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Grignard reagents : new developments

Author: Herman G Richey
Publisher: Chichester ; New York : Wiley, ©2000.
Edition/Format:   Print book : EnglishView all editions and formats
Summary:
"Publishing 100 years after Grignard proposed his simple procedure for preparing solutions of organomagnesium compounds, leading experts present authoritative perspectives on the current status of 12 areas that have developed significantly in recent years." "Grignard Reagents: New Developments will prove of great interest to academic and industrial chemists active in organometallic chemistry of main group metals,  Read more...
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Document Type: Book
All Authors / Contributors: Herman G Richey
ISBN: 0471999083 9780471999089
OCLC Number: 42004415
Description: xvi, 418 pages : illustrations ; 26 cm
Contents: 1. Mechanistic Features of the Reactions of Organomagnesium Compounds / Torkil Holm and Ingolf Crossland --
2. Nucleophilic Displacements at Carbon by Grignard Reagents / E. Alexander Hill --
3. Hydromagnesiation of Alkenes and Alkynes / Fumie Sato and Hirokazu Urabe --
4. Stereoselective Addition of Grignard Reagents to Alkenes / Amir H. Hoveyda, Nicola M. Heron and Jeffrey A. Adams --
5. Stereoselective Additions of Chiral Grignard Reagents to Aldehydes: Stereochemical and Mechanistic Principles, with Examples Using [alpha]-Amino Grignard Reagents / Robert E. Gawley --
6. Grignard Reagents --
Industrial Applications and Strategy / Frank R. Busch and David M. De Antonis --
7. Mechanisms of Grignard Reagent Formation / John F. Garst and Ferenc Ungvary --
8. Applications of Magnesium Anthracene in Forming Grignard Reagents / Colin L. Raston --
9. Structures of Organomagnesium Compounds as Revealed by X-ray Diffraction Studies / F. Bickelhaupt --
10. X-ray Absorption Spectroscopy and Large Angle X-ray Scattering of Grignard Compounds / T. S. Ertel and H. Bertagnolli --
11. Di- and Polyfunctional Organomagnesium Compounds / F. Bickelhaupt --
12. Unusual Organomagnesium Compounds / V. V. Smirnov, L. A. Tjurina and I. P. Beletskaya.
Responsibility: edited by Herman G. Richey, Jr.

Abstract:

Discovered early this century, Grignard reagents remain the most widely-used organometallic compounds. Recent years have seen a steady stream of developments in such areas as the nature of the  Read more...

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"...this book fills a need....it should be in every university and industrial library." --Angewandte Chemie, 18th September 2000

 
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