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Recent advances in hydride chemistry

Author: Maurizio Peruzzini; Rinaldo Poli
Publisher: Amsterdam ; New York : Elsevier Science Ltd., 2001.
Edition/Format:   eBook : Document : English : 1st edView all editions and formats
Summary:
This book has been conceived to collect the most important recent advances in all areas of hydride chemistry research, including chemical reactivity, instrumental investigation, theory, and applications in the areas of catalysis, biochemistry and materials science. Many of the chapters have been written by the plenary lecturers of the EURO-Hydrides 2000 conference, but other leading scientists in this field have  Read more...
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Genre/Form: Electronic books
Additional Physical Format: Print version:
Recent advances in hydride chemistry.
Amsterdam ; New York : Elsevier Science Ltd., 2001
(DLC) 2001054799
(OCoLC)48256496
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Maurizio Peruzzini; Rinaldo Poli
ISBN: 9780444507334 0444507337 9780080540337 0080540333
OCLC Number: 162131237
Description: 1 online resource (xii, 564 pages) : illustrations
Contents: Chapter headings. Non-classical hydrogen bonding along the pathway to the heterolytic splitting of dihydrogen. Protonation of transition metal hydrides to give dihydrogen complexes: mechanistic implications and catalytic applications. Hydrides and hydrogen bonding: combining theory with experiment. Hydridicity of transition metal hydrides and its implications for reactivity. Heterolytic cleavage of dihydrogen by ruthenium and molybdenum complexes. Paramagnetic mono- and polyhydrides of the transition metals. Ruthenium- and osmium- hydride compounds containing triisopropylphosphine as precursors for carbon-carbon and carbon-heteroatom coupling reactions. New trends in organolanthanide hydride chemistry. Dihydrogen metal complexes in catalysis. Mechanistic aspects of dihydrogen activation and catalysis by dinuclear complexes. Mechanistic aspects of inorganic chemistry probed via the parahydrogen phenomenon. NMR relaxation studies of polynuclear hydrides derivatives. Deuterium NMR relaxation as a method for the characterization and study of transition metal hydride systems in solution. Dihydrogen bonded complexes and proton transfer to hydride ligands by spectral (IR, NMR) studies. Quantum mechanical phenomena in dihydrogen and polyhydride transition metal systems: a unified view. Metal hydride intermediates in hydrogenases and nitrogenases: enzymological and model studies. Proton wave functions in palladium studied by ab initio calculations and inelastic neutron scattering methods. Hydrides for hydrogen storage.
Other Titles: Hybrid Chemistry
Responsibility: edited by Maurizio Peruzzini, Rinaldo Poli.
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Abstract:

Collects the important advances in the areas of hydride chemistry research, including chemical reactivity, instrumental investigation, theory, and applications in the areas of catalysis, biochemistry  Read more...

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