skip to content
Reactivity of nitric oxide on copper surfaces : elucidated by direct observation of valence orbitals Preview this item
ClosePreview this item
Checking...

Reactivity of nitric oxide on copper surfaces : elucidated by direct observation of valence orbitals

Author: Akitoshi Shiotari
Publisher: Singapore : Springer, 2017.
Series: Springer theses
Edition/Format:   eBook : Document : EnglishView all editions and formats
Summary:
This book provides microscopic insights into chemical properties of NO on metal surfaces. NO/metal systems have been studied intensively to understand heterogeneous catalysis to detox exhaust NOx gas. The identification and componential analysis of various and mixed chemical species of NO adsorbed onto the surfaces have been significant challenges faced by conventional experimental techniques, such as vibrational  Read more...
Rating:

(not yet rated) 0 with reviews - Be the first.

Subjects
More like this

 

Find a copy online

Links to this item

Find a copy in the library

&AllPage.SpinnerRetrieving; Finding libraries that hold this item...

Details

Genre/Form: Electronic books
Additional Physical Format: Print version:
(OCoLC)978290389
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Akitoshi Shiotari
ISBN: 9789811045820 9811045828
OCLC Number: 990138315
Notes: "Doctoral thesis accepted by Kyoto University, Kyoto, Japan."
Description: 1 online resource (xiii, 129 pages) : illustrations (some color).
Contents: Introduction --
Principles and methods --
Visualization of covalent bonding between NO molecules on Cu(110) --
NO reduction by co-adsorbed water molecules on Cu(110) --
Thermal and electron-induced configuration changes of NO on Cu(110) --
Valence orbitals of high symmetry NO on Cu(001) --
Symmetry correlation between molecular vibrations and valence orbitals: NO/Cu(110) and NO/Cu(001) --
Formation of unique trimer of NO on Cu(111) --
Conclusions --
Appendix: Analysis of tunneling current modified by vibrational excitations.
Series Title: Springer theses
Responsibility: Akitoshi Shiotari.

Abstract:

This book provides microscopic insights into chemical properties of NO on metal surfaces. Exploiting those techniques, the author chemically identified individual NO-related species on the surfaces  Read more...

Reviews

User-contributed reviews
Retrieving GoodReads reviews...
Retrieving DOGObooks reviews...

Tags

Be the first.
Confirm this request

You may have already requested this item. Please select Ok if you would like to proceed with this request anyway.

Linked Data


Primary Entity

<http://www.worldcat.org/oclc/990138315> # Reactivity of nitric oxide on copper surfaces : elucidated by direct observation of valence orbitals
    a schema:MediaObject, schema:CreativeWork, schema:Book ;
    library:oclcnum "990138315" ;
    library:placeOfPublication <http://id.loc.gov/vocabulary/countries/si> ;
    schema:about <http://dewey.info/class/547.04/e23/> ;
    schema:about <http://experiment.worldcat.org/entity/work/data/4140352499#Topic/scanning_tunneling_microscopy> ; # Scanning tunneling microscopy
    schema:about <http://experiment.worldcat.org/entity/work/data/4140352499#Topic/nitric_oxide> ; # Nitric Oxide
    schema:about <http://experiment.worldcat.org/entity/work/data/4140352499#Topic/copper_reactivity> ; # Copper--Reactivity
    schema:about <http://experiment.worldcat.org/entity/work/data/4140352499#Topic/science_chemistry_organic> ; # SCIENCE--Chemistry--Organic
    schema:about <http://experiment.worldcat.org/entity/work/data/4140352499#Topic/nitric_oxide_reactivity> ; # Nitric oxide--Reactivity
    schema:author <http://experiment.worldcat.org/entity/work/data/4140352499#Person/shiotari_akitoshi> ; # Akitoshi Shiotari
    schema:bookFormat schema:EBook ;
    schema:datePublished "2017" ;
    schema:description "Introduction -- Principles and methods -- Visualization of covalent bonding between NO molecules on Cu(110) -- NO reduction by co-adsorbed water molecules on Cu(110) -- Thermal and electron-induced configuration changes of NO on Cu(110) -- Valence orbitals of high symmetry NO on Cu(001) -- Symmetry correlation between molecular vibrations and valence orbitals: NO/Cu(110) and NO/Cu(001) -- Formation of unique trimer of NO on Cu(111) -- Conclusions -- Appendix: Analysis of tunneling current modified by vibrational excitations."@en ;
    schema:description "This book provides microscopic insights into chemical properties of NO on metal surfaces. NO/metal systems have been studied intensively to understand heterogeneous catalysis to detox exhaust NOx gas. The identification and componential analysis of various and mixed chemical species of NO adsorbed onto the surfaces have been significant challenges faced by conventional experimental techniques, such as vibrational spectroscopies. The author investigated "individual" NO molecules on Cu surfaces using low-temperature scanning tunneling microscopy (STM). STM not only provides information on the geometric, electronic, and vibrational properties at the single-molecule level; it is also able to manipulate molecules on surfaces to induce chemical reaction. Exploiting those techniques, the author chemically identified individual NO-related species on the surfaces and discovered new reaction processes for NO reduction, which provides microscopic insights into the catalytic mechanisms. The author also visualized wave functions of electrons in a valence orbital of NO and demonstrated that the wave functions are modified by the formation of covalent bonding or hydrogen bonding. This is, namely, "the visualization of quantum mechanics in real space," which is certainly worth reading. Furthermore, the book demonstrates that direct observation of valence orbitals helps to elucidate the reactivity of molecules adsorbed onto surfaces. This innovative approach to studying molecular properties will contribute to further development of STM and its related methods."@en ;
    schema:exampleOfWork <http://worldcat.org/entity/work/id/4140352499> ;
    schema:genre "Electronic books"@en ;
    schema:inLanguage "en" ;
    schema:isPartOf <http://worldcat.org/issn/2190-5053> ; # Springer theses,
    schema:isSimilarTo <http://www.worldcat.org/oclc/978290389> ;
    schema:name "Reactivity of nitric oxide on copper surfaces : elucidated by direct observation of valence orbitals"@en ;
    schema:productID "990138315" ;
    schema:url <http://library.smu.ca:2048/login?url=http://link.springer.com/10.1007/978-981-10-4582-0> ;
    schema:url <https://grinnell.idm.oclc.org/login?url=http://link.springer.com/10.1007/978-981-10-4582-0> ;
    schema:url <http://link.springer.com/10.1007/978-981-10-4582-0> ;
    schema:url <http://dx.doi.org/10.1007/978-981-10-4582-0> ;
    schema:url <http://public.eblib.com/choice/publicfullrecord.aspx?p=4873452> ;
    schema:url <https://link.springer.com/openurl?genre=book&isbn=978-981-10-4581-3> ;
    schema:url <http://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&db=nlabk&AN=1561388> ;
    schema:workExample <http://dx.doi.org/10.1007/978-981-10-4582-0> ;
    schema:workExample <http://worldcat.org/isbn/9789811045820> ;
    wdrs:describedby <http://www.worldcat.org/title/-/oclc/990138315> ;
    .


Related Entities

<http://experiment.worldcat.org/entity/work/data/4140352499#Person/shiotari_akitoshi> # Akitoshi Shiotari
    a schema:Person ;
    schema:familyName "Shiotari" ;
    schema:givenName "Akitoshi" ;
    schema:name "Akitoshi Shiotari" ;
    .

<http://experiment.worldcat.org/entity/work/data/4140352499#Topic/copper_reactivity> # Copper--Reactivity
    a schema:Intangible ;
    schema:name "Copper--Reactivity"@en ;
    .

<http://experiment.worldcat.org/entity/work/data/4140352499#Topic/nitric_oxide_reactivity> # Nitric oxide--Reactivity
    a schema:Intangible ;
    schema:name "Nitric oxide--Reactivity"@en ;
    .

<http://experiment.worldcat.org/entity/work/data/4140352499#Topic/scanning_tunneling_microscopy> # Scanning tunneling microscopy
    a schema:Intangible ;
    schema:name "Scanning tunneling microscopy"@en ;
    .

<http://experiment.worldcat.org/entity/work/data/4140352499#Topic/science_chemistry_organic> # SCIENCE--Chemistry--Organic
    a schema:Intangible ;
    schema:name "SCIENCE--Chemistry--Organic"@en ;
    .

<http://worldcat.org/isbn/9789811045820>
    a schema:ProductModel ;
    schema:isbn "9811045828" ;
    schema:isbn "9789811045820" ;
    .

<http://worldcat.org/issn/2190-5053> # Springer theses,
    a bgn:PublicationSeries ;
    schema:hasPart <http://www.worldcat.org/oclc/990138315> ; # Reactivity of nitric oxide on copper surfaces : elucidated by direct observation of valence orbitals
    schema:issn "2190-5053" ;
    schema:name "Springer theses," ;
    .

<http://www.worldcat.org/oclc/978290389>
    a schema:CreativeWork ;
    schema:description "Print version:" ;
    schema:isSimilarTo <http://www.worldcat.org/oclc/990138315> ; # Reactivity of nitric oxide on copper surfaces : elucidated by direct observation of valence orbitals
    .

<http://www.worldcat.org/title/-/oclc/990138315>
    a genont:InformationResource, genont:ContentTypeGenericResource ;
    schema:about <http://www.worldcat.org/oclc/990138315> ; # Reactivity of nitric oxide on copper surfaces : elucidated by direct observation of valence orbitals
    schema:dateModified "2018-02-16" ;
    void:inDataset <http://purl.oclc.org/dataset/WorldCat> ;
    .


Content-negotiable representations

Close Window

Please sign in to WorldCat 

Don't have an account? You can easily create a free account.