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Catalysis : Concepts and Green Applications.

Author: Gadi Rothenberg
Publisher: Newark : John Wiley & Sons, Incorporated, 2017.
Edition/Format:   eBook : Document : English : 2nd edView all editions and formats
Summary:

After the great success now in its 2nd Edition:This textbook covers all aspects of catalysis, including computational methods, industrial applications and green chemistry.

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Genre/Form: Electronic books
Additional Physical Format: Print version:
Rothenberg, Gadi.
Catalysis : Concepts and Green Applications.
Newark : John Wiley & Sons, Incorporated, ©2017
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Gadi Rothenberg
ISBN: 9783527808885 3527808884
OCLC Number: 1003264868
Notes: 4.2.4 Phase-Transfer Catalysis.
Description: 1 online resource (318 pages)
Contents: Cover; Main title; Copyright page; Contents; Preface; 1 Introduction; 1.1 Green Chemistry and Sustainable Development; 1.1.1 What Is `Green Chemistry'?; 1.1.2 Quantifying Environmental Impact: Efficiency, E-Factors, and Atom Economy; 1.1.3 Just How `Green' Is This Process?; 1.1.4 Product and Process Life-Cycle Assessment (LCA); 1.2 What Is Catalysis and Why Is It Important?; 1.2.1 Homogeneous Catalysis, Heterogeneous Catalysis, and Biocatalysis: Definitions and Examples; 1.2.2 Connecting Catalysis and Sustainability: Saving Resources by Using Catalytic Cycles. 1.2.3 Industrial Example: the BHC Ibuprofen Process1.3 Tools in Catalysis Research; 1.3.1 Catalyst Synthesis and Testing Tools; 1.3.2 Catalyst Characterisation Tools; 1.3.3 Modelling/Mechanistic Studies Tools; 1.4 Exercises; References; Further Reading; 2 The Basics of Catalysis; 2.1 Catalysis Is a Kinetic Phenomenon; 2.1.1 Reaction Rates, Reaction Orders, Rate Equations and Rate-Determining Steps; 2.1.2 The Reaction Profile and the Reaction Coordinate; 2.1.3 Zero-Order, First-Order and Second-Order Kinetics; 2.1.4 Langmuir8211`-Hinshelwood Kinetics; 2.1.5 The Steady-State Approximation. 2.1.6 Michaelis8211`-Menten Kinetics2.1.7 Consecutive and Parallel First-Order Reactions; 2.1.8 Pre-equilibrium, `Catalyst Reservoirs', and Catalyst Precursors; 2.2 Practical Approaches in Kinetic Studies; 2.2.1 Initial Reaction Rates and Concentration Effects; 2.2.2 Creating Pseudo-Order Conditions; 2.2.3 What You See vs. What You Get; 2.2.4 Learning from Stoichiometric Experiments; 2.3 An Overview of Some Basic Concepts in Catalysis; 2.3.1 Catalyst-Substrate Interactions and Sabatier's Principle; 2.3.2 Catalyst Deactivation, Sintering, and Thermal Degradation; 2.3.3 Catalyst Inhibition. 2.4 ExercisesReferences; 3 Homogeneous Catalysis; 3.1 Metal Complex Catalysis in the Liquid Phase; 3.1.1 Elementary Steps in Homogeneous Catalysis; 3.1.2 Structure-Activity Relationships in Homogeneous Catalysis; 3.1.3 Asymmetric Homogeneous Catalysis; 3.1.4 Industrial Examples; 3.2 Homogeneous Catalysis without Metals; 3.2.1 Classic Acid/Base Catalysis; 3.2.2 Organocatalysis; 3.3 Scaling Up Homogeneous Reactions: Pros and Cons; 3.3.1 Catalyst Recovery and Recycling; 3.3.2 Immobilised Complexes and Ship-In-A-Bottle Catalysts; 3.4 `Click Chemistry' and Homogeneous Catalysis; 3.5 Exercises.

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