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The chemistry of free radical polymerization

Author: Graeme Moad; D H Solomon
Publisher: Oxford, OX, U.K. ; Tarrytown, N.Y.U.S.A. : Pergamon, 1995.
Edition/Format:   Print book : English : 1st edView all editions and formats
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The overall aim of this work is to provide a framework for greater understanding of free radical polymerization. Each chapter describes some of the techniques that have been employed to characterize  Read more...

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Additional Physical Format: Online version:
Moad, Graeme.
Chemistry of free radical polymerization.
Oxford, OX, U.K. ; Tarrytown, N.Y.U.S.A. : Pergamon, 1995
(OCoLC)645775837
Document Type: Book
All Authors / Contributors: Graeme Moad; D H Solomon
ISBN: 0080420788 9780080420783 0080420796 9780080420790
OCLC Number: 30593575
Description: xvi, 408 pages : illustrations ; 24 cm
Contents: Part 1 Free radical reactions: introduction; addition to carbon-carbon double bonds; steric factors; polar factors; bond strengths; theoretical treatments; hydrogen atom transfer; polar factors; stereoelectronic factors; reaction conditions; abstraction vs. addition; summary radical-radical reactions; pathways for combination; pathways for disproportionation; combination vs. disproportionation; summary. Part 2 Initiation: introduction; the initiation process; reaction with monomer; fragmentation; reaction with solvents, additives or impurities; effects of the reaction medium on radical reactivity; reaction with oxygen; initiator efficiency; cage reaction and initiator-derived by-products; primary radical termination; transfer to initiator; initiation in heterogeneous polymerization; thermal initiation; the radicals; carbon-centred radicals; oxygen-centred radicals. Part 3 Propagation: introduction; stereosequence isomerism - tacticity; monoene polymers; conjugated diene polymers; structural isomerism - rearrangement; cyclopolymerization; ring-opening polymerization; intramolecular atom transfer; propagation kinetics and thermodynamics. Part 4 Termination; introduction; radical-radical termination; termination kinetics; disproportionation vs. combination - general considerations; disproportionation vs. combination - summary; chain transfer; mechanisms; transfer agents; transfer to monomer; transfer to polymer; inhibition and retardation; "stable" radicals; oxygen. Part 5 Copolymerization: introduction; statistical copolymerization; copolymerization mechanisms; block and graft copolymerization; end-functional polymers; block and graft copolymer synthesis. Part 6 Controlling polymerization: introduction; "defect structures" in polystyrene; "defect structures" in poly(methyl methacrylate); controlling propagation; solvent; Lewis acids and inorganics; template polymers; compositional heterogeneity in copolymers; agents for controlling termination; organosulfur iniferters; hexasubstituted ethanes and azo compounds; alkoxyamines and related species.
Responsibility: Graeme Moad and David H. Solomon.

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