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Phase equilibrium in mixtures

Author: M B King
Publisher: Oxford ; New York : Pergamon Press, [1969]
Series: International series of monographs on chemical engineering, v. 9.
Edition/Format:   eBook : Document : English : [1st ed.]View all editions and formats
Summary:
Phase Equilibrium in Mixtures.
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Genre/Form: Electronic books
Additional Physical Format: Print version:
King, M.B.
Phase equilibrium in mixtures.
Oxford, New York, Pergamon Press [1969]
(DLC) 67027484
(OCoLC)260
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: M B King
ISBN: 9781483152417 1483152413
OCLC Number: 680117940
Reproduction Notes: Electronic reproduction. [S.l.] : HathiTrust Digital Library, 2010. MiAaHDL
Description: 1 online resource (xviii, 585 pages) : illustrations.
Details: Master and use copy. Digital master created according to Benchmark for Faithful Digital Reproductions of Monographs and Serials, Version 1. Digital Library Federation, December 2002.
Contents: Front Cover; Phase Equilibrium in Mixtures; Copyright Page; Table of Contents; Preface; Nomenclature and units used; List of symbols; CHAPTER 1. INTRODUCTION AND SOME THERMODYNAMIC CONSIDERATIONS; SCOPE OF THE BOOK; THE ROLE OF THERMODYNAMICS AND THE CRITERIA FOR EQUILIBRIUM BETWEEN PHASES; THE CHEMICAL POTENTIAL; PROPERTIES OF PARTIAL MOLAR QUANTITIES; DEPENDENCE OF THE THERMODYNAMIC FUNCTIONS OF PURE SUBSTANCES ON PRESSURE. REFERENCE VALUES FOR THESE FUNCTIONS. THE FUGACITY OF A PURE SUBSTANCE; DEPENDENCE OF THE THERMODYNAMIC FUNCTIONS OF MIXTURES ON PRESSURE AND COMPOSITION; THE FUGACITY. Ideal solutionsnon-ideal solutions; the phase rule for non-reacting components; chemically reacting systems; chapter 2. descriptive account of phase equilibria; introduction, phase behaviour of pure substances; vapour-liquid equilibria for systems which are completely miscible in the liquid phase; phase equilibrium diagrams for mixtures of substances which are not completely miscible in the liquid phase; gas hydrates; chapter 3. latent heats and vapour pressures; latent heats; vapour pressure equations for pure substances. Temperature dependence of the dew- and bubble-point pressures of mixturesaccurate representation of vapour pressure and other phase boundary data using residual plots; extension of vapour pressure data using reference substance plots; chapter 4. dilute solutions; henry's law; liquid-liquid equilibrium; the solubility of non-polar substancesin water and in aqueous solutions of electrolytes; chapter 5. ideal and near-ideal solutions; chapter 6. non-ideal solutions at normalpressures: uses of the activity coefficient; introduction. Analytical representation of activity coefficients as functions of composition at constant temperature.correlation of isothermal vapour-liquid equilibrium datathe activity coefficient as a function of temperature; correlation of activity coefficients derived from isobaric vapour-liquid equilibrium data; partial pressures and activity coefficients in systems where a specific reaction occurs; prediction of activity coefficients for binary systems from the properties of the pure components. Prediction of liquid-liquid equilibria in a ternary system when two of the components are virtually immiscibleprediction of vapour-liquid equilibrium data for a binary system with immiscible liquid phases, from mutual solubility data for the two liquids; prediction of activity coefficients for ternary systems from phase equilibrium data for the corresponding binary systems; prediction of activity coefficients for quaternary and multicomponent systems from data for the appropriate binary systems; azeotropes; chapter 7. consistency tests.
Series Title: International series of monographs on chemical engineering, v. 9.
Responsibility: M.B. King.

Abstract:

Phase Equilibrium in Mixtures.

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