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The Chemistry of Inorganic Ring Systems.

Author: R Steudel
Publisher: Burlington : Elsevier Science, 1992.
Series: Studies in inorganic chemistry.
Edition/Format:   eBook : Document : EnglishView all editions and formats
Summary:
The present volume considers the most recent developments in the chemistry of cyclic inorganic and organoelement compounds. Nineteen of the 22 chapters are based on invited and other lectures presented at the 6th International Symposium on Inorganic Ring Systems held in Berlin on August 18-22, 1991. Main group compounds dominate the content from boron via carbon, silicon, germanium, tin, nitrogen, phosphorus and  Read more...
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Genre/Form: Electronic books
Conference papers and proceedings
Congresses
Additional Physical Format: Print version:
Steudel, R.
Chemistry of Inorganic Ring Systems.
Burlington : Elsevier Science, ©1992
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: R Steudel
ISBN: 9781483291154 1483291154
OCLC Number: 895435243
Notes: 2. Ring Opening Polymerization of Chlorocyclophosphazenes: The Classical Route to Poly(organophosphazenes).
Description: 1 online resource (509 pages).
Contents: FrontCover; The Chemistry of Inorganic Ring Systems; Copyright Page; Preface; List of Contributors; Table of Contents; Chapter 1. CLUSTERS, CAGES AND CONCATENATIONS; 1. Introduction; 2. Mechanisms of Borane Cluster Formation; 3. Synthesis of New Cluster Types; 4. Fluxional Cluster Isomerism; 5. Acknowledgements; 6. References; Chapter 2. NOVEL DELOCALIZED RINGS INVOLVING HEAVIER MAIN GROUP ELEMENTS; 1. Introduction; 2. Synthesis of Novel Potentially Delocalized Rings; 3. Structures and Properties; 4. Rings Comprised of Heavier Main Group Elements Only; 5. Conclusion; 6. Acknowledgement. 7. ReferencesChapter 3. BINARY CARBON SULFIDES: UNUSUAL MOLECULES AND MATERIALS; 1. Introduction; 2. Background; 3. Anionic Carbon Sulfides; 4. Molecular, Binary Carbon Sulfides; 5. Reactivity of Carbon Sulfides; 6. Summary and Outlook; 7. Acknowledgment; 8. References; Chapter 4. NOVEL SILICON RING COMPOUNDS FROM DISILENES; 1. Reactions with Chalcogens; 2. Reaction with Dioxygen; 3. Reaction with Nitro- and Nitrosobenzene; 4. Reactions with Azides and Azobenzene; 5. Reactions with Phosphorus; 6. Reaction with Bis(Phosphine)Platinum; 7. Summary; 8. Acknowledgements; 9. References. Chapter 5. NOVEL RING SYSTEMS FROM CYCLOTRISILANES AND CYCLOTRISTANNANES1. Introduction; 2. Synthesis and Reactivity of Cyclotrisilanes; 3. Synthesis and Reactivity of Cyclotrigermanes; 4. Synthesis and Reactivity of Cyclotristannanes; 5. References; Chapter 6. HOMO- AND HETEROCYCLIC Si-O-SYSTEMS -RINGS AND CAGES; 1. Bifunctional Silanols --
Initial Chemical Reagents of Siloxane Synthesis; 2. Alkali Metal Derivatives of Monomeric Silanols; 3. Ring Precursors and Ring Systems; 4. Summary; 5. References; Chapter 7. EXOTIC POLYHEDRAL OLIGOGERMANES AND RELATED MOLECULES. 1. Hexakis(trimethylsilyl) prismane: C6 (SIMe3)6. Synthesis of Hexakis (trimethylsilyl) tetracyclo [2.2.0.02'6.0 '5] hexane2. Hexagermaprismane: Ge6[CH (SIMe3)2]6. Synthesis of Tetracyclo [2.2.0.02'6.03'5] hexagermane; 3. Octagermacubane: Ge8[(CMeEt2)]8. Synthesis of Pentacyclo [4.2.0.02'50.'03'8'07'7] octagermane; 4. Tetrahalogenocyclotetragermane:A Potential Precursor of Cage and Ladder Systems; 5. Cage and Ladder Polygermanes:Synthesis of Tetracyclo[3.3.0.02'7.03'6] octagermane andTricyclo[4.2.0.02'5]octagermane; 6. One Pot Synthesis of Oligogermanes; 7. Acknowledegment; 8. References. Chapter 8. NEW HETEROMETALLIC SILYLAMIDES WITH POLYCYCLIC AND CAGE-LIKE STRUCTURES1. Introduction; 2. Syntheses of Heterometallic Octamethyltrisilazyls; 3. Molecular Structures of Heterometallic Octamethyltrisilazyls in the Solid; 4. General Discussion of the Structural Details in Heterometallic Octamethyltrisilazyls; 5. Acknowledgements; 6. References; Chapter 9. STRAINED INORGANIC HETEROCYCLIC COMPOUNDS AND THEIR CONVERSION TO MACROCYCLES AND HIGH POLYMERS; 1. The Importance of Ring-Opening Polymerization and Ring Expansion Reactions.
Series Title: Studies in inorganic chemistry.

Abstract:

The present volume considers the most recent developments in the chemistry of cyclic inorganic and organoelement compounds. Nineteen of the 22 chapters are based on invited and other lectures presented at the 6th International Symposium on Inorganic Ring Systems held in Berlin on August 18-22, 1991. Main group compounds dominate the content from boron via carbon, silicon, germanium, tin, nitrogen, phosphorus and arsenic, to sulfur and selenium. The book is organized by element, moving from left to right in the main groups of the Periodic Table, followed by one chapter each on bonding and nomen.

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