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Catalytic kinetics : chemistry and engineering

Author: Dmitry Murzin; Tapio Salmi
Publisher: Amsterdam ; Boston : Elsevier, [2016]
Edition/Format:   Print book : English : Second editionView all editions and formats
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Document Type: Book
All Authors / Contributors: Dmitry Murzin; Tapio Salmi
ISBN: 9780444637536 0444637532
OCLC Number: 956738648
Description: xii, 740 pages : illustrations (some color) ; 24 cm
Contents: Machine generated contents note: 1.1. History --
1.2. Catalysis --
1.3. Formal Kinetics --
1.4. Acquisition of Kinetic Data --
1.5. Kinetics and Thermodynamics --
1.6. Examples and Exercises --
Reference --
2.1. Homogeneous Catalysis --
2.2. Heterogeneous Catalysis --
2.3. Organocatalysis --
2.4. Examples and Exercises --
Reference --
3.1. Reaction Rate Theory --
3.2. Elementary Reactions in Solutions --
3.3. Reaction Mechanism --
3.4. Quasi-equilibrium Approximation --
3.5. Relationship Between Thermodynamics and Kinetics --
3.6. Transition State Theory of Surface Reactions --
3.7. Rates of Reactions on Nonideal Surfaces --
3.8. Deterministic and Stochastic Models --
3.9. Microkinetic Modeling --
3.10. Compensation Effect --
3.11. Isotope Effects --
3.12. Examples and Exercises --
References --
4.1. Steady State Kinetics of Complex Reactions --
4.2. Basic Routes of Complex Reactions --
4.3. Single-Route Steady-State Reaction --
4.4. Topological Analysis of Complex Reactions --
4.5. Electrical Analogy of Reaction Networks --
4.6. Thermodynamic Consistency of Rate Constants for Complex Networks --
4.7. Kinetic Aspects of Selectivity --
4.8. Parallel Reactions: Kinetic Coupling --
4.9. Reduction of Complexity --
4.10. Polynomial Kinetics --
4.11. Examples and Exercises --
References --
5.1. Homogeneous Acid-Base Catalysis --
5.2. Nucleophilic Catalysis --
5.3. Catalysis by Metal Ions --
5.4. Catalysis by Organometallic Complexes --
5.5. Organocatalysis --
5.6. Polymerization Catalysis --
5.7. Examples and Exercises --
References --
6.1. Enzymatic Catalysis --
6.2. Cooperative Kinetics --
6.3. Inhibition --
6.4. Effects of pH --
6.5. Single Molecule Enzymology --
6.6. Enantioselectivity in Enzyme Catalyzed Reactions --
6.7. Generalized Rate Laws for Enzymatic Reactions --
6.8. Heterogeneous Systems/Immobilized Enzymes --
6.9. Examples and Exercises --
References --
7.1. Reactions on Ideal Surfaces --
7.2. Reactions on Nonideal Surfaces --
7.3. Selectivity --
7.4. Polyatomic Nature of Reactants and Coverage-Dependent Adsorption Mode --
7.5. Solvent Effects --
7.6. Ionic Species --
7.7. Transfer of Labeled Atoms in Heterogeneous Catalytic Reactions --
7.8. Electrocatalytic Kinetics --
7.9. Photocatalytic Kinetics --
7.10. Nanokinetics --
7.11. Examples and Exercises --
References --
8.1. General --
8.2. Combined Catalytic and Noncatalytic Reactions --
8.3. Multiple Catalysts of the Same Type --
8.4. Multiple Catalysts of Different Types --
8.5. Examples and Exercises --
References --
9.1. Transient Kinetics --
9.2. Relaxation Methods --
9.3. Temperature-Programmed Desorption --
9.4. Oscillations --
9.5. Dynamic Catalyst Changes --
9.6. Examples and Exercises --
References --
10.1. Catalytic Multi-Phase Systems --
10.2. Simultaneous Reaction and Diffusion in Fluid Films and in Porous Materials --
10.3. Liquid-Liquid Diffusion, Phase-Transfer Catalysis --
10.4. Catalytic Two-Phase Systems --
10.5. Mass Transfer and Enzymatic Kinetics --
10.6. External Mass Transfer --
10.7. Internal Diffusion and Selectivity --
10.8. Internal Diffusion and Deactivation --
10.9. Elucidation of the Impact of Mass Transfer --
10.10. Three-Phase Systems --
10.11. Examples and Exercises --
References --
11.1. Basic Principles --
11.2. Heuristic Design of Experiments --
11.3. Parameter Estimation: Classical Methods --
11.4. Parameter Estimation: Regression --
11.5. Numerical Strategies --
11.6. Analysis of Parameters --
11.7. Model Discrimination --
11.8. Software --
11.9. Case Studies --
References.
Responsibility: Dmitry Yu. Murzin and Tapio Salmi.

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