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Conjugative Effects in Organic Chemistry

Author: Rolf Gleiter; G Haberhauer
Publisher: Weinheim, Bergstr Wiley-VCH 2011
Edition/Format:   Print book : English : 1., AuflageView all editions and formats
Database:WorldCat
Summary:

The authors provide an excellent overview of conjugation effects in organic chemistry within and between Pi systems. Besides various aspects of aromaticity one finds detailed discussions of homo-,  Read more...

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Genre/Form: Lehrbuch
Material Type: Internet resource
Document Type: Book, Internet Resource
All Authors / Contributors: Rolf Gleiter; G Haberhauer
ISBN: 9783527329465 3527329463 9783527329342 352732934X
OCLC Number: 725142225
Description: 350 S.
Contents: CONJUGATED pi-SYSTEMS Linear Conjugated Polyenes Conjugated Oligoalkynes Conjugated Planar Monocyclic Systems Aromaticity Criteria Structures of Monocyclic (4n)pi and (4n+2)pi Annulenes Conjugated Polycyclic Planar pi Electron Systems Substituent Effects Conjugation in Two and Three Dimensions THROUGH-SPACE INTERACTION BETWEEN pi SYSTEMS Homoconjugation Transannular Effects Homoaromatic Systems Spiroconjugation DONOR-ACCEPTOR INTERACTIONS BETWEEN PLANAR ARENES Donor-Acceptor Complexes Structures of Benzene and Related Aromatics in the Solid State Interactions Between Molecules of Opposite Electric Quadrupole Moments Model Studies to Measure the Strength of Non-Covalent Interactions Between pi Systems in Organic Solvents Model Calculations on pi-pi Interactions Applications and Consequences of pi-pi Interactions of Arenes in Chemistry THROUGH-BOND INTERACTION BETWEEN pi SYSTEMS AND NON-BONDING ELECTRON PAIRS OF HETEROATOMS Theoretical Models Dehydroaromatics Through-Bond Interaction Between Non-Conjugated pi Systems Rationalization of Intramolecular Reactivity by Through-Bond Coupling HYPERCONJUGATIVE INTERACTIONS Concept of the Two-Electron/Two-Orbital Interactions Definition and Manifestation on Ground State Properties Positive Hyperconjugation (sigma-p, sigma-pi* and sigma-sigma* Interactions) Negative Hyperconjugation (n-sigma* and pi-sigma* Interactions) THEORETICAL METHODS Quantum Chemical Calculation Methods - An Overview Orbital Interactions Spectroscopic Methods for Detecting Conjugation Effects APPENDIX Character Tables for Selected Symmetry Groups Basic Equations for Nuclear Magnetic Shielding in Molecules Energy Conversion Table and Abbreviations
Responsibility: Rolf Gleiter ; G. Haberhauer
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