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The organometallic chemistry of the transition metals

Author: Robert H Crabtree
Publisher: Hoboken, New Jersey : Wiley, [2014]
Edition/Format:   eBook : Document : English : Sixth editionView all editions and formats
Summary:
Fully updated and expanded to reflect recent advances, the sixth edition of this bestselling text provides students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications. Increased focus is given to organic synthesis  Read more...
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Genre/Form: Electronic books
Additional Physical Format: Print version:
Crabtree, Robert H., 1948-
Organometallic chemistry of the transition metals.
Hoboken, New Jersey : Wiley, [2014]
(DLC) 2013046043
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Robert H Crabtree
ISBN: 9781118788240 1118788249 9781118788448 1118788443 9781118788424 1118788427 9781118788301 1118788303 1118138074 9781118138076
OCLC Number: 863383849
Description: 1 online resource
Contents: 9.3 Hydrogenation --
Oxidative Addition Pathway --
Directing Effects --
Asymmetric Catalysis --
Reversibility --
Heterolytic H2 Activation --
Homolytic H2 Activation --
Outer Sphere Hydrogenation --
Transfer Hydrogenation --
Nanoparticles --
9.4 Alkene Hydroformylation --
Chelating and Phosphite Ligands --
9.5 Alkene Hydrocyanation --
9.6 Alkene Hydrosilylation and Hydroboration --
Hydrosilylation --
Hydroboration --
9.7 Coupling Reactions --
9.8 Organometallic Oxidation Catalysis --
Oxidase Reactions --
Water Splitting and C-H Oxidation --
9.9 Surface, Supported, and Cooperative Catalysis --
Surface Organometallic Chemistry --
Cooperative Catalysis --
Hidden Acid Catalysis --
References --
Problems --
10: Physical Methods --
10.1 Isolation --
10.2 1H NMR Spectroscopy --
Virtual Coupling --
Diastereotopy --
Chemical Shifts --
Paramagnetic NMR --
10.3 13C NMR Spectroscopy --
10.4 31P NMR Spectroscopy --
Mechanistic Study of Wilkinson Hydrogenation --
10.5 Dynamic NMR --
Rate of Fluxionality --
Ligand Fluxionality --
10.6 Spin Saturation Transfer --
10.7 T1 and the Nuclear Overhauser Effect --
T1 and H2 Complexes --
PHIP and SABRE --
Nuclear Overhauser Effect --
10.8 IR Spectroscopy --
Carbonyls --
Other Ligands --
Band Identification by Isotope Substitution --
Raman Spectroscopy --
10.9 Crystallography --
Limitations --
10.10 Electrochemistry and EPR --
10.11 Computation --
10.12 Other Methods --
Mass Spectroscopy --
Single-Molecule Imaging --
Interpretation of Results --
References --
Problems --
11: M-L Multiple Bonds --
11.1 Carbenes --
Fischer versus Schrock Carbenes --
Fischer Carbenes --
Schrock Carbenes --
Intermediate Cases --
Boryls --
11.2 Carbynes --
Synthesis --
Structure and Spectra --
Reactions --
11.3 Bridging Carbenes and Carbynes --
Structure and Spectra --
Reactions --
11.4 N-Heterocyclic Carbenes --
Synthesis of NHC Complexes. Polydentate NHCs --
Applications --
11.5 Multiple Bonds to Heteroatoms --
Oxo Wall --
Synthesis --
Spectra and Structure --
References --
Problems --
12: Applications --
12.1 Alkene Metathesis --
Mechanism --
Selectivity in Cross Metathesis --
Commercial Applications --
12.2 Dimerization, Oligomerization, and Polymerization of Alkenes --
Catalyst Activation --
Microstructure --
Mechanism --
SHOP Oligomerization --
12.3 Activation of CO And CO2 --
Water-Gas Shift --
Monsanto Acetic Acid Process --
CO2 Activation --
12.4 C-H Activation --
Shilov Chemistry --
Other Routes --
C-C Bond Formation and Cleavage --
12.5 Green Chemistry --
Alcohol Activation and Hydrogen Borrowing --
12.6 Energy Chemistry --
References --
Problems --
13: Clusters, Nanoparticles, Materials, and Surfaces --
13.1 Cluster Structures --
Effective Atomic Number (EAN) Rule --
Wade-Mingos Rules --
13.2 The Isolobal Analogy --
13.3 Nanoparticles --
13.4 Organometallic Materials --
Bulk Materials --
Porous Materials --
Metal Organic Frameworks (MOFs) --
Porous Organic Polymers (POPs) --
Organometallic Polymers --
Molecular Wires --
Molecular Electronics --
Nonlinear Optical (NLO) Materials --
Organic Light-Emitting Diodes (OLEDs) --
Sensors --
References --
Problems --
14: Organic Applications --
14.1 Carbon-Carbon Coupling --
14.2 Metathesis --
14.3 Cyclopropanation And C-H Insertion --
14.4 Hydrogenation --
Kinetic Resolution --
Asymmetric Hydrogenation --
14.5 Carbonylation --
14.6 Oxidation --
14.7 C-H Activation --
14.8 Click Chemistry --
References --
Problems --
15: Paramagnetic and High Oxidation-State Complexes --
15.1 Magnetism and Spin States --
Spin States --
Influence of Spin State Changes on Kinetics and Thermodynamics --
3d versus 4d and 5d Metals --
NMR Spectroscopy --
15.2 Polyalkyls and Polyhydrides --
Group 4 --
Group 5 --
Group 6 --
Group 7 --
Groups 8-l0 --
Group 11.
Responsibility: by Robert H. Crabtree.

Abstract:

Widely regarded as the premier text in this field, the sixth edition of The Organometallic Chemistry of the Transition Metals continues to provide students and researchers in organic chemistry with  Read more...

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Overall, this book is an insightful, detailed and, most importantly, up-to-date view of organometallic chemistry. (Applied Organometallic Chemistry, 14 November 2014)

 
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