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Electrostatic and Stereoelectronic Effects in Carbohydrate Chemistry.

Author: Momcilo Miljkovic.
Publisher: Springer US, 2014.
Edition/Format:   eBook : Document : EnglishView all editions and formats
Database:WorldCat
Summary:
This book deals with polar effects in carbohydrates and how these effects control the stereochemistry of carbohydrate reactions. This is important for understanding the mechanisms of certain carbohydrate reactions, including enzymatic reactions such as glycosidases, a very important group of enzymes in living matter. It is also very useful for synthetic carbohydrate chemists who would like to synthesize  Read more...
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Genre/Form: Electronic books
Additional Physical Format: Print version:
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Momcilo Miljkovic.
ISBN: 1306542391 9781306542395 9781461482680 1461482682
OCLC Number: 875638485
Description: 1 online resource
Contents: 1. Introduction --
2. Anomeric effect and related stereoelectronic effects --
3. Oxocarbenium ion --
4. Conformations and chemistry of oxocarbenium ion --
5. Armed-disarmed concept in the synthesis of glycosidic bond --
6. Stereoelectronic effects in nucleosides and nucleotides --
7. Free radical cyclizations --
8. Carbohydrate sulfones.

Abstract:

This book deals with polar effects in carbohydrates and how these effects control the stereochemistry of carbohydrate reactions. This is important for understanding the mechanisms of certain carbohydrate reactions, including enzymatic reactions such as glycosidases, a very important group of enzymes in living matter. It is also very useful for synthetic carbohydrate chemists who would like to synthesize stereoselectively certain classes of carbohydrates.

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