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Liquids and liquid mixtures

Author: J S Rowlinson
Publisher: London ; Boston : Butterworth Scientific, 1982.
Series: Butterworth's monographs in chemistry.
Edition/Format:   eBook : Document : English : Third editionView all editions and formats
Summary:
Liquids and Liquid Mixtures, Third Edition explores the equilibrium properties of liquids and liquid mixtures and relates them to the properties of the constituent molecules using the methods of statistical thermodynamics. Topics covered include the critical state, fluid mixtures at high pressures, and the statistical thermodynamics of fluids and mixtures. This book consists of eight chapters and begins with an  Read more...
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Genre/Form: Electronic books
Additional Physical Format: Print version:
Rowlinson, J.S. (John Shipley), 1926-
Liquids and liquid mixtures.
(DLC) 83161509
(OCoLC)8684977
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: J S Rowlinson
ISBN: 9781483140674 1483140679
OCLC Number: 881849374
Description: 1 online resource (viii, 328 pages) : illustrations.
Contents: Front Cover; Liquids and Liquid Mixtures; Copyright Page; Preface to the Third Edition; Table of Contents; Chapter 1. Introduction; 1.1 The liquid state; References; Chapter 2. The thermodynamic properties; 2.1 Summary of thermodynamic relations; 2.2 Vapour pressure; 2.3 Mechanical properties; 2.4 Heat capacities; 2.5 Adiabatic properties; 2.6 Residual and configurational properties; 2.7 van der Waals's equation; References; Chapter 3. The critical state; 3.1 Thermodynamics of the critical point; 3.2 Inequalities at the critical point; 3.3 The measurement of critical constants 3.4 Experimental values of the critical exponents3.5 Scaling the free energy; References; Chapter 4. The thermodynamics of liquid mixtures; 4.1 Introduction; 4.2 Partial molar quantities; 4.3 The ideal mixture; 4.4 Thermodynamics of non-ideal mixtures; 4.5 Tests for consistency; 4.6 Azeotropy; 4.7 Fields and densities; 4.8 Thermodynamics of partially miscible liquids; 4.9 Exponents at the critical point of a binary mixture; 4.10 Tricritical points; References; Chapter 5. Excess thermodynamic functions; 5.1 Introduction; 5.2 The experimental determination of excess functions 5.3 Mixtures of condensed gases5.4 Liquefied natural-gas mixtures; 5.5 Mixtures of the higher hydrocarbons; 5.6 Mixtures containing halides; 5.7 Mixtures containing fluorocarbons; 5.8 Mixtures containing polar liquids; 5.9 Aqueous mixtures; 5.10 Mixtures of quantum liquids; References; Chapter 6. Fluid mixtures at high pressures; 6.1 Introduction; 6.2 Gas-liquid critical states of binary mixtures; 6.3 High-pressure phase equilibria: type I mixtures; 6.4 High-pressure phase equilibria: type II and type VI mixtures; 6.5 High-pressure phase equilibria: type III mixtures 6.6 High-pressure phase equilibria: type IV and type V mixturesReferences; Chapter 7. The statistical thermodynamics of fluids; 7.1 Intermolecular forces; 7.2 Molecular distribution functions; 7.3 Molecular correlation functions; 7.4 The measurement and calculation of correlation functions; 7.5 The principle of corresponding states; 7.6 Perturbation theories: spherical molecules; 7.7 Perturbation theories: non-spherical molecules; References; Chapter 8. The statistical thermodynamics of mixtures; 8.1 Introduction; 8.2 Ideal and random mixtures; 8.3 Mixtures of spheres 8.4 The van der Waals approximation8.5 Perturbation theories of mixtures of spherical molecules; 8.6 Excess functions of simple mixtures; 8.7 Mixtures of alkanes; 8.8 Perturbation theories of mixtures of non-spherical molecules; 8.9 Phase equilibria at high pressures; 8.10 Conclusions; References; General index; Index of systems
Series Title: Butterworth's monographs in chemistry.
Responsibility: J.S. Rowlinson, F.L. Swinton.

Abstract:

Liquids and Liquid Mixtures, Third Edition explores the equilibrium properties of liquids and liquid mixtures and relates them to the properties of the constituent molecules using the methods of statistical thermodynamics. Topics covered include the critical state, fluid mixtures at high pressures, and the statistical thermodynamics of fluids and mixtures. This book consists of eight chapters and begins with an overview of the liquid state and the thermodynamic properties of liquids and liquid mixtures, including vapor pressure and heat capacities. The discussion then turns to the thermodynami.

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