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Fluorine in organic chemistry

Author: R D Chambers
Publisher: Oxford : Blackwell : CRC Press, 2003.
Edition/Format:   Print book : English : [Rev. and updated ed.]View all editions and formats

Introducing the chemical properties and electronic effects of fluorocarbon systems, this book details the methods for the preparation and synthesis of partially, selectively, and highly fluorinated  Read more...


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Document Type: Book
All Authors / Contributors: R D Chambers
ISBN: 1405107871 9781405107877 0849317908 9780849317903
OCLC Number: 56923568
Notes: Previous edition: New York; London: Wiley-Interscience, 1973.
Description: xvii, 406 pages : illustrations ; 25 cm
Contents: General Discussion of Fluorine in Organic Chemistry General introduction Electronic effects in fluorocarbon systems Nomenclature ReferencesPreparation of Highly Fluorinated Compounds Fluorination with metal fluorides Electrochemical fluorination Fluorination with elemental fluorine Halogen fluorides ReferencesPartial or Selective Fluorination Displacement of a single atom or group using metal fluorides Replacement of hydrogen by fluorine Replacement of hydroxyl by fluorine Miscellaneous methods Fluorination of carbonyl compounds and others Addition to olefins and acetylenes ReferencesInfluence of Fluorine or Fluorocarbon Groups on Reaction Centres Introduction Electronic effects of polyfluoroalkyl groups Strength of unsaturated fluoro acids and fluoro bases Fluorocarbon ions Fluorocarbanions ReferencesNucleophillic Displacement of Halogen from Fluorocarbon Systems Substituent effects of fluorine or fluorocarbon groups on the SN2 process Fluoride ion as a leaving groupElimination Reactions b Elimination of hydrogen halides b Eliminations of metal fluorides a Eliminations - Generation and reactivity of fluorocarbenes and polyfluoroalkylcarbenes ReferencesPolyfluoroalkanes, Polyfluoroalkenes, Polyfluoroalkynes and Derivatives; Perfluoroalkanes and perfluorocycloalkanes Perfluoroalkenes and perfluorocycloalkanes Fluoroacetylenes and fluoroalkylacetylenes ReferencesFunctional Compounds containing Oxygen, Sulphur or Nitrogen and their Derivatives Oxygen derivatives Sulphur derivatives Nitrogen derivatives ReferencesPolyfluoroaromatic Compounds Synthesis Properties and reactions ReferencesOrganometallic ReagentsFluorine in Biochemistry
Responsibility: Richard D. Chambers.


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"In this second, completely revised and enlarged edition, Richard Chambers, a leading expert in the field, brings together everything of importance to fluorine in organic synthesis. With almost 2000 Read more...

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