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Organic Chemistry of Nucleic Acids : Part B

Author: N K Kochetkov; E I Budovskii
Publisher: Boston, MA : Springer US, 1972.
Edition/Format:   eBook : Document : EnglishView all editions and formats
Summary:
5 Substitutions and Additions in the Heterocyclic Rings of the Bases of Nucleic Acids and their Derivatives.- I. Introduction.- II. Substitution and addition reactions at carbon atoms.- 1. Halogenation.- 2. Nitration.- 3. Hydroxymethylation, aminomethylation, and chloromethylation.- 4. Reactions with diazonium salts.- 5. Reactions with N-arylhydroxylamines and their derivatives.- 6. Isotopic exchange of hydrogen  Read more...
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Genre/Form: Electronic books
Additional Physical Format: Printed edition:
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: N K Kochetkov; E I Budovskii
ISBN: 9781468429732 1468429736 9781468429756 1468429752
OCLC Number: 840288061
Description: 1 online resource
Contents: 5 Substitutions and Additions in the Heterocyclic Rings of the Bases of Nucleic Acids and their Derivatives --
I. Introduction --
II. Substitution and addition reactions at carbon atoms --
III. Substitutionsand additions reaction at the nitrogen atoms --
6 Reactions of Exocyclic Substituents of the Bases of Nucleic Acids and their Derivatives --
I. Introduction --
II. Substitution reactions at the nitrogen atom of an exocyclic amino group --
III. Substitutions at exocyclic oxygen and sulphur atoms --
7 Reactions Involving the Cleavage or Regrouping of Heterocyclic Rings of the Bases of Nucleic acids and their Derivatives --
I. Introduction --
II. Reactions of cleavage and rearrangement of the rings by the action of nucleophilic agents --
III. Cleavage by the action of hydrazine --
IV. Cleavage by the action of hydroxylamine --
V. Cleavage of rings by the action of potassium permanganate and osmium tetroxide --
VI. Cleavage by the action of peroxide derivatives --
8 Hydrolysis of N-Glycosidic Bonds in Nucleosides, Nucleotides and their Derivatives --
I. Introduction --
II. Hydrolysis of N-glycosidic bonds catalyzed by acids 425 1. Effect of structural factors on the kinetics of hydrolysis of pyrimidine derivatives --
III. Hydrolysis of N-glycosidic bonds in pyrimidine deoxyribonucleosides, not catalyzed by acids or bases --
IV. Hydrolysis of N-glycosidic bonds in an alkaline medium --
V. Other reactions leading to cleavage of glycosidic bonds --
9 Reactions of the Carbohydrate Residues of Nucleic Acids --
I. Introduction --
II. Acylation of hydroxyl groups of carbohydrate residues --
III. Alkylation of the hydroxyl groups of carbohydrate residues --
IV. Reactions of hydroxyl groups of carbohydrate residues with vinyl esters --
V. Reactions of hydroxyl groups of carbohydrate residues with carbonyl compounds and with their derivatives --
VI. Oxidation of carbohydrate residues --
10 Cleavage of Phosphoester Bonds and some other Reactions of Phophate Groups of Nucleic Acids and their Derivatives --
I. Introduction --
II. Reactions with cleavage of P-O bonds --
III. Reactions with rupture of C-0 bonds --
IV. Reactions leading to the formation of phosphoester bonds --
11 Some Reactions of Minor Components of Nucleic Acids --
I. Introduction --
II. Reactions of 6-exo-N-isopentenyladenosine and its derivatives --
III. Reactions of pseudouridine and its derivatives --
IV. Reactions of 5-hydroxymethylpyrimidine derivatives --
12 Photochemistry of the Nucleic Acids and their Components --
I Introduction --
II The basic concepts and laws of photochemistry --
III Absorption spectra of nucleic acids and their components --
IV Excited states of nucleic acids and their components --
V. Photochemical conversions of nucleic acids and their components --
VI. Photosensitized reactions --
VII. The photodynamic effect --
VIII. The action of visible light in the presence of iron ions --
IX. Photochemical reactions induced by excitation of a reagent --
X. Effect of chelating agents on photodimerization --
Index for Parts A and B.
Responsibility: edited by N.K. Kochetkov, E.I. Budovskii.

Abstract:

The study of nucleic acids is one of the most rapidly developing fields in modern science. There is yet another highly important aspect of the chemistry of nucleic acids which is still in the  Read more...

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