skip to content
Diazo chemistry. 1, Aromatic and heteroaromatic compounds Preview this item
ClosePreview this item
Checking...

Diazo chemistry. 1, Aromatic and heteroaromatic compounds

Author: Heinrich Zollinger
Publisher: Weinheim ; Cambridge : VCH, ©1994.
Edition/Format:   Print book : EnglishView all editions and formats
Summary:

This text provides a homogenous presentation of aspects of diazo chemistry. It is practice-oriented due to a strong emphasis on applications and includes many tables, schemes and literature  Read more...

Rating:

(not yet rated) 0 with reviews - Be the first.

Subjects
More like this

Find a copy online

Links to this item

Find a copy in the library

&AllPage.SpinnerRetrieving; Finding libraries that hold this item...

Details

Material Type: Internet resource
Document Type: Book, Internet Resource
All Authors / Contributors: Heinrich Zollinger
ISBN: 1560818786 9781560818786 3527292136 9783527292134
OCLC Number: 60241197
Description: [1 volume]
Contents: Part 1 Introduction: history of aromatic and heteroaromatic diazo compounds; nomenclature; general references. Part 2 Methods for the preparation of aromatic and heteroaromatic diazo compounds: diazotization of amines with alkali nitrite in dilute aqueous mineral acids; diazotization in concentrated mineral acid; isolation of diazonium salts; diazotization of 2- and 4-aminophenols; formation of diazonium salts under anhydrous conditions; other reactions involving formation of aromatic diazonium ions. Part 3 Kinetics and mechanism of diazotization: historical development; influence of acidity on the rate and mechanism of diazotization in aqueous sulfuric and perchloric acids; nucleophilic catalysis of diazotization; transformation of the N-Nitrosoamine intermediate into the diazonium ion. Part 4 The structure of diazonium compounds: introductory remarks; structure of arenediazonium salts; theoretical investigations. Part 5 Acid-base and isomerization reactions of diazo compounds in water: the aromatic diazonium ion as a dibasic acid; the combined system of acid-base addition, (Z)/(E)- and prototropic isomerization reactions of arenediazonium ions; kinetics and equilibria of arenediazonium ions in water. Part 6 Additions of other nucleophiles to arenediazonium ions: O-Coupling; S-coupling; N-coupling; P-coupling; C-coupling; intramolecular coupling. Part 7 Structural and mechanistic aspects of additions of nucleophiles to diazonium ions: (Z)/(E)-isomerism; investigations on reactivities by the interpretation of substituent effects - the Hammett and related equations; the electronic influence of the diazonio group as a substituent; influence of substituents on the addition of nucleophiles to arenediazonium ions. Part 8 Dediazoniation of arenediazonium ions: introduction to dediazoniation in general; multiplicity of pathways and products; the D[N] + A[N] mechanism of dediazoniation; molecular orbital investigations on heterolytic dediazoniations and on aryl cations; dediazoniations via aryne intermediates; dediazoniation initiated by an electron transfer; solvent effects in competitive homolytic and heterolytic dediazoniation; dediazoniation in alkaline aqueous solutions; dediazoniation in highly nucleophilic solvents and in the presence of good nucleophiles; dediazoniation in alcohols. Part 9 Logic, psychology, and serendipity of scientific discoveries - an interlude. Part 10 Applications of heterolytic and homolytic dediazoniations in organic syntheses: hydro-de-diazoniation; hydroxy- and mercapto-de-diazoniations and related reactions; fluoro-de-diazoniation; chloro-, bromo-, and cyano-de-diazoniations - the Sandmeyer reaction; iodo-de-diazoniation and related reactions; azido-de-diazoniation; dediazoniation in the presence of carbonyl, sulfonyl, and related compounds; replacement of the diazonio group by alkenes and alkynes - the Meerwein reaction; arylation of aromatic compounds - the Gomberg-Bachmann and related reactions. (Part contents).
Responsibility: Heinrich Zollinger.

Reviews

User-contributed reviews
Retrieving GoodReads reviews...
Retrieving DOGObooks reviews...

Tags

Be the first.

Similar Items

Related Subjects:(1)

Confirm this request

You may have already requested this item. Please select Ok if you would like to proceed with this request anyway.

Linked Data


Primary Entity

<http://www.worldcat.org/oclc/60241197> # Diazo chemistry. 1, Aromatic and heteroaromatic compounds
    a schema:Book, schema:CreativeWork ;
   library:oclcnum "60241197" ;
   library:placeOfPublication <http://experiment.worldcat.org/entity/work/data/341467496#Place/weinheim> ; # Weinheim
   library:placeOfPublication <http://id.loc.gov/vocabulary/countries/enk> ;
   library:placeOfPublication <http://experiment.worldcat.org/entity/work/data/341467496#Place/cambridge> ; # Cambridge
   schema:about <http://id.worldcat.org/fast/815019> ; # Aromatic compounds
   schema:about <http://dewey.info/class/547.043/> ;
   schema:bookFormat bgn:PrintBook ;
   schema:copyrightYear "1994" ;
   schema:creator <http://viaf.org/viaf/92943094> ; # Heinrich Zollinger
   schema:datePublished "1994" ;
   schema:exampleOfWork <http://worldcat.org/entity/work/id/341467496> ;
   schema:inLanguage "en" ;
   schema:name "Diazo chemistry. 1, Aromatic and heteroaromatic compounds"@en ;
   schema:productID "60241197" ;
   schema:publication <http://www.worldcat.org/title/-/oclc/60241197#PublicationEvent/weinheim_cambridge_vch_1994> ;
   schema:publisher <http://experiment.worldcat.org/entity/work/data/341467496#Agent/vch> ; # VCH
   schema:url <http://www.gbv.de/dms/bowker/toc/9783527292134.pdf> ;
   schema:url <http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&doc_number=006411379&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA> ;
   schema:workExample <http://worldcat.org/isbn/9781560818786> ;
   schema:workExample <http://worldcat.org/isbn/9783527292134> ;
   umbel:isLike <http://d-nb.info/941025004> ;
   umbel:isLike <http://bnb.data.bl.uk/id/resource/GB9546449> ;
   wdrs:describedby <http://www.worldcat.org/title/-/oclc/60241197> ;
    .


Related Entities

<http://id.worldcat.org/fast/815019> # Aromatic compounds
    a schema:Intangible ;
   schema:name "Aromatic compounds"@en ;
    .

<http://viaf.org/viaf/92943094> # Heinrich Zollinger
    a schema:Person ;
   schema:familyName "Zollinger" ;
   schema:givenName "Heinrich" ;
   schema:name "Heinrich Zollinger" ;
    .

<http://worldcat.org/isbn/9781560818786>
    a schema:ProductModel ;
   schema:isbn "1560818786" ;
   schema:isbn "9781560818786" ;
    .

<http://worldcat.org/isbn/9783527292134>
    a schema:ProductModel ;
   schema:isbn "3527292136" ;
   schema:isbn "9783527292134" ;
    .


Content-negotiable representations

Close Window

Please sign in to WorldCat 

Don't have an account? You can easily create a free account.