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Photoinitiators for polymer synthesis : scope, reactivity and efficiency

Author: Jean-Pierre Fouassier; Jacques Lalevée
Publisher: Weinheim : Wiley-VCH, ©2012.
Edition/Format:   Print book : EnglishView all editions and formats
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This handbook covers radical and non-radical photoinitiating systems and describes the basic principles and applications of photopolymerization reactions within the fields of polymer and materials  Read more...

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Document Type: Book
All Authors / Contributors: Jean-Pierre Fouassier; Jacques Lalevée
ISBN: 9783527332106 3527332103 9783527648276 3527648275 9783527648269 3527648267 9783527648252 3527648259 9783527648245 3527648240
OCLC Number: 814300791
Description: xxviii, 476 pages : illustrations ; 25 cm
Contents: Abbreviations XIX Introduction XXV Part I Basic Principles and Applications of Photopolymerization Reactions 1 1 Photopolymerization and Photo-Cross-Linking 3 References 6 2 Light Sources 11 2.1 Electromagnetic Radiation 11 2.2 Characteristics of a Light Source 12 2.3 Conventional and Unconventional Light Sources 13 References 20 3 Experimental Devices and Examples of Applications 21 3.1 UV Curing Area: Coatings, Inks, Varnishes, Paints, and Adhesives 21 3.2 Conventional Printing Plates 25 3.3 Manufacture of Objects and Composites 25 3.4 Stereolithography 25 3.5 Applications in Microelectronics 26 3.6 Laser Direct Imaging 26 3.7 Computer-to-Plate Technology 27 3.8 Holography 27 3.9 Optics 28 3.10 Medical Applications 28 3.11 Fabrication of Nano-Objects through a Two-Photon Absorption Polymerization 29 3.12 Photopolymerization Using Near-Field Optical Techniques 29 3.13 Search for New Properties and New End Uses 30 3.14 Photopolymerization and Nanotechnology 32 3.15 Search for a Green Chemistry 33 References 34 4 Photopolymerization Reactions 41 4.1 Encountered Reactions, Media, and Experimental Conditions 41 4.2 Typical Characteristics of Selected Photopolymerization Reactions 45 4.3 Two-Photon Absorption-Induced Polymerization 60 4.4 Remote Curing: Photopolymerization without Light 60 4.5 Photoactivated Hydrosilylation Reactions 61 References 61 5 Photosensitive Systems 73 5.1 General Properties 73 5.2 Absorption of Light by a Molecule 74 5.3 Jablonski s Diagram 78 5.4 Kinetics of the Excited State Processes 78 5.5 Photoinitiator and Photosensitizer 80 5.6 Absorption of a Photosensitive System 81 5.7 Initiation Step of a Photoinduced Polymerization 82 5.8 Reactivity of a Photosensitive System 86 References 87 6 Approach of the Photochemical and Chemical Reactivity 89 6.1 Analysis of the Excited-State Processes 89 6.2 Quantum Mechanical Calculations 93 6.3 Cleavage Process 94 6.4 Hydrogen Transfer Processes 95 6.5 Energy Transfer 96 6.6 Reactivity of Radicals 98 References 99 7 Efficiency of a Photopolymerization Reaction 103 7.1 Kinetic Laws 103 7.2 Monitoring the Photopolymerization Reaction 109 7.3 Efficiency versus Reactivity 111 7.4 Absorption of Light by a Pigment 112 7.5 Oxygen Inhibition 114 7.6 Absorption of Light Stabilizers 115 7.7 Role of the Environment 117 References 118 Part II Radical Photoinitiating Systems 123 8 One-Component Photoinitiating Systems 127 8.1 Benzoyl-Chromophore-Based Photoinitiators 127 8.2 Substituted Benzoyl-Chromophore-Based Photoinitiators 148 8.3 Hydroxy Alkyl Heterocyclic Ketones 157 8.4 Hydroxy Alkyl Conjugated Ketones 158 8.5 Benzophenone- and Thioxanthone-Moiety-Based Cleavable Systems 158 8.6 Benzoyl Phosphine Oxide Derivatives 161 8.7 Phosphine Oxide Derivatives 165 8.8 Trichloromethyl Triazines 165 8.9 Biradical-Generating Ketones 166 8.10 Peroxides 166 8.11 Diketones 167 8.12 Azides and Aromatic Bis-Azides 168 8.13 Azo Derivatives 168 8.14 Disulfide Derivatives 168 8.15 Disilane Derivatives 169 8.16 Diselenide and Diphenylditelluride Derivatives 170 8.17 Digermane and Distannane Derivatives 170 8.18 Carbon Germanium Cleavable-Bond-Based Derivatives 170 8.19 Carbon Silicon and Germanium Silicon Cleavable Bond-Based Derivatives 172 8.20 Silicon Chemistry and Conventional Cleavable Photoinitiators 172 8.21 Sulfur Carbon Cleavable-Bond-Based Derivatives 173 8.22 Sulfur Silicon Cleavable-Bond-Based Derivatives 173 8.23 Peresters 173 8.24 Barton s Ester Derivatives 174 8.25 Hydroxamic and Thiohydroxamic Acids and Esters 174 8.26 Organoborates 176 8.27 Organometallic Compounds 176 8.28 Metal Salts and Metallic Salt Complexes 178 8.29 Metal-Releasing Compound 178 8.30 Cleavable Photoinitiators in Living Polymerization 179 8.31 Oxyamines 183 8.32 Cleavable Photoinitiators for Two-Photon Absorption 184 8.33 Nanoparticle-Formation-Mediated Cleavable Photoinitiators 185 8.34 Miscellaneous Systems 185 8.35 Tentatively Explored UV-Light-Cleavable Bonds 185 References 187 9 Two-Component Photoinitiating Systems 199 9.1 Ketone-/Hydrogen-Donor-Based Systems 199 9.2 Dye-Based Systems 238 9.3 Other Type II Photoinitiating Systems 241 References 258 10 Multicomponent Photoinitiating Systems 269 10.1 Generally Encountered Mechanism 269 10.2 Other Mechanisms 271 10.3 Type II Photoinitiator/Silane: Search for New Properties 279 10.4 Miscellaneous Multicomponent Systems 281 References 281 11 Other Photoinitiating Systems 283 11.1 Photoinitiator-Free Systems or Self-Initiating Monomers 283 11.2 Semiconductor Nanoparticles 284 11.3 Self-Assembled Photoinitiator Monolayers 284 References 285 Part III Nonradical Photoinitiating Systems 287 12 Cationic Photoinitiating Systems 289 12.1 Diazonium Salts 289 12.2 Onium Salts 289 12.3 Organometallic Derivatives 308 12.4 Onium Salt/Photosensitizer Systems 311 12.5 Free-Radical-Promoted Cationic Photopolymerization 318 12.6 Miscellaneous Systems 332 12.7 Photosensitive Systems for Living Cationic Polymerization 332 12.8 Photosensitive Systems for Hybrid Cure 333 References 333 13 Anionic Photoinitiators 343 13.1 Inorganic Complexes 343 13.2 Organometallic Complexes 343 13.3 Cyano Derivative/Amine System 344 13.4 Photosensitive Systems for Living Anionic Polymerization 344 References 345 14 Photoacid Generators (PAG) Systems 347 14.1 Iminosulfonates and Oximesulfonates 347 14.2 Naphthalimides 348 14.3 Photoacids and Chemical Amplification 349 References 349 15 Photobase Generators (PBG) Systems 351 15.1 Oxime Esters 351 15.2 Carbamates 351 15.3 Ammonium Tetraorganyl Borate Salts 351 15.4 N-Benzylated-Structure-Based Photobases 352 15.5 Other Miscellaneous Systems 353 15.6 Photobases and Base Proliferation Processes 354 References 354 Part IV Reactivity of the Photoinitiating System 357 16 Role of the Experimental Conditions in the Performance of a Radical Photoinitiator 359 16.1 Role of Viscosity 360 16.2 Role of the Surrounding Atmosphere 361 16.3 Role of the Light Intensity 361 References 364 17 Reactivity and Efficiency of Radical Photoinitiators 367 17.1 Relative Efficiency of Photoinitiators 367 17.2 Role of the Excited-State Reactivity 377 17.3 Role of the Medium on the Photoinitiator Reactivity 381 17.4 Structure/Property Relationships in Photoinitiating Systems 388 References 394 18 Reactivity of Radicals toward Oxygen, Hydrogen Donors, Monomers, and Additives: Understanding and Discussion 399 18.1 Alkyl and Related Carbon-Centered Radicals 399 18.2 Aryl Radicals 401 18.3 Benzoyl Radicals 402 18.4 Acrylate and Methacrylate Radicals 403 18.5 Aminoalkyl Radicals 404 18.6 Phosphorus-Centered Radicals 412 18.7 Thiyl Radicals 413 18.8 Sulfonyl and Sulfonyloxy Radicals 417 18.9 Silyl Radicals 418 18.10 Oxyl Radicals 425 18.11 Peroxyl Radicals 426 18.12 Aminyl Radicals 431 18.13 Germyl and Stannyl Radicals 432 18.14 Boryl Radicals 435 18.15 Lophyl Radicals 439 18.16 Iminyl Radicals 439 18.17 Metal-Centered Radicals 440 18.18 Propagating Radicals 442 18.19 Radicals in Controlled Photopolymerization Reactions 443 18.20 Radicals in Hydrosilylation Reactions 446 References 447 19 Reactivity of Radicals: Towards the Oxidation Process 455 19.1 Reactivity of Radicals toward Metal Salts 455 19.2 Radical/Onium Salt Reactivity in Free-Radical-Promoted Cationic Photopolymerization 456 References 459 Conclusion 461 Index 465
Responsibility: Jean-Pierre Fouassier and Jacques Lalevée.

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