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Organometallic chemistry and catalysis

Author: D Astruc
Publisher: Berlin ; New York : Springer, ©2007.
Series: Grenoble sciences.
Edition/Format:   eBook : Document : EnglishView all editions and formats
Summary:
This tutorial volume covers the basic and advanced aspects of organometallic chemistry of all metals and related catalysis topics. It treats historical background, concepts (including structures of mono- and polymetallic complexes), molecular orbitals, reactivity, implications in biology and applications to organic synthesis and catalysis. The catalysis section includes the challenging activation and  Read more...
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Genre/Form: Electronic books
Problems and exercises
Problems, exercises, etc
Additional Physical Format: Print version:
Astruc, D. (Didier).
Organometallic chemistry and catalysis.
Berlin ; New York : Springer, ©2007
(OCoLC)77541307
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: D Astruc
ISBN: 9783540461296 3540461299 9783540461289 3540461280
OCLC Number: 191467033
Language Note: Translated from French.
Description: 1 online resource (xii, 608 pages) : illustrations.
Contents: Introduction --
History of organometallic chemistry --
PART I STRUCTURES OF THE TRANSITION-METAL COMPLEXES Monometallic transition-metal complexes --
Bimetallic transition-metal complexes and clusters --
PART II THE STOICHIOMETRIC REACTIONS OF TRANSITION-METAL COMPLEXES Redox reactions, oxidative addition and s --
bond metathesis --
Reactions of nucleophiles and electrophiles with complexes --
Ligand substitution reactions --
Insertion and extrusion reactions --
PART III THE MAIN FAMILIES OF ORGANOMETALLIC COMPLEXES Metal carbonyls and complexes of other monohapto L ligands --
Metal-alkyl and -hydride complexes and other complexes of monohapto X ligands --
Metal-carbene and -carbyne complexes and multiple bonds with transition metals --
p complexes of mono- and polyenes and enyls --
Ionic and polar metal-carbon bonds: alkali and rare-earth complexes Metallocenes and sandwich complexes --
Covalent chemistry of the organoelements of frontier (11, 12) and main (13-16) groups --
PART IV CATALYSIS Hydrogenation and hydroelementation of alkenes --
Transformations of alkenes and alkynes --
Oxidation of olefins --
C-H activation and functionalization of alkanes and arenes --
Carbonylation and carboxylation reactions --
Bio-organometallic chemistry: enzymatic catalysis --
Heterogeneous catalysis --
PART V APPLICATIONS IN ORGANIC SYNTHESIS Organometallic complexes in organic synthesis Examples of applications --
Answers to exercises .
Series Title: Grenoble sciences.
Other Titles: Chimie organométallique.
Responsibility: Didier Astruc.

Abstract:

This volume is the first student text on the subject and covers both basic and advanced aspects of organometallic chemistry of all metals and catalysis. In order to present a comprehensive view of  Read more...

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Aus den Rezensionen:"Das erfolgreiche franzosische Lehrbuch `Chimie Organometallique' liegt nun uberarbeitet in englischer UEbersetzung vor. Es soll als Begleitung zur ersten Vorlesung in Read more...

 
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