 Calix[6]azacryptands as Ammonium Ion and Ion-Pair/Triad Receptors; 6.5 Calix[6]azacryptands as Neutral Guest Receptors; 6.6 Calix[6]azacryptands as Funnel Complexes; 6.7 Versatile and Acid/Base Controllable Receptors; 6.8 Conclusion; References; Chapter 7: Large Calixarenes; 7.1 Introduction; 7.2 Synthesis of Calix[7-20]arene Macrocycles 7.3 Functionalization of Calix[7-20]arene Macrocycles7.3.1 Lower Rim Functionalization of Large Calixarenes; 7.3.2 Shaping Large Calixarenes by Intramolecular Bridging; 7.3.3 Exo Rim Functionalization of Large Calixarenes; 7.3.4 Methylene Bridge Functionalization of Large Calixarenes; 7.4 Supramolecular Features of Large Calixarenes; 7.4.1 Biomolecular Applications of Large Calixarenes; 7.4.2 Coordination and Solid State Supramolecular Architectures Based on Large Calixarenes; 7.5 Conclusions; References
Responsibility: Placido Neri, Jonathan L. Sessler, Mei-Xiang Wang, editors.

Abstract:

Contributions featuring the chemistry and applications of a family of macrocyclic compounds collectively known as 'calixarenes' are presented in this edited volume. The arsenal of structures based on  Read more...

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"Book is most appropriate for synthetic chemists ... as the examples and analyses provided incorporate concepts from various fields. Examples for topics like NMR, coordination chemistry, and unit Read more...

 
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