skip to content
Omega-Terminated Alkanethiolate Monolayers on Surfaces of Copper, Silver and Gold Have Similar Wettabilities. Preview this item
ClosePreview this item
Checking...

Omega-Terminated Alkanethiolate Monolayers on Surfaces of Copper, Silver and Gold Have Similar Wettabilities.

Author: Paul E Laibinis; George M Whitesides; HARVARD UNIV CAMBRIDGE MA Dept. of CHEMISTRY.
Publisher: Ft. Belvoir : Defense Technical Information Center, DEC 1991.
Edition/Format:   Print book : English
Database:WorldCat
Summary:
Long chain alkanethiols (HS(CH2)nX) adsorb from solution onto the surfaces of freshly evaporated copper, silver and gold films and form oriented monolayers. Both polar and non-polar tail groups (X) can be accommodated in these adsorptions. Adsorption on all three metals generates self-assembled monolayers (SAMs) exhibiting similar wetting properties, and thus, by inference, having related oriented structures. XPS  Read more...
Rating:

(not yet rated) 0 with reviews - Be the first.

Subjects
More like this

 

Find a copy in the library

&AllPage.SpinnerRetrieving; Finding libraries that hold this item...

Details

Document Type: Book
All Authors / Contributors: Paul E Laibinis; George M Whitesides; HARVARD UNIV CAMBRIDGE MA Dept. of CHEMISTRY.
OCLC Number: 227775150
Notes: Technical rept.
Description: 51 pages ; 23 x 29 cm

Abstract:

Long chain alkanethiols (HS(CH2)nX) adsorb from solution onto the surfaces of freshly evaporated copper, silver and gold films and form oriented monolayers. Both polar and non-polar tail groups (X) can be accommodated in these adsorptions. Adsorption on all three metals generates self-assembled monolayers (SAMs) exhibiting similar wetting properties, and thus, by inference, having related oriented structures. XPS data suggest that the omega-terminated eta-alkanethiolate monolayers, like those derived from simple alkanethiols, are composed of trans-extended chains having orientations on copper and silver that are closer to the perpendicular to the surface than are those on gold. We have prepared and characterized monolayers (mixed monolayers) by exposure of all three metals to mixtures of HS (CH2)11OH and HS9CH2)11CH3.

Reviews

User-contributed reviews
Retrieving GoodReads reviews...
Retrieving DOGObooks reviews...

Tags

Be the first.
Confirm this request

You may have already requested this item. Please select Ok if you would like to proceed with this request anyway.

Linked Data


Primary Entity

<http://www.worldcat.org/oclc/227775150> # Omega-Terminated Alkanethiolate Monolayers on Surfaces of Copper, Silver and Gold Have Similar Wettabilities.
    a schema:CreativeWork, schema:Book ;
   library:oclcnum "227775150" ;
   library:placeOfPublication <http://id.loc.gov/vocabulary/countries/vau> ;
   library:placeOfPublication <http://experiment.worldcat.org/entity/work/data/137449077#Place/ft_belvoir> ; # Ft. Belvoir
   schema:about <http://experiment.worldcat.org/entity/work/data/137449077#Topic/adsorption> ; # Adsorption
   schema:about <http://experiment.worldcat.org/entity/work/data/137449077#Topic/organic_chemistry> ; # Organic chemistry
   schema:about <http://experiment.worldcat.org/entity/work/data/137449077#Topic/copper> ; # Copper
   schema:about <http://experiment.worldcat.org/entity/work/data/137449077#Topic/wetting> ; # Wetting
   schema:about <http://experiment.worldcat.org/entity/work/data/137449077#Topic/gold> ; # Gold
   schema:about <http://experiment.worldcat.org/entity/work/data/137449077#Topic/orientation_direction> ; # Orientation(direction)
   schema:about <http://experiment.worldcat.org/entity/work/data/137449077#Topic/silver> ; # Silver
   schema:about <http://experiment.worldcat.org/entity/work/data/137449077#Topic/polar_regions> ; # Polar regions
   schema:about <http://experiment.worldcat.org/entity/work/data/137449077#Topic/films> ; # Films
   schema:about <http://experiment.worldcat.org/entity/work/data/137449077#Topic/layers> ; # Layers
   schema:about <http://experiment.worldcat.org/entity/work/data/137449077#Topic/surfaces> ; # Surfaces
   schema:about <http://experiment.worldcat.org/entity/work/data/137449077#Topic/mixing> ; # Mixing
   schema:about <http://experiment.worldcat.org/entity/work/data/137449077#Topic/right_angles> ; # Right angles
   schema:about <http://experiment.worldcat.org/entity/work/data/137449077#Topic/tail_assemblies> ; # Tail assemblies
   schema:about <http://experiment.worldcat.org/entity/work/data/137449077#Topic/chains> ; # Chains
   schema:about <http://experiment.worldcat.org/entity/work/data/137449077#Topic/structures> ; # Structures
   schema:bookFormat bgn:PrintBook ;
   schema:contributor <http://experiment.worldcat.org/entity/work/data/137449077#Organization/harvard_univ_cambridge_ma_dept_of_chemistry> ; # HARVARD UNIV CAMBRIDGE MA Dept. of CHEMISTRY.
   schema:contributor <http://experiment.worldcat.org/entity/work/data/137449077#Person/laibinis_paul_e> ; # Paul E. Laibinis
   schema:contributor <http://viaf.org/viaf/59178840> ; # George M. Whitesides
   schema:datePublished "1991" ;
   schema:datePublished "DEC 1991" ;
   schema:description "Long chain alkanethiols (HS(CH2)nX) adsorb from solution onto the surfaces of freshly evaporated copper, silver and gold films and form oriented monolayers. Both polar and non-polar tail groups (X) can be accommodated in these adsorptions. Adsorption on all three metals generates self-assembled monolayers (SAMs) exhibiting similar wetting properties, and thus, by inference, having related oriented structures. XPS data suggest that the omega-terminated eta-alkanethiolate monolayers, like those derived from simple alkanethiols, are composed of trans-extended chains having orientations on copper and silver that are closer to the perpendicular to the surface than are those on gold. We have prepared and characterized monolayers (mixed monolayers) by exposure of all three metals to mixtures of HS (CH2)11OH and HS9CH2)11CH3."@en ;
   schema:exampleOfWork <http://worldcat.org/entity/work/id/137449077> ;
   schema:inLanguage "en" ;
   schema:name "Omega-Terminated Alkanethiolate Monolayers on Surfaces of Copper, Silver and Gold Have Similar Wettabilities."@en ;
   schema:productID "227775150" ;
   schema:publication <http://www.worldcat.org/title/-/oclc/227775150#PublicationEvent/ft_belvoir_defense_technical_information_center_dec_1991> ;
   schema:publisher <http://experiment.worldcat.org/entity/work/data/137449077#Agent/defense_technical_information_center> ; # Defense Technical Information Center
   wdrs:describedby <http://www.worldcat.org/title/-/oclc/227775150> ;
    .


Related Entities

<http://experiment.worldcat.org/entity/work/data/137449077#Agent/defense_technical_information_center> # Defense Technical Information Center
    a bgn:Agent ;
   schema:name "Defense Technical Information Center" ;
    .

<http://experiment.worldcat.org/entity/work/data/137449077#Organization/harvard_univ_cambridge_ma_dept_of_chemistry> # HARVARD UNIV CAMBRIDGE MA Dept. of CHEMISTRY.
    a schema:Organization ;
   schema:name "HARVARD UNIV CAMBRIDGE MA Dept. of CHEMISTRY." ;
    .

<http://experiment.worldcat.org/entity/work/data/137449077#Person/laibinis_paul_e> # Paul E. Laibinis
    a schema:Person ;
   schema:familyName "Laibinis" ;
   schema:givenName "Paul E." ;
   schema:name "Paul E. Laibinis" ;
    .

<http://experiment.worldcat.org/entity/work/data/137449077#Topic/orientation_direction> # Orientation(direction)
    a schema:Intangible ;
   schema:name "Orientation(direction)"@en ;
    .

<http://viaf.org/viaf/59178840> # George M. Whitesides
    a schema:Person ;
   schema:familyName "Whitesides" ;
   schema:givenName "George M." ;
   schema:name "George M. Whitesides" ;
    .

<http://www.worldcat.org/title/-/oclc/227775150>
    a genont:InformationResource, genont:ContentTypeGenericResource ;
   schema:about <http://www.worldcat.org/oclc/227775150> ; # Omega-Terminated Alkanethiolate Monolayers on Surfaces of Copper, Silver and Gold Have Similar Wettabilities.
   schema:dateModified "2017-04-02" ;
   void:inDataset <http://purl.oclc.org/dataset/WorldCat> ;
    .


Content-negotiable representations

Close Window

Please sign in to WorldCat 

Don't have an account? You can easily create a free account.