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Fluorine-containing synthons

Author: V A Soloshonok; American Chemical Society. Division of Fluorine Chemistry.; American Chemical Society. Division of Medicinal Chemistry.; American Chemical Society. Division of Organic Chemistry.
Publisher: Washington, DC : American Chemical Society : Distributed by Oxford University Press, ©2005.
Series: ACS symposium series, 911.
Edition/Format:   eBook : Document : Conference publication : EnglishView all editions and formats
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Genre/Form: Electronic books
Conference papers and proceedings
Congresses
Congrès
Additional Physical Format: Print version:
Fluorine-containing synthons.
Washington, DC : American Chemical Society : Distributed by Oxford University Press, ©2005
(DLC) 2005041194
(OCoLC)58563542
Material Type: Conference publication, Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: V A Soloshonok; American Chemical Society. Division of Fluorine Chemistry.; American Chemical Society. Division of Medicinal Chemistry.; American Chemical Society. Division of Organic Chemistry.
ISBN: 9780841220294 0841220298
OCLC Number: 429527954
Language Note: English.
Notes: Title from PDF title page (ACS publications, viewed Aug 5, 2009).
"Sponsored by the ACS Divisions of Fluorine Chemistry, Medicinal Chemistry, and Organic Chemistry."
Reproduction Notes: Electronic reproduction. [S.l.] : HathiTrust Digital Library, 2010. MiAaHDL
Description: 1 online resource (xiv, 666 pages) : illustrations.
Details: Master and use copy. Digital master created according to Benchmark for Faithful Digital Reproductions of Monographs and Serials, Version 1. Digital Library Federation, December 2002.
Contents: Recent advances in perfluoroalkylation methodology --
New nucleophilic fluoroalkylation chemistry --
Fluoroform, fluoral, trifluoroacetic, and trifluoromethanesulfinic acids derivatives as new reagents for the introduction of polyfluorinated moieties SF₅-synthons : pathways to organic derivatives of SF₆ --
Stereoselective synthesis of monofluoroalkenes using cross-coupling reactions --
A new in situ room temperature approach to fluorinated vinylzinc reagents and fluorinated styrenes --
Vinyl fluorides in cycloadditions --
Asymmetric synthesis of monofluorinated compounds having the fluorine atom vicinal to pi-systems --
A new aspect of fluoroalkylated acetylenes : synthesis and applications --
hydrometallation and carbometallation --
Functionalized fluorinated allenes --
Regioexhaustive functionalizations : to miss an isomer means to miss a chance --
Perfluoroketene dithioacetals : versatile building blocks toward trifluoromethyl heterocycles --
Highly functionalized heterocycles and macrocycles from pentafluoropyridine --
Synthetic methods for the preparation of ring-fluorinated heterocycles via intramolecular vinylic substitution of gem-difluoroalkenes --
Selective anodic fluorination of heterocyclic compounds --
Polyfluorinated binaphthol ligands in asymmetric catalysis --
Selective fluorination of biologically important imidazoles and indoles --
Functional group transformations at alpha-carbon to trifluoromethyl group --
Use of trifluoroacetaldehyde ethyl hemiacetal in a simple and practical synthesis of beta-hydroxy-beta-trifluoromethylated ketones --
Fluorinated synthon : asymmetric catalytic reactions --
Industrial synthetic application of fluoral and 3,3-dichloro-1,1,1-trifluoroacetone as fluorinated synthons --
Synthesis and utility of fluorinated acylsilanes --
The role of fluorine-containing methyl groups toward diastereofacial selection --Reactions of unsaturated organometallic reagents on trifluoroacetaldimines --
Optically active gem-difluorocyclopropanes : synthesis and application for novel molecular materials --
General methods for the synthesis of difluoromethylphosphonates --
Mg-promoted selective C-F bond cleavage : a general and efficient access to difluoroenol silyl ethers and their derivatives --
Reactions of ethyl bromodifluoroacetate in the presence of copper powder --
Fluorine-based crystal engineering --
Haloperfluorocarbons : versatile tectons in halogen bonding based crystal engineering --
Fluoro-beta-lactams as useful building blocks for the synthesis of fluorinated amino acids, dipeptides, and toxoids --
Synthesis of fluorinated prolines and pyroglutamic acids --
Synthesis and properties of new fluorinated peptidomimetics --
Fluorinated beta-enamino esters as versatile synthetic intermediates : synthesis of fluorinated beta-amino acids and uracils --
Using the potential of fluorine for peptide and protein modification.
Series Title: ACS symposium series, 911.
Responsibility: Vadim A. Soloshonok, editor.

Abstract:

The book contains 35 reviews on recent methodological developments in the area of synthetic fluoro-organic chemistry based on fluorinated synthons approach. Special emphases are given to the  Read more...

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