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Global Characteristics of Atomic Spectra and Their Use for the Analysis of Spectra. V. Relativistic Effects within an Open Shell
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Global Characteristics of Atomic Spectra and Their Use for the Analysis of Spectra. V. Relativistic Effects within an Open Shell

Author: V Jonauskas Affiliation: State Institute of Theoretical Physics and Astronomy, A. Goštauto 12, Vilnius, 2600, Lithuania; S Kučas; R Karazija
Edition/Format: Article Article : English
Publication:Physica Scripta, v67 n3 (2003): 208-218
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Document Type: Article
All Authors / Contributors: V Jonauskas Affiliation: State Institute of Theoretical Physics and Astronomy, A. Goštauto 12, Vilnius, 2600, Lithuania; S Kučas; R Karazija
ISSN:1402-4896
Language Note: English
Unique Identifier: 4843868454
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Abstract:

Explicit expressions for the variance of energy level spectra of relativistic nlj-configuration as well as of their set originating from the same nl-configuration are presented in the Dirac-Breit approximation. The relativistic formulae for the skewness and excess are derived too. These global characteristics are used to investigate the relativistic effects within an open electronic shell in homologous, isoelectronic and isoionic sequences. The change of the coupling scheme from LS to jj within the npN (n = 2 - 6) and ndN (n = 3 - 5) shells is considered. The main global characteristics are used also to investigate the accuracy of various relativistic approximations: Breit-Pauli, pseudorelativistic and the complex of noninteracting relativistic configurations.

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