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Non-equilibrium thermodynamics of heterogeneous systems

Author: Signe Kjelstrup; Dick Bedeaux
Publisher: Hackensack, NJ : World Scientific, ©2008.
Series: Series on advances in statistical mechanics, v. 16.
Edition/Format:   Print book : EnglishView all editions and formats
Database:WorldCat
Summary:
"The purpose of this book is to encourage the use of non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. With large coupling effects between the transport of heat, mass, charge and chemical reactions at surfaces, it is important to know how one should properly integrate across systems where different phases are in contact. No other book gives a prescription of how to set up flux  Read more...
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Material Type: Internet resource
Document Type: Book, Internet Resource
All Authors / Contributors: Signe Kjelstrup; Dick Bedeaux
ISBN: 9789812779137 9812779132
OCLC Number: 191658618
Description: xv, 434 p. : ill. ; 24 cm.
Contents: Scope --
Why non-equilibrium thermodynamics? --
Thermodynamic relations for heterogeneous systems --
The entropy production for a homogeneous phase --
The excess entropy production for the surface --
The excess entropy production for a three phase contact line --
Flux equations and Onsager relations --
Transport of heat and mass --
Transport of heat and charge --
Transport of mass and charge --
Evaporation and condensation --
Multi-component heat and mass diffusion --
A nonisothermal concentration cell --
The transported entropy --
Adiabatic electrode reactions --
The liquid junction potential --
The formation cell --
Power from regular and thermal osmosis --
Modeling the polymer electrolyte fuel cell --
Measuring membrane transport properties --
The impedance of an electrode surface --
Non-equilibrium molecular dynamics simulations --
The non-equilibrium two-phase van der Waals model.
Series Title: Series on advances in statistical mechanics, v. 16.
Responsibility: Signe Kjelstrup, Dick Bedeaux.

Abstract:

With large coupling effects between the transport of heat, mass, charge and chemical reactions at surfaces, it is important to know how one should properly integrate across systems where different  Read more...

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This textbook may serve as a basis for an introductory course on the theory of non-equilibrium thermodynamics in heterogeneous media. It will appeal to both mathematicians and mathematics graduate Read more...

 
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    schema:reviewBody ""The purpose of this book is to encourage the use of non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. With large coupling effects between the transport of heat, mass, charge and chemical reactions at surfaces, it is important to know how one should properly integrate across systems where different phases are in contact. No other book gives a prescription of how to set up flux equations for transports across heterogeneous systems." "The authors apply the thermodynamic description in terms of excess densities, developed by Gibbs for equilibrium, to non-equilibrium systems. The treatment is restricted to transport into and through the surface. Using local equilibrium together with the balance equations for the surface, expressions for the excess entropy production of the surface and of the contact line are derived. Many examples are given to illustrate how the theory can be applied to coupled transport of mass, heat, charge and chemical reactions; in phase transitions, at electrode surfaces and in fuel cells. Molecular simulations and analytical studies are used to add insight."--Jacket." ;
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