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Selective Nanocatalysts and Nanoscience : Concepts for Heterogeneous and Homogeneous Catalysis.

Author: Adriano Zecchina; Silvia Bordiga; Elena Groppo
Publisher: Weinheim : John Wiley & Sons, 2011.
Edition/Format:   eBook : Document : EnglishView all editions and formats
Summary:
A selective catalyst can be considered as a nanomachine designed to perform the synthesis of molecules with high reaction activity and high selectivityThe unique focus on both nanostructured heterogeneous and homogeneous catalysts makes this book an indispensable source for everyone who is interested in nanocatalysisGives an excellent overview about hot topics like nanoparticles, dendrimers, Metal-Organic Frameworks  Read more...
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Genre/Form: Electronic books
Additional Physical Format: Print version:
Zecchina, Adriano.
Selective Nanocatalysts and Nanoscience : Concepts for Heterogeneous and Homogeneous Catalysis.
Weinheim : John Wiley & Sons, ©2011
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Adriano Zecchina; Silvia Bordiga; Elena Groppo
ISBN: 9783527635702 352763570X
OCLC Number: 797919121
Notes: 8.7 Homochiral MOFs Used as Enantioselective Catalysts.
Description: 1 online resource (673 pages)
Contents: Cover; Series page; Title page; Copyright page; Preface; List of Contributors; 1.1 Introduction; 1.2 Definition of Multiple- and Single-Site Centers in Homogeneous and Heterogeneous Catalysis; 1.3 The Characterization Methods in Heterogeneous Catalysis (Including Operando Methods); 1.4 Conclusions; 1 The Structure and Reactivity of Single and Multiple Sites on Heterogeneous and Homogeneous Catalysts: Analogies, Differences, and Challenges for Characterization Methods; 2.1 General Introduction; 2.2 Synthesis of Supported Metal Nanoparticles: Size and Shape Control. 2.3 Selective Catalysis of Supported Metal Nanoparticles2.4 Summary; 2 Supported Nanoparticles and Selective Catalysis: A Surface Science Approach; 3.1 Introduction; 3.2 Nanoparticles vs. Homogeneous Catalysts in C-C Bond-Forming Reactions; 3.3 Nanoparticles vs. Homogeneous Catalysts in Hydrogenation Reactions; 3.4 Platinum-Catalyzed Hydrosilylation; 3.5 Conclusions; 3 When Does Catalysis with Transition Metal Complexes Turn into Catalysis by Nanoparticles?; 4.1 Introduction on Supramolecular Catalysis. 4.2 Compartmentalization of Reactive Species in Synthetic Hosts as Supramolecular Catalysts4.3 Conclusions; 4.4 Outlook; Acknowledgments; 4 Capsules and Cavitands: Synthetic Catalysts of Nanometric Dimension; 5.1 Principles of Overall Water Splitting Using Nanostructured Particulate Photocatalysts; 5.2 Oxide Photocatalysts for Overall Water Splitting; 5.3 Visible Light-Responsive Photocatalysts for Overall Water Splitting; 5.4 Conclusions; 5 Photocatalysts: Nanostructured Photocatalytic Materials for Solar Energy Conversion. 6.1 The Origin of Enantioselectivity in Catalytic Processes: the Nanoscale of Enantioselective Catalysis6.2 Parameters Affecting the Geometry of the Metal Environment; 6.3 Case of Study (1): Bis(oxazoline)-Cu Catalysts for Cyclopropanation; 6.4 Case of Study (2): Catalysts for Diels-Alder Reactions; 6.5 Case of Study (3): Salen-Based Catalysts; 6.6 Case of Study (4): Multifunctional Catalysis; 6.7 Conclusions; 6 Chiral Catalysts; 7.1 Overview of Petrochemical Industry and Refinery Processes; 7.2 Catalysis in the Petrochemical Industry; 7.3 Microporous Materials and Shape Selectivity. 7.4 Selected Examples of Shape-Selective Catalysis by Zeolites/Zeotypes7.5 Summary and Outlook; 7 Selective Catalysts for Petrochemical Industry; 8.1 Introduction; 8.2 Volatile Molecules Coordinated Metal Nodes Acted as Catalytic Centers; 8.3 Coordinatively Unsaturated Metal Nodes Acted as Catalytic Centers; 8.4 Coordinatively Unsaturated Catalytic Metal Ions Exposed in the Pores of MOFs; 8.5 Guest-Accessible Catalytically Functionalized Organic Sites in Porous MOF; 8.6 Nanochannel-Promoted Polymerization of Organic Substrates in Porous MOFs.

Abstract:

Filling a gap in the literature, this book is unique in focusing on both nanostructured heterogeneous and homogeneous catalysts, resulting in an excellent overview of such hot topics as  Read more...

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