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|Additional Physical Format:||Print version:
Palladium-Catalyzed Coupling Reactions.
Weinheim : Wiley, ©2013
|Material Type:||Document, Internet resource|
|Document Type:||Internet Resource, Computer File|
|All Authors / Contributors:||
|Notes:||3.2 General Considerations Concerning Magnetic Particles as Catalyst Supports.|
|Description:||1 online resource (533 pages)|
|Contents:||Palladium-Catalyzed Coupling Reactions: Practical Aspects and Future Developments; Contents; Foreword; Preface; List of Contributors; 1 Palladium-Catalyzed Cross-Coupling Reactions --
A General Introduction; 1.1 Introduction; 1.1.1 Historical Reflection; 1.1.2 Characteristics, Recent Developments, and Progress; 1.1.3 Literature Reviews and Organization of the Chapter; 1.2 Carbon-Carbon Cross-Coupling Reactions Catalyzed by Palladium; 1.2.1 Classification and Overview; 1.2.2 Common Mechanistic Features of Cross-Coupling Reactions and Reactivity of the Substrates. 22.214.171.124 Choice of the Carbon Electrophile126.96.36.199 Choice of the Carbon Nucleophile --
What Makes the Difference?; 1.3 The Catalysts; 1.3.1 The Particular Features of Palladium; 1.3.2 Classes of Palladium Catalysts Applied to Cross-Coupling Reactions; 188.8.131.52 Ligands and Palladium Complexes --
Homogeneous Systems; 184.108.40.206 Immobilized or Supported Palladium Complexes and Particles --
Heterogeneous Systems; 220.127.116.11 Palladium Colloids and (Nonsupported) Nanoparticles; 18.104.22.168 Activity of Heterogeneous Catalysts; 1.4 Mechanistic Aspects. 1.4.1 General Mechanism of C C Cross-Coupling and Heck Reactions with Homogeneous Catalyst Precursors1.4.2 Models for Heck and Suzuki Reactions with Supported Pd Precursors; 1.4.3 Recent Results on the Reaction Mechanism and the Nature of the Active Pd Species; 22.214.171.124 Observation of Intermediates in Homogeneous Catalysis by Electrochemical Methods; 126.96.36.199 The Question of Pd Leaching; 188.8.131.52 Selectivity Pattern; 184.108.40.206 In Situ Observation by Spectroscopic Methods; 220.127.116.11 Immobilized Pd Pincer Complexes; 18.104.22.168 Palladium Bulk Materials (Pd Foil, Wire, Sponge) as Catalyst. 1.5 Future ChallengesAbbreviations; References; 2 High-Turnover Heterogeneous Palladium Catalysts in Coupling Reactions: the Case of Pd Loaded on Dealuminated Y Zeolites; 2.1 Introduction; 2.2 Various Methodologies to Afford High Turnover Numbers Over Supported Pd Catalysts; 2.3 Structure and Characteristics of Ultrastable Y Zeolites; 2.4 Suzuki-Miyaura Reactions Catalyzed by Pd/USY; 2.4.1 Catalytic Performance of Pd/USY; 2.4.2 Pd Leaching from Pd/USY; 2.4.3 Selectivity in the Homocoupling Reactions; 2.4.4 Characterization of the Active Pd Species by X-Ray Absorption Spectroscopy. 2.4.5 A Suggested Mechanism for the Formation of Active Pd Species in Suzuki-Miyaura Coupling Reactions2.5 Catalytic Performance of Pd/USY in Mizoroki-Heck Reactions; 2.5.1 Effect of H2 Bubbling on the Catalytic Reactions of Pd/USY; 2.5.2 Catalytic Reactions Using Chlorobenzene Derivatives; 2.5.3 Characterization of the Pd Species by X-Ray Absorption Spectroscopy; 2.6 Conclusion and Perspective; Abbreviations; References; 3 Palladium-Catalyzed Coupling Reactions with Magnetically Separable Nanocatalysts; 3.1 Introduction.
"Overall, the sensible and logical presentation of information and breadth of material covered should make this book a very useful interdisciplinary reference text, while also providing for readers