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Crystal-liquid-gas phase transitions and thermodynamic similarity

Author: V P Skripov; Mars Z Faizullin
Publisher: Weinheim ; [Chichester] : Wiley-VCH, 2006.
Edition/Format:   Print book : EnglishView all editions and formats
Summary:
"This monograph investigates the properties of crystal, liquid and gas phases of substances, and also metastable states. New relations for the thermodynamic similarity for liquid-vapour phase transitions are derived, and the authors describe solid-liquid, liquid-vapour and liquid-liquid phase transitions for binary systems employing the methodology of thermodynamic similarity."--BOOK JACKET.
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Additional Physical Format: Online version:
Skripov, V.P. (Vladimir Pavlovich).
Crystal-liquid-gas phase transitions and thermodynamic similarity.
Weinheim ; [Chichester] : Wiley-VCH, 2006
(OCoLC)607504505
Online version:
Skripov, V.P. (Vladimir Pavlovich).
Crystal-liquid-gas phase transitions and thermodynamic similarity.
Weinheim ; [Chichester] : Wiley-VCH, 2006
(OCoLC)631978092
Document Type: Book
All Authors / Contributors: V P Skripov; Mars Z Faizullin
ISBN: 3527405763 9783527405763
OCLC Number: 64097068
Description: ix, 174 pages : illustrations ; 25 cm
Contents: Foreword. 1 Introduction. 1.1 Basic Aims and Methods. 1.2 States of Aggregation. Phase Diagrams and the Clausius-Clapeyron Equation. 1.3 Metastable States. Relaxation via Nucleation. 1.4 Phase Transformations in a Metastable Phase. Homogeneous Nucleation. 2 Liquid-Gas Phase Transitions. 2.1 BasicFact: ExistenceofaCriticalPoint. 2.2 Method of Thermodynamic Similarity. 2.3 Similarity Near the Critical Point: The Change of Critical Indices. 2.4 New Universal Relationships for Liquid-Vapor Phase Coexistence in One-Component Systems. 2.4.1 Correlation Between Pressure and Densities of Liquid and Vapor Along the Saturation Curve. 2.4.2 Correlation Between Caloric Properties and Densities of Liquid and VaporAlongtheSaturationCurve. 2.4.3 Correlation Between Surface Tension and Heat of Evaporation of Nonassociated Liquids. 2.4.4 One-Parameter Correlation for the Heat of Evaporation of NonassociatedLiquids. 3 Crystal-Liquid Phase Transitions. 3.1 The Behavior of the Crystal-Liquid Equilibrium Curve at High Pressures. 3.2 Experimental Methods of Investigation of Melting of Substances at High Pressure. 3.3 Application of Similarity Methods for a Description of Melting. 3.4 The Extension of the Melting Curve into the Range of Negative Pressures and the Scaling of Thermodynamic Parameters. 3.5 Internal Pressure in a Liquid Along the Equilibrium Curves with Crystal and Vapor. 3.6 Stability of Thermodynamic States and the Metastable Continuation of the Melting Curves. 3.7 The Behavior of the Viscosity of a Liquid Along the Coexistence Curve with the Crystalline Phase. 3.8 The Behavior of Volume and Entropy Jumps Along the Melting Curve. 3.9 The Surface Tension of Simple Liquids Along the Melting Curve. 3.10 Correlations Between Thermodynamic Properties Characterizing Melting. 3.11 Melting and Crystallization of Small Particles. 3.11.1 Thermodynamic Aspects. 3.11.2 KineticAspects. 4 Phase Transitions in Solutions. 4.1 Generalized Clausius-Clapeyron Equation for Solutions. 4.2 Application of the Generalized Clausius-Clapeyron Equation for the Plot of thePhaseDiagrams. 4.3 Thermodynamic Correlations for Phase-Separating Solutions. 4.4 Experimental Studies of Phase-Separating Solutions. 4.5 Thermodynamic Similarity of Phase-Separating Binary Solutions with Upper Critical Dissolution Temperature. 4.6 Thermodynamic Similarity of Phase-Separating Binary Solutions with Lower Critical Dissolution Temperature. 4.7 Concluding Remarks. A Appendices. A.1 List of Symbols. A.2 SuperscriptsandSubscripts. References. Index.
Responsibility: Vladimir P. Skripov and Mars Z. Faizullin.
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Abstract:

Professor Skripov obtained worldwide recognition with his monograph "Metastable liquids", published in English by Wiley & Sons.  Read more...

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