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Comparison of Self-Assembled Monolayers on Gold: Coadsorption of Thiols and Disulfides.

Author: Colin D Bain; Hans A Biebuyck; George M Whitesides; HARVARD UNIV CAMBRIDGE MASS DEPT OF CHEMISTRY.
Publisher: Ft. Belvoir Defense Technical Information Center 15 FEB 1989.
Edition/Format:   Book : English
Database:WorldCat
Summary:
Ordered, organic monolayers were formed on gold slides by adsorption from ethanol of HS(CH2)10CH2OH, HS(CH2)10CH3, S(CH2)10CH2OH2, S(CH2)10Ch32, and of binary mixtures of these molecules in which one component was terminated by a hydrophobic methyl group and one by a hydrophilic alcohol group. The compositions of the monolayers were determined by X-ray photoelectron spectroscopy (XPS). Wettability was used as a  Read more...
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Document Type: Book
All Authors / Contributors: Colin D Bain; Hans A Biebuyck; George M Whitesides; HARVARD UNIV CAMBRIDGE MASS DEPT OF CHEMISTRY.
OCLC Number: 227731864
Description: 28 p.

Abstract:

Ordered, organic monolayers were formed on gold slides by adsorption from ethanol of HS(CH2)10CH2OH, HS(CH2)10CH3, S(CH2)10CH2OH2, S(CH2)10Ch32, and of binary mixtures of these molecules in which one component was terminated by a hydrophobic methyl group and one by a hydrophilic alcohol group. The compositions of the monolayers were determined by X-ray photoelectron spectroscopy (XPS). Wettability was used as a probe of the chemical composition and structure of the surface of the monolayer. When monolayers were formed in solutions containing mixtures of a thiol and a disulfide, adsorption of the thiol was strongly preferred (approx. 75:1). Monolayer, Gold, Surface, Contact angles, Thiols, Disulfides. (mjm).

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