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Metal-ammonia solutions : proceedings of an international conference on the nature of metal-ammonia solutions. Colloque Weyl II held at Cornell University ... 1969.

Author: Michell J Sienko; J J Lagowski; International Union of Pure and Applied Chemistry.
Publisher: London : Butterworths, [1970]
Series: Pure and applied chemistry. Supplement
Edition/Format:   eBook : Document : Conference publication : EnglishView all editions and formats
Summary:
Metal-Ammonia Solutions contains the proceedings of an International Conference on the Nature of Metal-Ammonia Solutions Colloque Weyl II held at Cornell University in Ithaca, New York, on June 15-19, 1969. The papers explore the nature of metal-ammonia solutions and cover topics ranging from the dilemma of metal-ammonia models to the magnetic properties of metal-ammonia solutions, the reactions of such solutions,  Read more...
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Genre/Form: Electronic books
Conference papers and proceedings
Congresses
Additional Physical Format: Print version:
Colloque Weyl (2nd : 1969 : Cornell University).
Metal-ammonia solutions.
London, Butterworths [1970]
(OCoLC)818192
Material Type: Conference publication, Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Michell J Sienko; J J Lagowski; International Union of Pure and Applied Chemistry.
ISBN: 9781483136233 148313623X
OCLC Number: 727865748
Description: 1 online resource (viii, 514 pages) : illustrations.
Details: Master and use copy. Digital master created according to Benchmark for Faithful Digital Reproductions of Monographs and Serials, Version 1. Digital Library Federation, December 2002.
Contents: Front Cover; Metal-Ammonia Solutions; Copyright Page; PREFACE; LIST OF PARTICIPANTS; Table of Contents; CHAPTER 1. THE DILEMMA OF METAL-AMMONIA MODELS; NULL RESULTS; CATION-ELECTRON INTERACTIONS; ELECTRON-ELECTRON INTERACTIONS; NON-SPECIFIC CONCENTRATION EFFECTS; MODELS OF METAL-AMMONIA SOLUTIONS; CALCULATION OF EQUILIBRIUM CONSTANTS; CATION MOBILITY; ACTIVITY COEFFICIENTS; ENTHALPY OF SOLUTION; CONCLUSIONS; ACKNOWLEDGEMENT; REFERENCES; GENERAL DISCUSSION; CHAPTER 2. A MODEL FOR THE SOLVATED DIELECTRON IN DIELECTRIC MEDIA; THEORY; APPLICATION TO THE e2-CENTRE IN LIQUID AMMONIA; REFERENCES. Vi. wigner-seitz model for the quasi-free electron statevii. the ground state energy of a quasi-free electron; viii. localized excess electron states in non-polar fluids; ix. the bubble model; x. the electron bubble in liquid helium; xi. a localization criterion for an excess electron in a non-polar fluid; xii. electron localization in solid helium; xiii. positronium bubbles in non-polar liquids; xiv. implications for the understanding ofexcess electron states in polar solvents; xv. energetics of solvated electrons; xvi. the simple version of the continuum model. Xvii. speculations on the quasi-free electron state in polar liquidsxviii. a modified continuum model for the solvated electron; xix. medium rearrangement energy in a polar solvent; xx. configuration diagrams for solvated electrons; xxi. optical properties; xxii. future trends; acknowledgements; references; general discussion; chapter 6. the magnetic properties of metal-ammonia solutions; magnetic measurements; metal-ammonia solutions; conclusions: the structure of thesolvated electron; acknowledgements; references; general discussion. Chapter 7. a proton resonance study of metal-ammonia solutionstheory; experimental; results and discussion; acknowledgements; references; general discussion; chapter 8. intermetallic solutes in liquid ammonia; experimental results; knight shifts; esr absorptions; conclusions; acknowledgements; references; discussion; chapter 9. magnetic resonance and susceptibility measurements on sodium-hexamethylphosphoramide (hmpa) solutions; results; discussion; acknowledgements; references; general discussion; chapter 10. lithium-7 knight shifts for lithium in ammonia and lithium in methylamine.
Series Title: Pure and applied chemistry. Supplement
Responsibility: Technical editors: J.J. Lagowski and M.J. Sienko.

Abstract:

Metal-Ammonia Solutions contains the proceedings of an International Conference on the Nature of Metal-Ammonia Solutions Colloque Weyl II held at Cornell University in Ithaca, New York, on June 15-19, 1969. The papers explore the nature of metal-ammonia solutions and cover topics ranging from the dilemma of metal-ammonia models to the magnetic properties of metal-ammonia solutions, the reactions of such solutions, and solid metal-ammonia compounds. This monograph is comprised of 39 chapters and begins with an overview of models for the concentration dependence of the properties of dilute metal.

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