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Picosecond Flash Photolysis: Transient Absorption in Sn(IV), Pd(II), and Cu(II) Porphyrins.

Author: Douglas Magde; M W Windsor; D Holten; M Gouterman; WASHINGTON STATE UNIV PULLMAN Dept. of CHEMISTRY.
Publisher: Ft. Belvoir Defense Technical Information Center JUN 1974.
Edition/Format:   Print book : English
Database:WorldCat
Summary:
From picosecond flash photolysis and spectroscopy, the absorption spectra of the first excited singlet S(1) and of the first excited triplet T(1) of (OEP)SnCl2 (Octaethylporphinatotin dichloride) are determined. The triplet quantum yield is determined. Similar S(1) and T(1) phototransient absorption spectra occur in (OEP)Pd. However, two Cu porphyrins show only one phototransient absorption spectrum. T(1) absorption  Read more...
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Document Type: Book
All Authors / Contributors: Douglas Magde; M W Windsor; D Holten; M Gouterman; WASHINGTON STATE UNIV PULLMAN Dept. of CHEMISTRY.
OCLC Number: 227596853
Notes: Prepared in cooperation with Washington Univ., Seattle. Dept. of Chemistry.
Description: 19 pages

Abstract:

From picosecond flash photolysis and spectroscopy, the absorption spectra of the first excited singlet S(1) and of the first excited triplet T(1) of (OEP)SnCl2 (Octaethylporphinatotin dichloride) are determined. The triplet quantum yield is determined. Similar S(1) and T(1) phototransient absorption spectra occur in (OEP)Pd. However, two Cu porphyrins show only one phototransient absorption spectrum. T(1) absorption results are generally consistent with the available earlier spectroscopic studies made with other techniques. (Modified author abstract).

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