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Fundamentals of chemical engineering thermodynamics : with applications to chemical processes

Author: Themis Matsoukas
Publisher: Upper Saddle River, NJ : Prentice Hall, ©2013.
Series: Prentice-Hall international series in the physical and chemical engineering sciences.
Edition/Format:   Print book : EnglishView all editions and formats
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Genre/Form: Textbooks
Document Type: Book
All Authors / Contributors: Themis Matsoukas
ISBN: 0132693062 9780132693066
OCLC Number: 794711765
Description: xxiii, 690 pages : illustrations ; 27 cm.
Contents: Machine generated contents note: pt. I Pure Fluids --
ch. 1 Scope and Language of Thermodynamics --
1.1. Molecular Basis of Thermodynamics --
1.2. Statistical versus Classical Thermodynamics --
1.3. Definitions --
1.4. Units --
1.5. Summary --
1.6. Problems --
ch. 2 Phase Diagrams of Pure Fluids --
2.1. The PVT Behavior of Pure Fluid --
2.2. Tabulation of Properties --
2.3.Compressibility Factor and the ZP Graph --
2.4. Corresponding States --
2.5. Virial Equation --
2.6. Cubic Equations of State --
2.7. PVT Behavior of Cubic Equations of State --
2.8. Working with Cubic Equations --
2.9. Other Equations of State --
2.10. Thermal Expansion and Isothermal Compression --
2.11. Empirical Equations for Density --
2.12. Summary --
2.13. Problems --
ch. 3 Energy and the First Law --
3.1. Energy and Mechanical Work --
3.2. Shaft Work and PV Work --
3.3. Internal Energy and Heat --
3.4. First Law for a Closed System --
3.5. Elementary Paths --
3.6. Sensible Heat --
Heat Capacities --
3.7. Heat of Vaporization --
3.8. Ideal-Gas State --
3.9. Energy Balances and Irreversible Processes --
3.10. Summary --
3.11. Problems --
ch. 4 Entropy and the Second Law --
4.1. The Second Law in a Closed System --
4.2. Calculation of Entropy --
4.3. Energy Balances Using Entropy --
4.4. Entropy Generation --
4.5. Carnot Cycle --
4.6. Alternative Statements of the Second Law --
4.7. Ideal and Lost Work --
4.8. Ambient Surroundings as a Default Bath --
Exergy --
4.9. Equilibrium and Stability --
4.10. Molecular View of Entropy --
4.11. Summary --
4.12. Problems --
ch. 5 Calculation of Properties --
5.1. Calculus of Thermodynamics --
5.2. Integration of Differentials --
5.3. Fundamental Relationships --
5.4. Equations for Enthalpy and Entropy --
5.5. Ideal-Gas State --
5.6. Incompressible Phases --
5.7. Residual Properties --
5.8. Pressure-Explicit Relations --
5.9. Application to Cubic Equations --
5.10. Generalized Correlations --
5.11. Reference States --
5.12. Thermodynamic Charts --
5.13. Summary --
5.14. Problems --
ch. 6 Balances in Open Systems --
6.1. Flow Streams --
6.2. Mass Balance --
6.3. Energy Balance in Open System --
6.4. Entropy Balance --
6.5. Ideal and Lost Work --
6.6. Thermodynamics of Steady-State Processes --
6.7. Power Generation --
6.8. Refrigeration --
6.9. Liquefaction --
6.10. Unsteady-State Balances --
6.11. Summary --
6.12. Problems --
ch. 7 VLE of Pure Fluid --
7.1. Two-Phase Systems --
7.2. Vapor-Liquid Equilibrium --
7.3. Fugacity --
7.4. Calculation of Fugacity --
7.5. Saturation Pressure from Equations of State --
7.6. Phase Diagrams from Equations of State --
7.7. Summary --
7.8. Problems --
pt. II Mixtures --
ch. 8 Phase Behavior of Mixtures --
8.1. The Txy Graph --
8.2. The Pxy Graph --
8.3. Azeotropes --
8.4. The xy Graph --
8.5. VLE at Elevated Pressures and Temperatures --
8.6. Partially Miscible Liquids --
8.7. Ternary Systems --
8.8. Summary --
8.9. Problems --
ch. 9 Properties of Mixtures --
9.1.Composition --
9.2. Mathematical Treatment of Mixtures --
9.3. Properties of Mixing --
9.4. Mixing and Separation --
9.5. Mixtures in the Ideal-Gas State --
9.6. Equations of State for Mixtures --
9.7. Mixture Properties from Equations of State --
9.8. Summary --
9.9. Problems --
ch. 10 Theory of Vapor-Liquid Equilibrium --
10.1. Gibbs Free Energy of Mixture --
10.2. Chemical Potential --
10.3. Fugacity in a Mixture --
10.4. Fugacity from Equations of State --
10.5. VLE of Mixture Using Equations of State --
10.6. Summary --
10.7. Problems --
ch. 11 Ideal Solution --
11.1. Ideality in Solution --
11.2. Fugacity in Ideal Solution --
11.3. VLE in Ideal Solution-Raoult's Law --
11.4. Energy Balances --
11.5. Noncondensable Gases --
11.6. Summary --
11.7. Problems --
ch. 12 Nonideal Solutions --
12.1. Excess Properties --
12.2. Heat Effects of Mixing --
12.3. Activity Coefficient --
12.4. Activity Coefficient and Phase Equilibrium --
12.5. Data Reduction: Fitting Experimental Activity Coefficients --
12.6. Models for the Activity Coefficient --
12.7. Summary --
12.8. Problems --
ch. 13 Miscibility, Solubility, and Other Phase Equilibria --
13.1. Equilibrium between Partially Miscible Liquids --
13.2. Gibbs Free Energy and Phase Splitting --
13.3. Liquid Miscibility and Temperature --
13.4.Completely Immiscible Liquids --
13.5. Solubility of Gases in Liquids --
13.6. Solubility of Solids in Liquids --
13.7. Osmotic Equilibrium --
13.8. Summary --
13.9. Problems --
ch. 14 Reactions --
14.1. Stoichiometry --
14.2. Standard Enthalpy of Reaction --
14.3. Energy Balances in Reacting Systems --
14.4. Activity --
14.5. Equilibrium Constant --
14.6.Composition at Equilibrium --
14.7. Reaction and Phase Equilibrium --
14.8. Reaction Equilibrium Involving Solids --
14.9. Multiple Reactions --
14.10. Summary --
14.11. Problems.
Series Title: Prentice-Hall international series in the physical and chemical engineering sciences.
Responsibility: Themis Matsoukas.

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