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Six-membered transition states in organic synthesis

Author: Jaemoon Yang
Publisher: Hoboken, N.J. : Wiley-Interscience, ©2008.
Edition/Format:   Print book : EnglishView all editions and formats
Summary:
"This book is a definitive guide for furthering readers' understanding of the amazing features of six-membered transition states in stereoselective organic reactions. Comprehensive and logically organized, it: Covers reactions classified in four categories: [3,3]-sigmatropic rearrangements, aldol reactions, metal allylation reactions, and stereoselective reductions; Includes "General Considerations" for each  Read more...
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Material Type: Internet resource
Document Type: Book, Internet Resource
All Authors / Contributors: Jaemoon Yang
ISBN: 9780470178836 0470178833
OCLC Number: 126230993
Description: x, 210 pages : illustrations ; 25 cm
Contents: [3,3]-Sigmatropic rearrangements. Claisen rearrangement ; Johnson-Claisen rearrangement ; Ireland-Claisen rearrangement ; Cope rearrangement ; Anionic oxy-Cope rearrangement ; Aza-Cope-Mannich reaction --
Aldol reactions. Asymmetric syn-Aldol reaction ; Asymmetric anti-Aldol reaction ; Proline-catalyzed asymmetric Aldol reaction --
Metal allylation reactions. Boron allylation reaction ; Silicon allylation reaction --
Stereoselective reductions. Diastereoselective syn-reduction of [beta]-hydroxy ketones ; Diastereoselective anti-reduction of [beta]-hydroxy ketones ; Asymmetric reduction.
Responsibility: Jaemoon Yang.
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Abstract:

This book furthers readers understanding of the amazing features of six-membered transition states in stereoselective organic reactions. Comprehensive and logically organized, it covers reactions  Read more...

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Fifty years ago, Zimmerman and Traxler put forth an audacious suggestion that in a reaction they were studying six of the atoms were oriented in a ring as the two components approached each other. Read more...

 
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    schema:reviewBody ""This book is a definitive guide for furthering readers' understanding of the amazing features of six-membered transition states in stereoselective organic reactions. Comprehensive and logically organized, it: Covers reactions classified in four categories: [3,3]-sigmatropic rearrangements, aldol reactions, metal allylation reactions, and stereoselective reductions; Includes "General Considerations" for each category in which the author presents computational studies that support a proposal of a six-membered state; Provides a thorough discussion of each reaction category, including an introduction and history, a discussion of the corresponding six-membered transition state, and details of synthetic applications in natural product synthesis; Incorporates real-life applications of these transition states to the total syntheses of biologically active natural products; and Covers literature up to 2006, with the original references cited for further study." "This is a premier reference for organic chemists, medicinal chemists, and physical organic chemists and researchers in industries and institutes focusing on fine chemicals, including pharmaceuticals, agriculture/biotech, and polymers/materials. It is also an illuminating text for upper-level undergraduate and graduate students in organic chemistry. The author's primary goal is to assist professors, researchers, and students in proposing reasonable transition states for the description of newly discovered stereoselective reactions."--Jacket." ;
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