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Radical chemistry

Author: M John Perkins
Publisher: New York ; London : Ellis Horwood, 1994.
Series: Ellis Horwood series in organic chemistry.
Edition/Format:   Print book : EnglishView all editions and formats
Summary:

This text explains the methodology and basic ideas of radical chemistry at third year undergraduate level, and shows how these ideas have on the one hand been developed into powerful tools in the  Read more...

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Additional Physical Format: Online version:
Perkins, M. John (Michael John).
Radical chemistry.
New York ; London : Ellis Horwood, 1994
(OCoLC)904161900
Document Type: Book
All Authors / Contributors: M John Perkins
ISBN: 0133209202 9780133209204
OCLC Number: 31608655
Description: x, 182 pages : illustrations ; 24 cm.
Contents: 1. Introduction --
2. Chain reactions and unit steps --
2.2. Bimolecular processes --
2.3. Unimolecular processes --
2.4. An introduction to the kinetics of radical chain reactions --
3. Initiation and some non-chain processes: "free" and "caged" radicals --
3.1. Thermolysis --
3.2. Photolysis --
3.3. Radiolysis --
3.4. Electron transfer and molecule-induced homolysis --
4. An introduction to reactivity and selectivity in radical reactions --
4.2. Halogenation of alkanes --
4.3. Other reactions --
4.4. Stereoelectronic effects --
4.5. Polar influences --
4.6. Steric effects --
4.7. Intra- versus inter-molecular reactions --
4.8. Radical addition versus hydrogen atom transfer --
4.9. Summary --
5. Detection of organic free radicals, and a discussion of their structures --
5.2. ESR spectroscopy --
5.3. ESR and radical structure --
5.4. Spin trapping --
5.5. Electron nuclear double resonance spectroscopy --
5.6. Chemically induced dynamic nuclear polarisation (CIDNP) --
6. Radicals and radical reactions in organic synthesis --
6.2. Chain reactions in synthesis --
6.3. Non-chain processes --
7. Some stereochemical considerations --
8. Radical ions and electron transfer --
9. Some special topics --
9.1. Frontier orbital approach to radical reactivity --
9.2. Radical kinetics and thermodynamics --
9.3. Captodative stabilisation --
9.4. Autoxidation of unsaturated lipids --
9.5. Antioxidants --
9.6. Adamantane matrix studies --
9.7. Thermolysis of dibenzoyl peroxide in benzene --
9.8. Stable-radical effects --
9.9. Radicals from ketone photochemistry --
9.10. Transition-metal ions in radical reactions --
10. Radicals in biology --
10.1. Oxidising radicals --
10.2. Enzyme catalysis mechanisms --
10.3. Spin trapping and spin labelling --
10.4. The enediyne antibiotics --
Appendix: Absolute rate constants of unit steps in radical chemistry.
Series Title: Ellis Horwood series in organic chemistry.
Responsibility: M. John Perkins.

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