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Conjugative Effects in Organic Chemistry

Author: Rolf Gleiter; G Haberhauer
Publisher: Weinheim, Bergstr Wiley-VCH 2011
Edition/Format:   Print book : English : 1., AuflageView all editions and formats

The authors provide an excellent overview of conjugation effects in organic chemistry within and between Pi systems. Besides various aspects of aromaticity one finds detailed discussions of homo-,  Read more...


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Genre/Form: Lehrbuch
Material Type: Internet resource
Document Type: Book, Internet Resource
All Authors / Contributors: Rolf Gleiter; G Haberhauer
ISBN: 9783527329465 3527329463 9783527329342 352732934X
OCLC Number: 725142225
Description: 350 S.
Contents: CONJUGATED pi-SYSTEMS Linear Conjugated Polyenes Conjugated Oligoalkynes Conjugated Planar Monocyclic Systems Aromaticity Criteria Structures of Monocyclic (4n)pi and (4n+2)pi Annulenes Conjugated Polycyclic Planar pi Electron Systems Substituent Effects Conjugation in Two and Three Dimensions THROUGH-SPACE INTERACTION BETWEEN pi SYSTEMS Homoconjugation Transannular Effects Homoaromatic Systems Spiroconjugation DONOR-ACCEPTOR INTERACTIONS BETWEEN PLANAR ARENES Donor-Acceptor Complexes Structures of Benzene and Related Aromatics in the Solid State Interactions Between Molecules of Opposite Electric Quadrupole Moments Model Studies to Measure the Strength of Non-Covalent Interactions Between pi Systems in Organic Solvents Model Calculations on pi-pi Interactions Applications and Consequences of pi-pi Interactions of Arenes in Chemistry THROUGH-BOND INTERACTION BETWEEN pi SYSTEMS AND NON-BONDING ELECTRON PAIRS OF HETEROATOMS Theoretical Models Dehydroaromatics Through-Bond Interaction Between Non-Conjugated pi Systems Rationalization of Intramolecular Reactivity by Through-Bond Coupling HYPERCONJUGATIVE INTERACTIONS Concept of the Two-Electron/Two-Orbital Interactions Definition and Manifestation on Ground State Properties Positive Hyperconjugation (sigma-p, sigma-pi* and sigma-sigma* Interactions) Negative Hyperconjugation (n-sigma* and pi-sigma* Interactions) THEORETICAL METHODS Quantum Chemical Calculation Methods - An Overview Orbital Interactions Spectroscopic Methods for Detecting Conjugation Effects APPENDIX Character Tables for Selected Symmetry Groups Basic Equations for Nuclear Magnetic Shielding in Molecules Energy Conversion Table and Abbreviations
Responsibility: Rolf Gleiter ; G. Haberhauer
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