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Investigation of reactions involving pentacoordinate intermediates : the mechanism of the Wittig reaction

Author: Peter A Byren
Publisher: Berlin ; London : Springer, 2012.
Dissertation: Thesis (PhD.)-- University College Dublin, Ireland.
Series: Springer theses.
Edition/Format:   Thesis/dissertation : Document : Thesis/dissertation : eBook   Computer File : EnglishView all editions and formats
Database:WorldCat
Summary:
In this thesis, the author outlines the discovery of an effect common to representative examples of all Li salt-free Wittig Reactions. The implications of such a universally applicable effect are that all such Wittig reactions occur through the same mechanism. Although the Wittig reaction was first discovered in 1953, its reaction mechanism has never been definitively settled with many different variants proposed  Read more...
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Genre/Form: Electronic books
Additional Physical Format: Print version:
Byren, Peter A.
Investigation of reactions involving pentacoordinate intermediates.
Berlin ; London : Springer, 2012
(OCoLC)815367905
Material Type: Document, Thesis/dissertation, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Peter A Byren
ISBN: 9783642320453 3642320457
OCLC Number: 826864899
Description: 1 online resource.
Contents: Introduction to the Wittig Reaction and Discussion of the Mechanism --
Wittig Reactions of Aldehydes Bearing a [beta]-Heteroatom Substituent --
A Convenient Chromatography-Free Method for the Purification of Alkenes Produced in the Wittig Reaction --
Experimental.
Series Title: Springer theses.
Responsibility: Peter A. Byren.
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Abstract:

Although the Wittig reaction was first discovered in 1953, its reaction mechanism has never been definitively settled. This book shows conclusively that for [2+2] cycloadditions all Wittig reactions  Read more...

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