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Radiation effects : ESR and ENDOR analysis

Author: Harold C Box
Publisher: New York, New York ; London, England : Academic Press, 1977. ©1977
Edition/Format:   eBook : Document : EnglishView all editions and formats
Summary:
Radiation Effects: ESR and ENDOR Analysis presents an explanation of the biological effects of radiation. The book discusses the characteristics of the electron spin resonance (ESR) and electron-nuclear double resonance (ENDOR) spectra, such as radiation damage and magnetic resonance spectroscopy, g values, hyperfine couplings, and other special effects. The text also describes the radiation effects and damage  Read more...
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Genre/Form: Electronic books
Additional Physical Format: Print version:
Box, Harold C.
Radiation effects : ESR and ENDOR analysis.
New York, New York ; London, England : Academic Press, ©1977
viii, 280 pages
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Harold C Box
ISBN: 9781483216515 1483216519
OCLC Number: 899002108
Description: 1 online resource (289 pages) : illustrations
Contents: Front Cover; Dedication; Radiation Effects: ESR and ENDOR Analysis; Copyright Page; Table of Contents; PREFACE; PART I: CHARACTERISTICS OF ESR AND ENDOR SPECTRA; Chapter 1. Radiation Damage and Magnetic Resonance Spectroscopy; 1-1 Introduction; 1-2 ESR and Radiation Effects; 1-3 ENDOR and Radiation Effects; 1-4 Spectral Parameters; 1-5 Temporal Parameters; 1-6 Objectives of Radiation Research; References; Chapter 2. g Values; 2-1 Introduction; 2-2 Spin Hamiltonian; 2-3 Measurement of g Tensors; 2-4 Origin of the g Shift; 2-5 Free Radical Structure and the g Tensor; References. Chapter 3. Hyperfine Couplings3-1 Introduction; 3-2 The Spin Hamiltonian Revisited; 3-3 Measurement of Hyperfine Couplings; 3-4 Calculation of Hyperfine Tensors; 3-5 Spin Density Distributions; 3-6 The Hückel Approximation; 3-7 The INDO Approximation; References; Chapter 4. Special Effects; 4-1 Excited Triplet States; 4-2 ESR Studies of Triplet States; 4-3 Radical Pairs and Their Triplet State; 4-4 ESR and ENDOR Studies of Radical Pairs; 4-5 Quadrupole Couplings; 4-6 Spin Polarization in Radical Reactions; References; Chapter 5. Experimental Considerations; 5-1 ESR Spectroscopy. 5-2 ENDOR Spectroscopy5-3 Irradiation Techniques; 5-4 G Value Measurements; 5-5 Computer Aids; 5-6 Kinetic Studies; 5-7 Direct and Indirect Effects; References; PART II: RADIATION EFFECTS AND DAMAGE MECHANISMS; Chapter 6. Oxidation Effects; 6-1 Introduction; 6-2 Carboxylic Acids and Amides; 6-3 Amino Acids, Peptides, and Proteins; 6-4 Sulfur Compounds; 6-5 Nucleic Acids and Their Constituents; 6-6 Halogen Compounds; 6-7 Water and Aqueous Systems; References; Chapter 7. Reduction Effects; 7-1 Introduction; 7-2 Carboxylic Acids and Amides; 7-3 Amino Acids, Peptides, and Proteins. 7-4 Sulfur Compounds7-5 Nucleic Acids and their Constituents; 7-6 Trapped Electrons; 7-7 Frozen Aqueous Solutions; 7-8 Miscellaneous Results; References; Chapter 8. Excitations and Photolysis; 8-1 Excitation; 8-2 Homolytic Cleavage; 8-3 Photoionization; 8-4 Photolysis via Intermediates; References; Chapter 9. Secondary Processes; 9-1 Introduction; 9-2 Reactions of Hydrogen Atoms; 9-3 Reactions of Hydroxyl Radicals; 9-4 Electron Transfer; 9-5 Proton Transfer; 9-6 Conformational Changes; 9-7 Abstraction, Transfer, Migration, and Exchange of Hydrogen; 9-8 Radical Addition Reactions. 9-9 Radical Pair FormationReferences; Chapter 10. Overall Mechanisms: Some Examples; 10-1 Introduction; 10-2 Carboxylic Acids; 10-3 Protein Constituents; 10-4 Nucleic Acid Constituents; References; Chapter 11. Perspectives; 11-1 Introduction; 11-2 Sensitization: Oxygen and its Mimics; 11-3 Radiation Sensitization: Halogenated Pyrimidines; 11-4 Radiation Protectors; 11-5 Radiation Damage in Electron Microscopy; 11-6 Photosynthesis; 11-7 Carcinogenesis and Mutagenesis; References; APPENDIXES; Appendix A: Spin Matrices; Appendix B: Van Vleck Perturbation Theory.
Responsibility: Harold C. Box.

Abstract:

Radiation Effects: ESR and ENDOR Analysis presents an explanation of the biological effects of radiation. The book discusses the characteristics of the electron spin resonance (ESR) and electron-nuclear double resonance (ENDOR) spectra, such as radiation damage and magnetic resonance spectroscopy, g values, hyperfine couplings, and other special effects. The text also describes the radiation effects and damage mechanisms; as well as the free radicals produced in the primary oxidative process initiated by ionizing radiation, in the primary reductive process initiated by ionizing radiation, and.

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