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Catalytic Hydroarylation of Carbon-Carbon Multiple Bonds.

Author: Lutz Ackermann; T Brent Gunnoe; Laurel Goj Habgood
Publisher: Newark : John Wiley & Sons, Incorporated, 2017.
Edition/Format:   eBook : Document : EnglishView all editions and formats
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Genre/Form: Electronic books
Additional Physical Format: Print version:
Ackermann, Lutz.
Catalytic Hydroarylation of Carbon-Carbon Multiple Bonds.
Newark : John Wiley & Sons, Incorporated, ©2017
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Lutz Ackermann; T Brent Gunnoe; Laurel Goj Habgood
ISBN: 9783527697632 3527697632
OCLC Number: 1007922522
Notes: ""4.6 Formal Hydroarylation Reactions with PdII Catalysts via Heck-Like Mechanisms""
Description: 1 online resource (416 pages)
Contents: ""Cover""; ""Title Page""; ""Copyright""; ""Contents""; ""Introduction and Preface""; ""References""; ""Chapter 1 Functionalization of Heteroaromatic Substrates using Groups 9 and 10 Catalysts""; ""1.1 Introduction""; ""1.2 Thiophenes, furans, and Related Heterocycles""; ""1.3 Pyrroles, Indoles, Pyridines, and Imidazopyridines""; ""1.4 Azoles and Other Miscellaneous Heterocycles""; ""1.5 Summary""; ""References""; ""Chapter 2 Ruthenium Catalysts for the Alkylation of Functionalized Arenes and Heteroaromatic Substrates via Hydroarylation""; ""2.1 Introduction"" ""2.2 Alkylation by Ruthenium(0) Catalysts via Oxidative-Addition C-H Activation""""2.2.1 Alkylation by Ruthenium(II) Catalysts via Carboxylate-Assisted C-H Activation""; ""2.3 Summary and Conclusions""; ""Abbreviations""; ""References""; ""Chapter 3 Alkylation of Arenes Without Chelation Assistance: Transition Metal Catalysts with d6 Electron Configurations""; ""3.1 Transition Metal-Mediated Arene Alkylation: Overview""; ""3.2 Octahedral d6 Transition Metal Catalysts for Olefin Hydroarylation: Scorpionate Supported Ru(II) Catalysts"" ""3.2.1 Structureâ#x80;#x93;Activity Relationships with TpRu(L)(NCMe)Ph: Examination of Elementary Steps and Catalytic Hydrophenylation of Ethylene as a Function of Ligand L""""3.2.2 Ethylene Hydrophenylation Catalyzed by Cationic Ru(II) Complexes Ligated by Poly(pyrazolyl)alkanes""; ""3.3 Olefin Hydroarylation Catalyzed by Octahedral d6 Ir(III) Supported by the Acetylacetonate Ligand""; ""3.3.1 Mechanism of Catalytic Olefin Hydrophenylation using Ir(III) Supported by the Acetylacetonate Ligand""; ""3.3.2 Other d6 Ir(III) Catalysts"" ""3.4 Summary: Comparison of Ru(II) and Ir(III) Catalysts for Olefin Hydroarylation""""3.5 Future Outlook: Extension of Olefin Hydroarylation using Hydrocarbons to Earth Abundant Metals""; ""References""; ""Chapter 4 Hydroarylation of Olefins with Complexes Bearing d8 Metal Centers""; ""4.1 Introduction""; ""4.2 PtII Catalyzed Hydroarylation""; ""4.2.1 PtII Hydroarylation Catalysts Bearing Anionic Bidentate (NN) Ligands""; ""4.2.2 PtII Hydroarylation Catalysts Bearing Neutral Bidentate (NN) Ligands""; ""4.2.3 PtII Hydroarylation Catalysts Supported by Nonnitrogen-based Ligands"" ""4.2.4 Summary of PtII Catalyzed Hydroarylations""""4.3 RhI-Catalyzed Hydroarylation""; ""4.3.1 Reactions of Unfunctionalized Arenes with RhI Complexes Proceeding via Hydroarylation-Like Mechanisms""; ""4.3.2 Directed ortho-Hydroarylation Catalyzed by RhI Complexes""; ""4.3.3 RhI-Catalyzed Hydroarylation with Fluorinated Arenes""; ""4.3.4 Summary of RhI-Catalyzed Hydroarylation""; ""4.4 Directed ortho-Hydroarylation Catalyzed by IrI Complexes""; ""4.5 Hydroarylation with Ni0 Complexes via NiII Intermediates""

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