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| 1 An Overview of Zeolite, Zeotype and Mesoporous Solids Chemistry: Design, Synthesis and Catalytic Properties (Thomas Maschmeyer and Leon van de Water). |
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| 1.1 Zeolites, zeotypes and mesoporous solids: synthetic aspects. |
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| 1.1.2 Synthetic aspects: template theory for zeolite synthesis. |
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| 1.1.3 Synthetic aspects: template theory for mesoporous oxides synthesis. |
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| 1.2 Design of extra-large pore zeolites and other micro- and mesoporous catalysts. |
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| 1.2.2 Extra-large pore zeolites. |
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| 1.2.3 Hierarchical pore architectures: combining micro- and mesoporosity. |
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| 1.3 Potential of post-synthesis functionalized micro- and mesoporous solids as catalysts for fine chemical synthesis. |
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| 1.3.2 Covalent functionalization. |
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| 1.3.3 Noncovalent immobilization approaches. |
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| 1.3.4 Single-site catalysts inspired by natural systems. |
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| 2 Problems and Pitfalls in the Applications of Zeolites and other Microporous and Mesoporous Solids to Catalytic Fine Chemical Synthesis (Michel Guisnet and Matteo Guidotti). |
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| 2.2 Zeolite catalysed organic reactions. |
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| 2.2.1 Fundamental and practical differences with homogeneous reactions. |
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| 2.2.2 Batch mode catalysis. |
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| 2.2.3 Continuous flow mode catalysis. |
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| 2.2.4 Competition for adsorption: influence on reaction rate, stability and selectivity. |
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| 2.2.5 Catalyst deactivation. |
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| 3 Aromatic Acetylation (Michel Guisnet and Matteo Guidotti). |
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| 3.1 Aromatic acetylation. |
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| 3.1.1 Acetylation with Acetic Anhydride. |
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| 3.1.2 Acetylation with Acetic Acid. |
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| 3.2 Procedures and protocols. |
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| 3.2.1 Selective synthesis of acetophenones in batch reactors through acetylation with acetic anhydride. |
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| 3.2.2 Selective synthesis of acetophenones in fixed bed reactors through acetylation with acetic anhydride. |
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| 4 Aromatic Benzoylation (Patrick Geneste and Annie Finiels). |
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| 4.1 Aromatic benzoylation. |
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| 4.1.1 Effect of the zeolite. |
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| 4.1.2 Effect of the acylating agent. |
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| 4.1.3 Effect of the solvent. |
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| 4.1.4 Benzoylation of phenol and the Fries rearrangement. |
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| 4.1.6 Substituent effect. |
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| 4.2 Acylation of anisole over mesoporous aluminosilicates. |
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| 5 Nitration of Aromatic Compounds (Avelino Corma and Sara Iborra). |
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| 5.3 Nitration of aromatic compounds using zeolites as catalysts. |
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| 5.3.1 Nitration in liquid phase. |
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| 5.3.2 Vapour phase nitration. |
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| 6 Oligomerization of Alkenes (Avelino Corma and Sara Iborra). |
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| 6.3 Acid zeolites as catalysts for oligomerization of alkenes. |
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| 6.3.1 Medium pore zeolites: influence of crystal size and acid site density. |
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| 6.3.2 Use of large pore zeolites. |
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| 6.3.3 Catalytic membranes for olefin oligomerization. |
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| 6.4 Mesoporous aluminosilicates as oligomerization catalysts. |
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| 6.5 Nickel supported aluminosilicates as catalysts. |
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| 7 Microporous and Mesoporous Catalysts for the Transformation of Carbohydrates (Claude Moreau). |
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| 7.2 Hydrolysis of sucrose in the presence of H-form zeolites. |
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| 7.3 Hydrolysis of fructose and glucose precursors. |
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| 7.4 Isomerization of glucose into fructose. |
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| 7.5 Dehydration of fructose and fructose-precursors. |
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| 7.6 Dehydration of xylose. |
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| 7.7 Synthesis of alkyl-D-glucosides. |
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| 7.7.1 Synthesis of butyl-D-glucosides. |
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| 7.7.2 Synthesis of long-chain alkyl-D-glucosides. |
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| 7.8 Synthesis of alkyl-D-fructosides. |
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| 7.9 Hydrogenation of glucose. |
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| 7.10 Oxidation of glucose. |
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| 8 One-pot Reactions on Bifunctional Catalysts (Michel Guisnet and Matteo Guidotti). |
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| 8.2.1 One-pot transformations involving successive hydrogenation and acid–base steps. |
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| 8.2.2 One-pot transformations involving successive oxidation and acid–base steps. |
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| 9 Base-type Catalysis (Didier Tichit, Sara Iborra, Avelino Corma and Daniel Brunel). |
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| 9.2 Characterization of solid bases. |
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| 9.2.2 Probe molecules combined with spectroscopic methods. |
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| 9.3 Solid base catalysts. |
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| 9.3.1 Alkaline earth metal oxides. |
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| 9.3.2 Catalysis on alkaline earth metal oxides. |
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| 9.3.3 Hydrotalcites and related compounds. |
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| 9.3.4 Organic base-supported catalysts. |
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| 10 Hybrid Oxidation Catalysts from Immobilized Complexes on Inorganic Microporous Supports (Dirk De Vos, Ive Hermans, Bert Sels and Pierre Jacobs). |
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| 10.1 Introduction and scope. |
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| 10.2 Oxygenation potential of heme-type complexes in zeolite. |
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| 10.2.1 Metallo-phthallocyanines encapsulated in the cages of faujasite-type zeolites. |
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| 10.2.2 Oxygenation potential of metallo-phthallocyanines encapsulated in the mesopores of VPI-5 AlPO4. |
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| 10.2.3 Oxygenation potential of zeolite encapsulated metallo-porphyrins. |
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| 10.3 Oxygenation potential of zeolite encapsulated nonheme complexes. |
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| 10.3.1 Immobilization of N,N0-bidentate complexes in zeolite Y. |
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| 10.3.2 Ligation of zeolite exchanged transition ions with bidentate aza ligands. |
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| 10.3.3 Ligation of zeolite exchanged transition ions with tri- and tetra-aza(cyclo)alkane ligands. |
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| 10.3.4 Ligation of zeolite exchanged transition ions with Schiff base-type ligands. |
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| 10.3.5 Zeolite effects with N,N0-bis(2-pyridinecarboxamide) complexes of Mn and Fe in zeolite Y. |
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| 10.3.6 Zeolite encapsulated chiral oxidation catalysts. |
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