skip to content
Supercritical water : a green solvent, properties and uses Preview this item
ClosePreview this item
Checking...

Supercritical water : a green solvent, properties and uses

Author: Y Marcus
Publisher: Hoboken, N.J. : Wiley, 2012.
Edition/Format:   Print book : EnglishView all editions and formats
Database:WorldCat
Summary:
"This is the only book on the market that covers the issue of supercritical water in such a comprehensive way. The book begins with an introduction that defines supercritical fluids in general and supercritical water in particular and relates it to water along the saturation curve"--
Rating:

(not yet rated) 0 with reviews - Be the first.

Subjects
More like this

 

Find a copy in the library

&AllPage.SpinnerRetrieving; Finding libraries that hold this item...

Details

Document Type: Book
All Authors / Contributors: Y Marcus
ISBN: 9780470889473 0470889470
OCLC Number: 769419850
Notes: Includes indexes.
Machine generated contents note: PrefaceList of symbols1. Introduction1.1 Phase diagrams of single fluids1.2 The critical point1.3 Supercritical fluids as solvents1.4 Gaseous and liquid water1.5 Near-critical water1.6 Summary2. Bulk properties of SCW2.1 Equations of state2.2 Thermophysical properties2.3 Electrical and Optical Properties2.4 Transport Properties2.5 Ionic Dissociation of SCW2.6 Properties related to the solvent power of SCW2.7 Summary3. Molecular properties3.1 Structure of SCW obtained by diffraction3.2 Computer simulations of SCW3.3 Spectroscopic studies of SCW3.4 Extent of hydrogen bonding3.5 The dynamics of water molecules in SCW3.5 Summary4. SCW as a 'green' solvent4.1 Solutions of gases in SCW4.2 Solutions of organic substances in SCW4.3 Solutions of Salts and ions in SCW4.4 Binary mixtures of co-solvents with SCW4.5 Summary5. Applications of SCW5.1 Conversion of organic material to fuel5.2 SCWO: Total oxidation of obnoxious and hazardous materials5.3 Uses of SCW in organic synthesis5.4 Uses in powder technology of inorganic substances5.5 Geothermal aspects of SCW5.6 Application of SCW in nuclear reactors5.7 Corrosion problems with SCW5.8 Summary6. Indexes6.1 Author Index6.2 Subject Index.
Description: 202 pages : illustrations ; 24 cm
Contents: Preface ix List of Acronyms and Symbols xiii 1 Introduction 1 1.1 Phase Diagrams of Single Fluids / 1 1.2 The Critical Point / 3 1.3 Supercritical Fluids as Solvents / 5 1.4 Gaseous and Liquid Water / 8 1.5 Near-Critical Water / 15 1.6 Summary / 17 2 Bulk Properties of SCW 22 2.1 Equations of State(EoS) / 22 2.1.1 PVT Data for SCW / 22 2.1.2 Classical Equations of State of SCW / 24 2.1.3 Scaling Equations of State for SCW / 26 2.1.4 EoS of Supercritical Heavy Water / 29 2.2 Thermophysical Properties of SCW / 30 2.2.1 Heat Capacity / 30 2.2.2 Enthalpy and Entropy / 32 2.2.3 Sound Velocity / 34 2.3 Electrical and Optical Properties / 34 2.3.1 Static Relative Permittivity / 34 2.3.2 Electrical Conductivity / 37 2.3.3 Light Refraction / 38 2.4 Transport Properties / 39 2.4.1 Viscosity / 39 2.4.2 Self-Diffusion / 41 2.4.3 Thermal Conductivity / 42 2.5 Ionic Dissociation of SCW / 44 2.6 Properties Related to the Solvent Power of SCW / 47 2.7 Summary / 49 3 Molecular Properties of SCW 57 3.1 Diffraction Studies of SCW Structure / 60 3.1.1 X-Ray Diffraction Studies of SCW Structure / 61 3.1.2 Neutron Diffraction Studies of SCW Structure / 62 3.2 Computer Simulations of SCW / 66 3.2.1 Monte Carlo Simulations / 67 3.2.2 Molecular Dynamics Simulations / 70 3.3 Spectroscopic Studies of SCW / 74 3.3.1 Infrared Absorption Spectroscopy / 74 3.3.2 Raman Scattering Spectroscopy / 77 3.3.3 Nuclear Magnetic Resonance / 79 3.3.4 Dielectric Relaxation Spectroscopy / 82 3.4 The Extent of Hydrogen Bonding in SCW / 83 3.5 The Dynamics of Water Molecules in SCW / 90 3.6 Summary / 92 4 SCW as a Green Solvent 100 4.1 Solutions of Gases in SCW / 101 4.1.1 Phase Equilibria / 101 4.1.2 Interactions in the Solutions / 104 4.2 Solutions of Organic Substances in SCW / 106 4.2.1 Phase Equilibria / 106 4.2.2 Interactions in the Solutions / 111 4.3 Solutions of Salts and Ions in SCW / 115 4.3.1 Solubilities of Salts and Electrolytes / 115 4.3.2 Thermodynamic Properties / 121 4.3.3 Transport Properties / 123 4.3.4 Ion Association in SCW / 129 4.3.5 Ion Hydration in SCW / 134 4.4 Binary Mixtures of Cosolvents with SCW / 138 4.5 Summary / 141 5 Applications of SCW 151 5.1 Conversion of Organic Substances to Fuel / 152 5.1.1 Conversion to Hydrogen and Natural Gas / 152 5.1.2 Conversion to Liquid Fuel / 156 5.2 Supercritical Water Oxidation / 157 5.2.1 General Aspects of SCWO Process / 158 5.2.2 Examples of SCWO Applications / 160 5.3 Uses of SCW in Organic Synthesis / 162 5.4 Uses in Powder Technology of Inorganic Substances / 164 5.5 Geothermal Aspects of SCW / 166 5.6 Application of SCW in Nuclear Reactors / 169 5.7 Corrosion Problems with SCW / 171 5.8 Summary / 174 Author Index 183 Subject Index 199
Responsibility: Yizhak Marcus.
More information:

Abstract:

Drawing from thousands of original research articles, this book focuses on new and emerging applications of supercritical water as a green solvent, including the catalytic conversion of biomass into  Read more...

Reviews

User-contributed reviews
Retrieving GoodReads reviews...
Retrieving DOGObooks reviews...

Tags

Be the first.
Confirm this request

You may have already requested this item. Please select Ok if you would like to proceed with this request anyway.

Linked Data


Primary Entity

<http://www.worldcat.org/oclc/769419850> # Supercritical water : a green solvent, properties and uses
    a schema:Book, schema:CreativeWork ;
   library:oclcnum "769419850" ;
   library:placeOfPublication <http://id.loc.gov/vocabulary/countries/nju> ;
   library:placeOfPublication <http://experiment.worldcat.org/entity/work/data/1074798840#Place/hoboken_n_j> ; # Hoboken, N.J.
   schema:about <http://id.worldcat.org/fast/1125677> ; # Solvents
   schema:about <http://dewey.info/class/541.3482/e23/> ;
   schema:about <http://id.worldcat.org/fast/947645> ; # Green technology
   schema:about <http://experiment.worldcat.org/entity/work/data/1074798840#Topic/science_chemistry_physical_&_theoretical> ; # SCIENCE--Chemistry--Physical & Theoretical
   schema:bookFormat bgn:PrintBook ;
   schema:creator <http://viaf.org/viaf/76404746> ; # Y. Marcus
   schema:datePublished "2012" ;
   schema:description ""This is the only book on the market that covers the issue of supercritical water in such a comprehensive way. The book begins with an introduction that defines supercritical fluids in general and supercritical water in particular and relates it to water along the saturation curve"--"@en ;
   schema:exampleOfWork <http://worldcat.org/entity/work/id/1074798840> ;
   schema:inLanguage "en" ;
   schema:name "Supercritical water : a green solvent, properties and uses"@en ;
   schema:productID "769419850" ;
   schema:publication <http://www.worldcat.org/title/-/oclc/769419850#PublicationEvent/hoboken_n_j_wiley_2012> ;
   schema:publisher <http://experiment.worldcat.org/entity/work/data/1074798840#Agent/wiley> ; # Wiley
   schema:workExample <http://worldcat.org/isbn/9780470889473> ;
   wdrs:describedby <http://www.worldcat.org/title/-/oclc/769419850> ;
    .


Related Entities

<http://experiment.worldcat.org/entity/work/data/1074798840#Topic/science_chemistry_physical_&_theoretical> # SCIENCE--Chemistry--Physical & Theoretical
    a schema:Intangible ;
   schema:name "SCIENCE--Chemistry--Physical & Theoretical"@en ;
    .

<http://id.worldcat.org/fast/1125677> # Solvents
    a schema:Intangible ;
   schema:name "Solvents"@en ;
    .

<http://id.worldcat.org/fast/947645> # Green technology
    a schema:Intangible ;
   schema:name "Green technology"@en ;
    .

<http://viaf.org/viaf/76404746> # Y. Marcus
    a schema:Person ;
   schema:familyName "Marcus" ;
   schema:givenName "Y." ;
   schema:name "Y. Marcus" ;
    .

<http://worldcat.org/isbn/9780470889473>
    a schema:ProductModel ;
   schema:isbn "0470889470" ;
   schema:isbn "9780470889473" ;
    .


Content-negotiable representations

Close Window

Please sign in to WorldCat 

Don't have an account? You can easily create a free account.