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Global characteristics of atomic spectra and their use for the analysis of spectra. IV. Configuration interaction effects
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Global characteristics of atomic spectra and their use for the analysis of spectra. IV. Configuration interaction effects

Author: S Kučas Affiliation: Institute of Theoretical Physics and Astronomy, A. Goštauto 12, 2600 Vilnius, Lithuania; V Jonauskas; R Karazija
Edition/Format: Article Article : English
Publication:Physica Scripta, v55 n6 (1997): 667-675
Other Databases: WorldCatWorldCat
Summary:

Changes of the moments of atomic spectrum due to configuration interaction (CI), the CI strength, the average shift of the energy of a level due to its interaction with all levels of distant configuration and other global characteritics of CI effects in atoms are systematised and their expressions presented. The results of the calculation of these characteristics for the energy level spectra of the 3s3p3 + 3s23p3d configurations in Si isoelectronic series, 3p53dN + 3p63dN−24p + 3p63dN−24f (N = 5, 6, 7, 8) in Cr, Mn, Fe and Co isoelectronic series, ns2 npN + npN+2 at n = 2 - 5 and N = 2 - 4 in neutral atoms as well as for the characteristic emission spectra corresponding to the 3p53d9 + 3d74p → 3d8 transitions as well as for the Auger M4,5N1N2,3 spectra in Kr and N4,5O1O2,3 in Xe are given and compared with the same characteristics of the more complete experimental spectra.

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Document Type: Article
All Authors / Contributors: S Kučas Affiliation: Institute of Theoretical Physics and Astronomy, A. Goštauto 12, 2600 Vilnius, Lithuania; V Jonauskas; R Karazija
ISSN:1402-4896
Language Note: English
Unique Identifier: 4843862338
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Abstract:

Changes of the moments of atomic spectrum due to configuration interaction (CI), the CI strength, the average shift of the energy of a level due to its interaction with all levels of distant configuration and other global characteritics of CI effects in atoms are systematised and their expressions presented. The results of the calculation of these characteristics for the energy level spectra of the 3s3p3 + 3s23p3d configurations in Si isoelectronic series, 3p53dN + 3p63dN−24p + 3p63dN−24f (N = 5, 6, 7, 8) in Cr, Mn, Fe and Co isoelectronic series, ns2 npN + npN+2 at n = 2 - 5 and N = 2 - 4 in neutral atoms as well as for the characteristic emission spectra corresponding to the 3p53d9 + 3d74p → 3d8 transitions as well as for the Auger M4,5N1N2,3 spectra in Kr and N4,5O1O2,3 in Xe are given and compared with the same characteristics of the more complete experimental spectra.

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