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Calixarènes pour la synthèse radiolytique de nanoparticules métalliques

Author: Marie ClémentIsabelle LampreJean-Cyrille HiersoThibaud CoradinMyrtil KahnAll authors
Publisher: 2017.
Dissertation: Thèse de doctorat : Chimie : Université Paris-Saclay (ComUE) : 2017.
Edition/Format:   Computer file : Document : Thesis/dissertation : French
Summary:
Au cours de ces travaux de thèse, la synthèse de différents calix[8]arènes et complexes calixarèniques mono- et bimétalliques a été réalisée, en vue de préparer des nanoparticules par radiolyse. Les différentes étapes de synthèse ont été optimisées et différentes fonctionnalisations ont été testées pour améliorer la solubilité et le greffage des calixarènes à la surface des nanoparticules.
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Genre/Form: Thèses et écrits académiques
Material Type: Document, Thesis/dissertation, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Marie Clément; Isabelle Lampre; Jean-Cyrille Hierso; Thibaud Coradin; Myrtil Kahn; Eddy Dumas; Vincent Huc; Université Paris-Saclay (2015-2019).; École doctorale Sciences chimiques : molécules, matériaux, instrumentation et biosystèmes (Orsay, Essonne / 2015-....).; Institut de chimie physique (Orsay, Essonne / 2000-....).; Laboratoire de Chimie Inorganique (Orsay, Essonne).; Institut de chimie moléculaire et des matériaux d'Orsay (2006-....).; Université Paris-Sud (1970-2019).
OCLC Number: 1024297406
Notes: Titre provenant de l'écran-titre.
Description: 1 online resource
Responsibility: Marie Clément ; sous la direction de Isabelle Lampre.

Abstract:

Au cours de ces travaux de thèse, la synthèse de différents calix[8]arènes et complexes calixarèniques mono- et bimétalliques a été réalisée, en vue de préparer des nanoparticules par radiolyse. Les différentes étapes de synthèse ont été optimisées et différentes fonctionnalisations ont été testées pour améliorer la solubilité et le greffage des calixarènes à la surface des nanoparticules. Les nanoparticules métalliques obtenues à partir de sels d'argent et/ou d'or et stabilisées par les calix[8]arènes dans l'éthanol sont sphériques, très petites et très homogènes en taille (inférieures à 5 nm). Les analyses HAADF/STEM-EDX réalisées sur les nanoparticules Au-Ag ont permis de mettre en évidence le caractère bimétallique de ces nanoparticules et la présence de très petits agrégats de tailles inférieures à 1 nm. Les nanoparticules d'argent synthétisées ont montré leur efficacité en catalyse de réduction de composés nitrés. Ces résultats montrent l'efficacité des calixarènes pour stabiliser de très petites nanoparticules, tout en permettant une activité catalytique. Des nanoparticules mono- et bimétalliques (Au et Au-Ag) ont également été obtenues à partir des complexes calixarèniques par voie radiolytique. Cette voie de synthèse a permis d'augmenter la quantité de métal dans le milieu sans accroître la taille des nanoparticules formées, qui reste de l'ordre de 3-4 nm. Cette particularité peut être liée à la présence d'échanges rapides entre des clusters formés entre les calixarènes et les complexes métalliques précurseurs, mis en évidence par RMN. Toutefois, cette étude mérite d'être poursuivie.

During this thesis, the synthesis of different calix[8]arenes and mono- and bimetallic calixarenic complexes was performed in order to produce nanoparticles by radiolysis. The different steps of the synthesis were optimized and different functionalizations were tested to improve the solubility and the anchoring at the nanoparticles surface. Metallic nanoparticles were generated from silver and/or gold salts and stabilized by calix[8]arenes in ethanol. The obtained spherical nanoparticles were very small (less than 5 nm) and homogeneous in size. HAADF/STEM-EDS analyses performed on Au-Ag nanoparticles revealed their bimetallic character and the presence of very small aggregates of less than 1 nm. Catalyticefficiency of the silver nanoparticles was tested through nitreous compound reduction.These results show the calixarenes efficiency to stabilize small nanoparticles while allowing the catalytic activity. Mono- and bimetallic nanoparticles (Au and Au-Ag) were also synthesized by radiolysis from the calixarenic complexes. This synthetic pathway allowed the increase of the amount of metal used during the synthesis without increasing the size of the obtained nanoparticles (3-4 nm). This particularity can be related to fast exchange phenomena between clusters formed by the calixarenes and the metallic precursors complexes, that were shown by NMR spectroscopy. However, this NMR study needs to be pursued.

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Primary Entity<\/h3>\n
<http:\/\/www.worldcat.org\/oclc\/1024297406<\/a>> # Calixar\u00E8nes pour la synth\u00E8se radiolytique de nanoparticules m\u00E9talliques<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:MediaObject<\/a>, bgn:ComputerFile<\/a>, schema:CreativeWork<\/a>, bgn:Thesis<\/a> ;\u00A0\u00A0\u00A0\nbgn:inSupportOf<\/a> \"Th\u00E8se de doctorat : Chimie : Universit\u00E9 Paris-Saclay (ComUE) : 2017.<\/span>\" ;\u00A0\u00A0\u00A0\nlibrary:oclcnum<\/a> \"1024297406<\/span>\" ;\u00A0\u00A0\u00A0\nlibrary:placeOfPublication<\/a> <http:\/\/id.loc.gov\/vocabulary\/countries\/fr<\/a>> ;\u00A0\u00A0\u00A0\nschema:about<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Thing\/radiolyse<\/a>> ; # Radiolyse<\/span>\n\u00A0\u00A0\u00A0\nschema:about<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Topic\/calixarenes<\/a>> ; # Calixar\u00E8nes<\/span>\n\u00A0\u00A0\u00A0\nschema:about<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Topic\/chimie_sous_rayonnement<\/a>> ; # Chimie sous rayonnement<\/span>\n\u00A0\u00A0\u00A0\nschema:about<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Thing\/or<\/a>> ; # Or<\/span>\n\u00A0\u00A0\u00A0\nschema:about<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Thing\/argent<\/a>> ; # Argent<\/span>\n\u00A0\u00A0\u00A0\nschema:about<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Topic\/alliages_argent_or<\/a>> ; # Alliages argent-or<\/span>\n\u00A0\u00A0\u00A0\nschema:about<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Topic\/nanoparticules<\/a>> ; # Nanoparticules<\/span>\n\u00A0\u00A0\u00A0\nschema:author<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Person\/clement_marie_1991<\/a>> ; # Marie Cl\u00E9ment<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Organization\/universite_paris_saclay_2015_2019<\/a>> ; # Universit\u00E9 Paris-Saclay (2015-2019).<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Person\/hierso_jean_cyrille_1971<\/a>> ; # Jean-Cyrille Hierso<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Person\/lampre_isabelle<\/a>> ; # Isabelle Lampre<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Organization\/ecole_doctorale_sciences_chimiques_molecules_materiaux_instrumentation_et_biosystemes_orsay_essonne_2015<\/a>> ; # \u00C9cole doctorale Sciences chimiques : mol\u00E9cules, mat\u00E9riaux, instrumentation et biosyst\u00E8mes (Orsay, Essonne \/ 2015-....).<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Person\/dumas_eddy_1972<\/a>> ; # Eddy Dumas<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Organization\/universite_paris_sud_1970_2019<\/a>> ; # Universit\u00E9 Paris-Sud (1970-2019).<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Person\/coradin_thibaud<\/a>> ; # Thibaud Coradin<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Organization\/institut_de_chimie_physique_orsay_essonne_2000<\/a>> ; # Institut de chimie physique (Orsay, Essonne \/ 2000-....).<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Person\/huc_vincent<\/a>> ; # Vincent Huc<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Organization\/institut_de_chimie_moleculaire_et_des_materiaux_d_orsay_2006<\/a>> ; # Institut de chimie mol\u00E9culaire et des mat\u00E9riaux d\'Orsay (2006-....).<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Person\/kahn_myrtil<\/a>> ; # Myrtil Kahn<\/span>\n\u00A0\u00A0\u00A0\nschema:contributor<\/a> <http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Organization\/laboratoire_de_chimie_inorganique_orsay_essonne<\/a>> ; # Laboratoire de Chimie Inorganique (Orsay, Essonne).<\/span>\n\u00A0\u00A0\u00A0\nschema:datePublished<\/a> \"2017<\/span>\" ;\u00A0\u00A0\u00A0\nschema:description<\/a> \"Au cours de ces travaux de th\u00E8se, la synth\u00E8se de diff\u00E9rents calix[8]ar\u00E8nes et complexes calixar\u00E8niques mono- et bim\u00E9talliques a \u00E9t\u00E9 r\u00E9alis\u00E9e, en vue de pr\u00E9parer des nanoparticules par radiolyse. Les diff\u00E9rentes \u00E9tapes de synth\u00E8se ont \u00E9t\u00E9 optimis\u00E9es et diff\u00E9rentes fonctionnalisations ont \u00E9t\u00E9 test\u00E9es pour am\u00E9liorer la solubilit\u00E9 et le greffage des calixar\u00E8nes \u00E0 la surface des nanoparticules. Les nanoparticules m\u00E9talliques obtenues \u00E0 partir de sels d\'argent et\/ou d\'or et stabilis\u00E9es par les calix[8]ar\u00E8nes dans l\'\u00E9thanol sont sph\u00E9riques, tr\u00E8s petites et tr\u00E8s homog\u00E8nes en taille (inf\u00E9rieures \u00E0 5 nm). Les analyses HAADF\/STEM-EDX r\u00E9alis\u00E9es sur les nanoparticules Au-Ag ont permis de mettre en \u00E9vidence le caract\u00E8re bim\u00E9tallique de ces nanoparticules et la pr\u00E9sence de tr\u00E8s petits agr\u00E9gats de tailles inf\u00E9rieures \u00E0 1 nm. Les nanoparticules d\'argent synth\u00E9tis\u00E9es ont montr\u00E9 leur efficacit\u00E9 en catalyse de r\u00E9duction de compos\u00E9s nitr\u00E9s. Ces r\u00E9sultats montrent l\'efficacit\u00E9 des calixar\u00E8nes pour stabiliser de tr\u00E8s petites nanoparticules, tout en permettant une activit\u00E9 catalytique. Des nanoparticules mono- et bim\u00E9talliques (Au et Au-Ag) ont \u00E9galement \u00E9t\u00E9 obtenues \u00E0 partir des complexes calixar\u00E8niques par voie radiolytique. Cette voie de synth\u00E8se a permis d\'augmenter la quantit\u00E9 de m\u00E9tal dans le milieu sans accro\u00EEtre la taille des nanoparticules form\u00E9es, qui reste de l\'ordre de 3-4 nm. Cette particularit\u00E9 peut \u00EAtre li\u00E9e \u00E0 la pr\u00E9sence d\'\u00E9changes rapides entre des clusters form\u00E9s entre les calixar\u00E8nes et les complexes m\u00E9talliques pr\u00E9curseurs, mis en \u00E9vidence par RMN. Toutefois, cette \u00E9tude m\u00E9rite d\'\u00EAtre poursuivie.<\/span>\"@fr<\/a> ;\u00A0\u00A0\u00A0\nschema:description<\/a> \"During this thesis, the synthesis of different calix[8]arenes and mono- and bimetallic calixarenic complexes was performed in order to produce nanoparticles by radiolysis. The different steps of the synthesis were optimized and different functionalizations were tested to improve the solubility and the anchoring at the nanoparticles surface. Metallic nanoparticles were generated from silver and\/or gold salts and stabilized by calix[8]arenes in ethanol. The obtained spherical nanoparticles were very small (less than 5 nm) and homogeneous in size. HAADF\/STEM-EDS analyses performed on Au-Ag nanoparticles revealed their bimetallic character and the presence of very small aggregates of less than 1 nm. Catalyticefficiency of the silver nanoparticles was tested through nitreous compound reduction.These results show the calixarenes efficiency to stabilize small nanoparticles while allowing the catalytic activity. Mono- and bimetallic nanoparticles (Au and Au-Ag) were also synthesized by radiolysis from the calixarenic complexes. This synthetic pathway allowed the increase of the amount of metal used during the synthesis without increasing the size of the obtained nanoparticles (3-4 nm). This particularity can be related to fast exchange phenomena between clusters formed by the calixarenes and the metallic precursors complexes, that were shown by NMR spectroscopy. However, this NMR study needs to be pursued.<\/span>\"@fr<\/a> ;\u00A0\u00A0\u00A0\nschema:exampleOfWork<\/a> <http:\/\/worldcat.org\/entity\/work\/id\/4780529780<\/a>> ;\u00A0\u00A0\u00A0\nschema:genre<\/a> \"Th\u00E8ses et \u00E9crits acad\u00E9miques<\/span>\"@fr<\/a> ;\u00A0\u00A0\u00A0\nschema:inLanguage<\/a> \"fr<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Calixar\u00E8nes pour la synth\u00E8se radiolytique de nanoparticules m\u00E9talliques<\/span>\"@fr<\/a> ;\u00A0\u00A0\u00A0\nschema:productID<\/a> \"1024297406<\/span>\" ;\u00A0\u00A0\u00A0\nschema:url<\/a> <http:\/\/www.theses.fr\/2017SACLS449\/document<\/a>> ;\u00A0\u00A0\u00A0\nschema:url<\/a> <https:\/\/tel.archives-ouvertes.fr\/tel-01885500<\/a>> ;\u00A0\u00A0\u00A0\nschema:url<\/a> <http:\/\/www.theses.fr\/2017SACLS449\/abes<\/a>> ;\u00A0\u00A0\u00A0\nwdrs:describedby<\/a> <http:\/\/www.worldcat.org\/title\/-\/oclc\/1024297406<\/a>> ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n\n

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<http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Organization\/ecole_doctorale_sciences_chimiques_molecules_materiaux_instrumentation_et_biosystemes_orsay_essonne_2015<\/a>> # \u00C9cole doctorale Sciences chimiques : mol\u00E9cules, mat\u00E9riaux, instrumentation et biosyst\u00E8mes (Orsay, Essonne \/ 2015-....).<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Organization<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"\u00C9cole doctorale Sciences chimiques : mol\u00E9cules, mat\u00E9riaux, instrumentation et biosyst\u00E8mes (Orsay, Essonne \/ 2015-....).<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Organization\/institut_de_chimie_moleculaire_et_des_materiaux_d_orsay_2006<\/a>> # Institut de chimie mol\u00E9culaire et des mat\u00E9riaux d\'Orsay (2006-....).<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Organization<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Institut de chimie mol\u00E9culaire et des mat\u00E9riaux d\'Orsay (2006-....).<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Organization\/institut_de_chimie_physique_orsay_essonne_2000<\/a>> # Institut de chimie physique (Orsay, Essonne \/ 2000-....).<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Organization<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Institut de chimie physique (Orsay, Essonne \/ 2000-....).<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Organization\/laboratoire_de_chimie_inorganique_orsay_essonne<\/a>> # Laboratoire de Chimie Inorganique (Orsay, Essonne).<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Organization<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Laboratoire de Chimie Inorganique (Orsay, Essonne).<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Organization\/universite_paris_saclay_2015_2019<\/a>> # Universit\u00E9 Paris-Saclay (2015-2019).<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Organization<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Universit\u00E9 Paris-Saclay (2015-2019).<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Organization\/universite_paris_sud_1970_2019<\/a>> # Universit\u00E9 Paris-Sud (1970-2019).<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Organization<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Universit\u00E9 Paris-Sud (1970-2019).<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Person\/clement_marie_1991<\/a>> # Marie Cl\u00E9ment<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Person<\/a> ;\u00A0\u00A0\u00A0\nschema:birthDate<\/a> \"1991<\/span>\" ;\u00A0\u00A0\u00A0\nschema:deathDate<\/a> \"\" ;\u00A0\u00A0\u00A0\nschema:familyName<\/a> \"Cl\u00E9ment<\/span>\" ;\u00A0\u00A0\u00A0\nschema:givenName<\/a> \"Marie<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Marie Cl\u00E9ment<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Person\/coradin_thibaud<\/a>> # Thibaud Coradin<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Person<\/a> ;\u00A0\u00A0\u00A0\nschema:familyName<\/a> \"Coradin<\/span>\" ;\u00A0\u00A0\u00A0\nschema:givenName<\/a> \"Thibaud<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Thibaud Coradin<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Person\/dumas_eddy_1972<\/a>> # Eddy Dumas<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Person<\/a> ;\u00A0\u00A0\u00A0\nschema:birthDate<\/a> \"1972<\/span>\" ;\u00A0\u00A0\u00A0\nschema:deathDate<\/a> \"\" ;\u00A0\u00A0\u00A0\nschema:familyName<\/a> \"Dumas<\/span>\" ;\u00A0\u00A0\u00A0\nschema:givenName<\/a> \"Eddy<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Eddy Dumas<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Person\/hierso_jean_cyrille_1971<\/a>> # Jean-Cyrille Hierso<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Person<\/a> ;\u00A0\u00A0\u00A0\nschema:birthDate<\/a> \"1971<\/span>\" ;\u00A0\u00A0\u00A0\nschema:deathDate<\/a> \"\" ;\u00A0\u00A0\u00A0\nschema:familyName<\/a> \"Hierso<\/span>\" ;\u00A0\u00A0\u00A0\nschema:givenName<\/a> \"Jean-Cyrille<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Jean-Cyrille Hierso<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Person\/huc_vincent<\/a>> # Vincent Huc<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Person<\/a> ;\u00A0\u00A0\u00A0\nschema:familyName<\/a> \"Huc<\/span>\" ;\u00A0\u00A0\u00A0\nschema:givenName<\/a> \"Vincent<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Vincent Huc<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Person\/kahn_myrtil<\/a>> # Myrtil Kahn<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Person<\/a> ;\u00A0\u00A0\u00A0\nschema:familyName<\/a> \"Kahn<\/span>\" ;\u00A0\u00A0\u00A0\nschema:givenName<\/a> \"Myrtil<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Myrtil Kahn<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Person\/lampre_isabelle<\/a>> # Isabelle Lampre<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Person<\/a> ;\u00A0\u00A0\u00A0\nschema:familyName<\/a> \"Lampre<\/span>\" ;\u00A0\u00A0\u00A0\nschema:givenName<\/a> \"Isabelle<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Isabelle Lampre<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Thing\/argent<\/a>> # Argent<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Thing<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Argent<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Thing\/or<\/a>> # Or<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Thing<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Or<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Thing\/radiolyse<\/a>> # Radiolyse<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Thing<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Radiolyse<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Topic\/alliages_argent_or<\/a>> # Alliages argent-or<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Intangible<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Alliages argent-or<\/span>\"@fr<\/a> ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Topic\/calixarenes<\/a>> # Calixar\u00E8nes<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Intangible<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Calixar\u00E8nes<\/span>\"@fr<\/a> ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Topic\/chimie_sous_rayonnement<\/a>> # Chimie sous rayonnement<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Intangible<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Chimie sous rayonnement<\/span>\"@fr<\/a> ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/4780529780#Topic\/nanoparticules<\/a>> # Nanoparticules<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Intangible<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Nanoparticules<\/span>\"@fr<\/a> ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/id.loc.gov\/vocabulary\/countries\/fr<\/a>>\u00A0\u00A0\u00A0\u00A0a \nschema:Place<\/a> ;\u00A0\u00A0\u00A0\ndcterms:identifier<\/a> \"fr<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/www.theses.fr\/2017SACLS449\/document<\/a>>\u00A0\u00A0\u00A0\nrdfs:comment<\/a> \"Acc\u00E8s au texte int\u00E9gral<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/www.worldcat.org\/title\/-\/oclc\/1024297406<\/a>>\u00A0\u00A0\u00A0\u00A0a \ngenont:InformationResource<\/a>, genont:ContentTypeGenericResource<\/a> ;\u00A0\u00A0\u00A0\nschema:about<\/a> <http:\/\/www.worldcat.org\/oclc\/1024297406<\/a>> ; # Calixar\u00E8nes pour la synth\u00E8se radiolytique de nanoparticules m\u00E9talliques<\/span>\n\u00A0\u00A0\u00A0\nschema:dateModified<\/a> \"2020-10-12<\/span>\" ;\u00A0\u00A0\u00A0\nvoid:inDataset<\/a> <http:\/\/purl.oclc.org\/dataset\/WorldCat<\/a>> ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n\n

Content-negotiable representations<\/p>\n