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Bioinspiration and biomimicry in chemistry : reverse-engineering nature

Author: Gerhard F Swiegers
Publisher: Hoboken, N.J. : Wiley, ©2012.
Edition/Format:   Print book : EnglishView all editions and formats

This book reviews and summarizes the many and varied forms of bioinspiration and biomimicry that are found in chemistry, from the crude to the highly sophisticated, from the near-biological to the  Read more...


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Material Type: Internet resource
Document Type: Book, Internet Resource
All Authors / Contributors: Gerhard F Swiegers
ISBN: 9780470566671 0470566671
OCLC Number: 772711834
Notes: Includes index.
Description: xxvii, 480 pages, [16] pages of plates : illustrations (some color) ; 24 cm
Contents: <p>Foreword xvii <p>Jean-Marie Lehn <p>Foreword xix Janine Benyus <p>Preface xxiii <p>Contributors xxv <p>1. Introduction: The Concept of Biomimicry and Bioinspirationin Chemistry 1 Timothy W. Hanks and Gerhard F. Swiegers <p>1.1 What is Biomimicry and Bioinspiration? 1 <p>1.2 Why Seek Inspiration from, or Replicate Biology? 3 <p>1.3 Other Monikers: Bioutilization, Bioextraction,Bioderivation, and Bionics 5 <p>1.4 Biomimicry and Sustainability 5 <p>1.5 Biomimicry and Nanostructure 7 <p>1.6 Bioinspiration and Structural Hierarchies 9 <p>1.7 Bioinspiration and Self-Assembly 11 <p>1.8 Bioinspiration and Function 12 <p>1.9 Future Perspectives: Drawing Inspiration from theComplex <p>System that is Nature 13 <p>References 14 <p>2. Bioinspired Self-Assembly I: Self-Assembled Structures17 Leonard F. Lindoy, Christopher Richardson, and Jack K.Clegg <p>2.1 Introduction 17 <p>2.2 Molecular Clefts, Capsules, and Cages 19 <p>2.3 Enzyme Mimics and Models: The Example of Carbonic Anhydrase28 <p>2.4 Self-Assembled Liposome-Like Systems 30 <p>2.5 Ion Channel Mimics 32 <p>2.6 Base-Pairing Structures 34 <p>2.7 DNA RNA Structures 36 <p>2.8 Bioinspired Frameworks 38 <p>2.9 Conclusion 41 <p>References 41 <p>3. Bioinspired Self-Assembly II: Principles of Cooperativityin Bioinspired Self-Assembling Systems 47 Gianfranco Ercolani and Luca Schiaffino <p>3.1 Introduction 47 <p>3.2 Statistical Factors in Self-Assembly 48 <p>3.3 Allosteric Cooperativity 50 <p>3.4 Effective Molarity 52 <p>3.5 Chelate Cooperativity 55 <p>3.6 Interannular Cooperativity 60 <p>3.7 Stability of an Assembly 62 <p>3.8 Conclusion 67 <p>References 67 <p>4. Bioinspired Molecular Machines 71 Christopher R. Benson, Andrew I. Share, and Amar H.Flood <p>4.1 Introduction 71 <p>4.2 Mechanical Effects in Biological Machines 78 <p>4.3 Theoretical Considerations: Flashing Ratchets 83 <p>4.4 Sliding Machines 86 <p>4.5 Rotary Motors 102 <p>4.6 Moving Larger Scale Objects 104 <p>4.7 Walking Machines 106 <p>4.8 Ingenious Machines 109 <p>4.9 Using Synthetic Bioinspired Machines in Biology 111 <p>4.10 Perspective 111 <p>References 116 <p>5. Bioinspired Materials Chemistry I: Organic InorganicNanocomposites 121 Pilar Aranda, Francisco M. Fernandes, Bernd Wicklein,Eduardo Ruiz-Hitzky, Jonathan P. Hill, and Katsuhiko Ariga <p>5.1 Introduction 121 <p>5.2 Silicate-Based Bionanocomposites as Bioinspired Systems122 <p>5.3 Bionanocomposite Foams 124 <p>5.4 Biomimetic Membranes 126 <p>5.5 Hierarchically Layered Composites 129 <p>5.6 Conclusion 133 <p>References 134 <p>6. Bioinspired Materials Chemistry II: Biomineralization asInspiration for Materials Chemistry 139 Fabio Nudelman and Nico A. J. M. Sommerdijk <p>6.1 Inspiration from Nature 139 <p>6.2 Learning from Nature 144 <p>6.3 Applying Lessons from Nature: Synthesis of Biomimetic andBioinspired Materials 146 <p>6.4 Conclusion 160 <p>References 160 <p>7. Bioinspired Catalysis 165 Gerhard F. Swiegers, Jun Chen, and Pawel Wagner <p>7.1 Introduction 165 <p>7.2 A General Description of the Operation of Catalysts 168 <p>7.3 A Brief History of Our Understanding of the Operation ofEnzymes 169 <p>7.4 Representative Studies of Bioinspired/Biomimetic Catalysts177 <p>7.5 The Relationship Between Enzymatic Catalysis andNonbiological Homogeneous and Heterogeneous Catalysis 192 <p>7.6 Selected High-Performance NonBiological Catalysts thatExploit Nature s Catalytic Principles 193 <p>7.7 Conclusion: The Prospects for Harnessing Nature sCatalytic Principles 203 <p>References 204 <p>8. Biomimetic Amphiphiles and Vesicles 209 Sabine Himmelein and Bart Jan Ravoo <p>8.1 Introduction 209 <p>8.2 Synthetic Amphiphiles as Building Blocks for BiomimeticVesicles 210 <p>8.3 Vesicle Fusion Induced by Molecular Recognition 216 <p>8.4 Stimuli-Responsive Shape Control of Vesicles 224 <p>8.5 Transmembrane Signaling and Chemical Nanoreactors 231 <p>8.6 Toward Higher Complexity: Vesicles with Subcompartments239 <p>8.7 Conclusion 245 <p>References 246 <p>9. Bioinspired Surfaces I: Gecko-Foot Mimetic Adhesion251 Liangti Qu, Yan Li, and Liming Dai <p>9.1 The Hierarchical Structure of Gecko Feet 251 <p>9.2 Origin of Adhesion in Gecko Setae 252 <p>9.3 Structural Requirements for Synthetic Dry Adhesives 253 <p>9.4 Fabrication of Synthetic Dry Adhesives 254 <p>9.5 Outlook 284 <p>References 286 <p>10. Bioinspired Surfaces II: Bioinspired Photonic Materials293 Cun Zhu and Zhong-Ze Gu <p>10.1 Structural Color in Nature: From Phenomena to Origin293 <p>10.2 Bioinspired Photonic Materials 296 <p>10.3 Conclusion and Outlook 317 <p>References 319 <p>11. Biomimetic Principles in Macromolecular Science 323 Wolfgang H. Binder, Marlen Schunack, Florian Herbst, andBhanuprathap Pulamagatta <p>11.1 Introduction 323 <p>11.2 Polymer Synthesis Versus Biopolymer Synthesis 325 <p>11.3 Biomimetic Structural Features in Synthetic Polymers330 <p>11.4 Movement in Polymers 343 <p>11.5 Antibody-Like Binding and Enzyme-Like Catalysis inPolymeric Networks 352 <p>11.6 Self-Healing Polymers 355 <p>References 362 <p>12. Biomimetic Cavities and Bioinspired Receptors 367 <p>Stephane Le Gac, Ivan Jabin, and Olivia Reinaud <p>12.1 Introduction 367 <p>12.2 Mimics of the Michaelis Menten Complexes of Zinc(II)Enzymes with Polyimidazolyl Calixarene-Based Ligands 368 <p>12.3 Combining a Hydrophobic Cavity and A Tren-Based Unit:Design of Tunable, Versatile, but Highly Selective Receptors377 <p>12.4 Self-Assembled Cavities 383 <p>12.5 Conclusion 391 <p>References 392 <p>13. Bioinspired Dendritic Light-Harvesting Systems 397 Andrea M. Della Pelle and Sankaran Thayumanavan <p>13.1 Introduction 397 <p>13.2 Dendrimer Architectures 399 <p>13.3 Electronic Processes in Light-Harvesting Dendrimers 403 <p>13.4 Light-Harvesting Dendrimers in Clean Energy Technologies407 <p>13.5 Conclusion 413 <p>References 414 <p>14. Biomimicry in Organic Synthesis 419 Reinhard W. Hoffmann <p>14.1 Introduction 419 <p>14.2 Biomimetic Synthesis of Natural Products 420 <p>14.3 Biomimetic Reactions in Organic Synthesis 437 <p>14.4 Biomimetic Considerations as an Aid in StructuralAssignment 447 <p>14.5 Reflections on Biomimicry in Organic Synthesis 448 <p>References 450 <p>15. Conclusion and Future Perspectives: Drawing Inspirationfrom the Complex System that Is Nature 455 Clyde W. Cady, David M. Robinson, Paul F. Smith, andGerhard F. Swiegers <p>15.1 Introduction: Nature as a Complex System 455 <p>15.2 Common Features of Complex Systems and the Aims of SystemsChemistry 457 <p>15.3 Examples of Research in Systems Chemistry 460 <p>15.3.1 Self-Replication, Amplification, and <p>15.4 Conclusion: Systems Chemistry may have Implications inOther Fields 468 <p>References 470 <p>Index 473
Responsibility: edited by Gerhard F. Swiegers.


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