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An Introduction to ionic liquids

Author: Michael Freemantle
Publisher: Cambridge, UK : RSC Pub., ©2010.
Edition/Format:   Book : EnglishView all editions and formats
Database:WorldCat
Summary:
In the late 1990s, there was an explosion of research on ionic liquids and they are now a major topic of academic and industrial interest with numerous existing and potential applications. Over the past decade, the number of scientific papers focusing on ionic liquids has risen exponentially. A few edited multi-author books covering the latest advances in ionic liquid chemistry and several volumes of symposium  Read more...
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Material Type: Internet resource
Document Type: Book, Internet Resource
All Authors / Contributors: Michael Freemantle
ISBN: 9781847551610 1847551610
OCLC Number: 477137207
Description: xiv, 281 p. : ill. ; 24 cm.
Contents: Introduction --
Ionic liquids --
Cations and anions --
Aprotic and protic ionic liquids --
Binary mixtures --
Organic and inorganic ionic liquids --
Deep eutectic solvents --
Task-specific ionic liquids --
Chiral ionic liquids --
History --
Synthesis of Ionic liquids --
Alkylation --
Anion exchange --
Microwave- and ultrasound-assisted synthesis --
Halide-free synthesis --
Synthesis by protonation --
Synthesis by haloaluminate ionic liquids --
Synthesis of task-specific ionic liquids --
Chiral synthesis --
Properties of Ionic liquids --
Liquid range and thermal stability --
Melting points --
Vapour pressure --
Heat capacity and heat transfer --
Viscosity --
Density --
Solubility and miscibility --
Water stability --
Conductivity --
Electrochemical potential window --
surface tension --
Fluorescence --
Refractive indices --
Impact of impurities --
Ionic liquids as designer solvents --
Solubility and miscibility --
Polarity and solvation --
Miscibility with water --
Miscibility with organic compounds --
Solubility of metal salts --
Gas solubility --
Biphasic systems --
Phase diagrams --
Partitioning of solutes between ionic liquids and water --
Biphasic systems of hydrophilic ionic liquids and water --
Mutually immiscible ionic liquids --
Extraction of organic compounds --
Gas separations --
Carbon dioxide extractions and separations --
Metal ion extractions --
Extractive distillations --
Membrane separations --
Green credentials of Ionic liquids --
Vapour pressure --
Flammability and combustibility --
Recycling --
Environmental exposure and toxicity --
Biodegradability --
Bioaccumulation --
Electrochemistry --
Cyclic voltammetry --
Batteries --
Fuel cells --
Dye-sensitized solar cells --
Electrodeposition --
Actuators --
Supercapacitors --
Electrosynthesis --
Catalysis --
Monophasic and biphasic catalysis --
Solvents, catalysts and ligands --
Catalyst performance --
Supported ionic liquid catalysis --
Nanoparticle catalysts --
Acid-base catalysis --
Transition metal catalysis --
Chiral transition metal catalysis --
Task-specific ionic liquids in catalysis --
Inorganic chemistry --
Main group chemistry --
Transition metal chemistry --
Organometallic compounds --
Nuclear chemistry --
Nanoparticles --
Carbon nanotubes --
Metal and semiconductor nanoparticles --
Alloy nanoparticles --
Metal oxide nanoparticles --
Other nanoparticles --
Microspheres --
Sol-gel synthesis of porous materials --
Ionothermal synthesis of porous materials --
General organic reactions --
Aldol condensation --
Alkylation --
Cracking --
Cycloaddition --
Debromination --
Dimerization and oligomerization --
Electrophilic reactions --
Epoxidation --
Esterification --
Etherization --
Halogenation --
Hydroformylation --
Hydrogenation --
Hydrosilylation --
Nitration of aromatics --
Nucleophilic reactions --
Olefin metathesis --
Oxidation --
Peptide synthesis --
Photochemical reactions --
Polymerizations --
Named organic reactions --
Baeyer-Villiger oxidation --
Baylis-Hillman reaction --
Beckmann rearrangement --
Diels-Alder reaction --
Friedel-Crafts reactions --
Grignard reaction --
Heck reaction --
Knoevenagel condensation and Robinson annulation --
Mannich reaction --
Michael addition --
Sonogashira coupling --
Stille coupling --
Suzuki cross-coupling --
Swern oxidation --
Ullmann coupling --
Wacker oxidation --
Wittig reaction --
Biotechnology --
Carbohydrate solubility --
Biomass conversion --
Enzyme catalysis --
Early studies of ionic liquid-enzyme systems --
Lipases --
Proteases , esterases and other enzymes --
Enantioselectivity and regioselectivity --
Biphasic systems and separations --
Analysis --
Chromatography --
Capillary electrophoresis --
Sensors --
Gas sensors --
Ion-selective electrodes --
Biosensors --
Spectroscopy --
Mass spectrometry --
Applications --
Synthesis of 2,5-dihydrofuran --
Difasol process --
BASIL process --
Storage of hazardous gases --
Lubrication --
Compressors --
Energetic materials and propellants --
Optical immersion fluids --
Lunar liquid mirror telescope --
Thermometers --
Antimicrobial agents --
Active pharmaceutical ingredients --
Nucleoside-based antiviral drugs --
Embalming and tissue preservation fluids.
Responsibility: Michael Freemantle.

Abstract:

This is the first single-author book on ionic liquids and the first introductory book on the topic. It is written in a clear, concise and consistent way. The book provides a useful introduction to  Read more...

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"If there ever was a case of a reporter becoming part of the story, it would have to be Michael FreemantleAes pivotal role in the growth of the field now known as ionic liquids." Robin D.Rogers Read more...

 
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schema:description"Introduction -- Ionic liquids -- Cations and anions -- Aprotic and protic ionic liquids -- Binary mixtures -- Organic and inorganic ionic liquids -- Deep eutectic solvents -- Task-specific ionic liquids -- Chiral ionic liquids -- History -- Synthesis of Ionic liquids -- Alkylation -- Anion exchange -- Microwave- and ultrasound-assisted synthesis -- Halide-free synthesis -- Synthesis by protonation -- Synthesis by haloaluminate ionic liquids -- Synthesis of task-specific ionic liquids -- Chiral synthesis -- Properties of Ionic liquids -- Liquid range and thermal stability -- Melting points -- Vapour pressure -- Heat capacity and heat transfer -- Viscosity -- Density -- Solubility and miscibility -- Water stability -- Conductivity -- Electrochemical potential window -- surface tension -- Fluorescence -- Refractive indices -- Impact of impurities -- Ionic liquids as designer solvents -- Solubility and miscibility -- Polarity and solvation -- Miscibility with water -- Miscibility with organic compounds -- Solubility of metal salts -- Gas solubility -- Biphasic systems -- Phase diagrams -- Partitioning of solutes between ionic liquids and water -- Biphasic systems of hydrophilic ionic liquids and water -- Mutually immiscible ionic liquids -- Extraction of organic compounds -- Gas separations -- Carbon dioxide extractions and separations -- Metal ion extractions -- Extractive distillations -- Membrane separations -- Green credentials of Ionic liquids -- Vapour pressure -- Flammability and combustibility -- Recycling -- Environmental exposure and toxicity -- Biodegradability -- Bioaccumulation -- Electrochemistry -- Cyclic voltammetry -- Batteries -- Fuel cells -- Dye-sensitized solar cells -- Electrodeposition -- Actuators -- Supercapacitors -- Electrosynthesis -- Catalysis -- Monophasic and biphasic catalysis -- Solvents, catalysts and ligands -- Catalyst performance -- Supported ionic liquid catalysis -- Nanoparticle catalysts -- Acid-base catalysis -- Transition metal catalysis -- Chiral transition metal catalysis -- Task-specific ionic liquids in catalysis -- Inorganic chemistry -- Main group chemistry -- Transition metal chemistry -- Organometallic compounds -- Nuclear chemistry -- Nanoparticles -- Carbon nanotubes -- Metal and semiconductor nanoparticles -- Alloy nanoparticles -- Metal oxide nanoparticles -- Other nanoparticles -- Microspheres -- Sol-gel synthesis of porous materials -- Ionothermal synthesis of porous materials -- General organic reactions -- Aldol condensation -- Alkylation -- Cracking -- Cycloaddition -- Debromination -- Dimerization and oligomerization -- Electrophilic reactions -- Epoxidation -- Esterification -- Etherization -- Halogenation -- Hydroformylation -- Hydrogenation -- Hydrosilylation -- Nitration of aromatics -- Nucleophilic reactions -- Olefin metathesis -- Oxidation -- Peptide synthesis -- Photochemical reactions -- Polymerizations -- Named organic reactions -- Baeyer-Villiger oxidation -- Baylis-Hillman reaction -- Beckmann rearrangement -- Diels-Alder reaction -- Friedel-Crafts reactions -- Grignard reaction -- Heck reaction -- Knoevenagel condensation and Robinson annulation -- Mannich reaction -- Michael addition -- Sonogashira coupling -- Stille coupling -- Suzuki cross-coupling -- Swern oxidation -- Ullmann coupling -- Wacker oxidation -- Wittig reaction -- Biotechnology -- Carbohydrate solubility -- Biomass conversion -- Enzyme catalysis -- Early studies of ionic liquid-enzyme systems -- Lipases -- Proteases , esterases and other enzymes -- Enantioselectivity and regioselectivity -- Biphasic systems and separations -- Analysis -- Chromatography -- Capillary electrophoresis -- Sensors -- Gas sensors -- Ion-selective electrodes -- Biosensors -- Spectroscopy -- Mass spectrometry -- Applications -- Synthesis of 2,5-dihydrofuran -- Difasol process -- BASIL process -- Storage of hazardous gases -- Lubrication -- Compressors -- Energetic materials and propellants -- Optical immersion fluids -- Lunar liquid mirror telescope -- Thermometers -- Antimicrobial agents -- Active pharmaceutical ingredients -- Nucleoside-based antiviral drugs -- Embalming and tissue preservation fluids."@en
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