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Chemical thermodynamics of compounds and complexes of U, Np, Pu, Am, Tc, Se, Ni, and Zr, with selected organic ligands

Author: Wolfgang Hummel; Federico J Mompean; Myriam Illemassène; Jane Perrone
Publisher: Amsterdam ; Boston : Elsevier, 2005.
Series: Chemical thermodynamics (Amsterdam, Netherlands), v. 9.
Edition/Format:   eBook : Document : EnglishView all editions and formats
Summary:
Contains a review of the literature on thermodynamic data for compounds of complexes of oxalate, citrate, EDTA and iso-saccharinate with uranium, neptunium, plutonium, americium, technetium, selenium, nickel and zirconium. This volume is part of the series on "Chemical Thermodynamics", published under the aegis of the OECD Nuclear Energy Agency.
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Genre/Form: Electronic books
Additional Physical Format: Print version:
Chemical thermodynamics of compounds and complexes of U, Np, Pu, Am, Tc, Se, Ni, and Zr, with selected organic ligands.
Amsterdam ; Boston : Elsevier, 2005
(DLC) 2005052149
(OCoLC)61425085
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Wolfgang Hummel; Federico J Mompean; Myriam Illemassène; Jane Perrone
ISBN: 0080457525 9780080457529
OCLC Number: 75196328
Description: 1 online resource (xliii, 1088 pages) : illustrations.
Contents: Cover --
Contents --
Preface --
Acknowledgement --
Note from the chairman of the NEA TDB Project Phase II --
Editor's note --
Introductory material --
Introduction --
Background --
Focus of the review --
Review procedure and results --
Standards, conventions, and contents of the tables --
Symbols, terminology and nomenclature --
Units and conversion factors --
Standard and reference conditions --
Fundamental physical constants --
Uncertainty estimates --
The NEA-TDB system --
Presentation of the selected data --
Tables of selected data --
Selected data for organic compounds and complexes --
Selected auxiliary data --
Discussion of data selection --
Criteria for data evaluation and particular problems encountered in the review procedure --
Criteria for data evaluation --
Particular problems of commonly used experimental methods --
Ionic medium effects on protonation constants for organic ligands --
Weak complexes versus strong specific ion interaction --
Discussion of data selection for oxalate compounds and complexes. --
Introduction --
Oxalic acid --
Protonation constants of oxalate --
Alkali metal oxalate compounds and complexes --
Magnesium and calcium oxalate compounds and complexes --
Selenium oxalate compounds and complexes --
Nickel oxalate compounds and complexes --
Technetium oxalate compounds and complexes --
Zirconium oxalate compounds and complexes --
Uranium oxalate compounds and complexes --
Neptunium oxalate compounds and complexes --
Plutonium oxalate compounds and complexes --
Americium oxalate compounds and complexes --
Discussion of data selection for citrate compounds and complexes . --
Introduction --
Metal ion citrates --
Citric acid --
H3citH2O(cr) --
H3cit(cr) --
H3cit(aq) --
Protonation constants for citrate --
Introduction --
Analysis of K3 --
Analysis of K2 --
Analysis of K1 --
Analysis of Ko --
Selected protonation constants for citrate --
Temperature effects --
Alkali metal citrate compounds and complexes --
Complexes with Na+ and K+ --
Magnesium and calcium citrate compounds and complexes --
Magnesium and calcium citrate complexes --
Magnesium and calcium citrate compounds --
Selenium citrate compounds and complexes --
Nickel citrate compounds and complexes --
Technetium citrate compounds and complexes --
Zirconium citrate compounds and complexes --
Uranium citrate compounds and complexes --
U(IV) citrate complexes --
U(VI) citrate complexes --
Neptunium citrate compounds and complexes --
Plutonium citrate compounds and complexes --
Americium citrate compounds and complexes --
Discussion of data selection for ethylenediaminetetraacetate (edta) compounds and complexes --
Introduction --
H4edta(cr) --
Thermodynamic properties --
Solubility of H4edta(cr) --
Acid-base equilibria of edta in aqueous solutions --
Introduction --
Analysis of K5 and K6 --
Analysis of K4 --
Analysis of K3 --
Analysis of K2 --
Analysis of K1 --
Selected protonation constants for edta4" --tidti.
Series Title: Chemical thermodynamics (Amsterdam, Netherlands), v. 9.
Responsibility: Wolfgang Hummel (chairman) [and others] ; edited by Federico J. Mompean, Myriam Illemassène, and Jane Perrone.

Abstract:

Contains a review of the literature on thermodynamic data for compounds of complexes of oxalate, citrate, EDTA and iso-saccharinate with uranium, neptunium, plutonium, americium, technetium, selenium, nickel and zirconium. This volume is part of the series on "Chemical Thermodynamics", published under the aegis of the OECD Nuclear Energy Agency.

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