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Viscoelastic behavior of rubbery materials

Author: C M Roland
Publisher: Oxford ; New York : Oxford University Press, 2011.
Edition/Format:   Print book : EnglishView all editions and formats
Summary:

The gigantic size of polymer molecules makes them "viscoelastic": their behavior changes depending on how fast and for how long the material is used. This book describes the latest discoveries in the  Read more...

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Document Type: Book
All Authors / Contributors: C M Roland
ISBN: 9780199571574 0199571570
OCLC Number: 701807846
Description: viii, 332 pages : illustrations ; 26 cm
Contents: 1 Introduction 1 --
1.1 Viscoelasticity and high elasticity in polymers 2 --
1.2 Modes of motion 7 --
1.3 yFluctuations and linear response theory 28 --
References 33 --
2 Cooperative local dynamics --
the glass-transition zone 38 --
2.1 Non-exponential and non-Arrhenius behavior 42 --
2.2 Temperature and density effects on Ta 48 --
2.3 Dispersion of relaxation times and dynamic heterogeneity 54 --
2.4 Johari-Goldstein secondary relaxations 60 --
2.5 Decoupling phenomena 65 --
2.6 Applications 69 --
References 72 --
3 Chain dynamics 79 --
3.1 Unentangled polymers 79 --
3.2 Entangled polymers 87 --
3.3 Practical aspects of diffusion 104 --
References 114 --
4 Networks 120 --
4.1 henomenological elasticity models 121 --
4.2 Chain models 128 --
4.3 Constraint models 131 --
4.4 Role of molecular motions in the elastic response 135 --
4.5 lternative network structures 139 --
References 154 --
5 Constitutive modeling, non-linear behavior, and the stress-optic law 160 --
5.1 Linearity and the superposition principle 160 --
5.2 Internal stress and optical birefringence 164 --
5.3 Reversing strain histories 175 --
5.4 Empirical rules for non-linear flow 182 --
5.5 Payne effect 187 --
References 193 --
6 educed variables and characteristic relaxation times 199 --
6.1 Time-temperature superpositioning 199 --
6.2 Thermorheological complexity 207 --
6.3 Density scaling of the dynamics 211 --
6.4 Characteristic relaxation times 227 --
References 232 --
7 Blends 236 --
7.1 Dynamic properties of miscible polymer blends 236 --
7.2 Relaxation models for miscible blends 249 --
7.3 Phase-separated blends 255 --
References 261 --
8 Liquid-crystalline materials 264 --
8.1 Liquid crystals 265 --
8.2 Liquid-crystal elastomers 275 --
References 279 --
9 Bioelastomers 282 --
9.1 Proteins 282 --
9.2 Bioelastomers 284 --
References 295 --
10 Confinement effects on polymer dynamics 298 --
10.1 Spatial confinement 298 --
10.2 Filler effects 306 --
References 315.
Responsibility: C.M. Roland.

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... The result is a very readable presentation of viscoelastic behavior with an emphasis on the phenomenology and an understanding of its molecular basis. * Patrick Ilg, Applied Rheology *

 
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