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Contribution to the study of heat relaxation in nanostructures of biological interest

Author: Jordane SoussiSebastian VolzYann ChalopinBruno Le PioufleDavide DonadioAll authors
Publisher: 2015.
Dissertation: Thèse de doctorat : Énergétique : Université Paris-Saclay (ComUE) : 2015.
Edition/Format:   Computer file : Document : Thesis/dissertation : English
Summary:
En médecine, les nanotechnologies permettent le développement de nouvelles techniques de soin comme l'hyperthermie local ou la délivrance ciblée de médicaments. Ces applications impliquent de nouveaux défis scientifiques concernant la conception de nanosystems et les propriétés de leur environnement biologique. Dans cette thèse, nous avons analysé plusieurs aspects de la relaxation thermique de tels
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Genre/Form: Thèses et écrits académiques
Material Type: Document, Thesis/dissertation, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Jordane Soussi; Sebastian Volz; Yann Chalopin; Bruno Le Pioufle; Davide Donadio; Florence Gazeau, membre du jury d'une thèse de doctorat en immunologie).; Robert Pansu; Université Paris-Saclay (2015-2019).; École doctorale Sciences mécaniques et énergétiques, matériaux et géosciences (Gif-sur-Yvette, Essonne / 2015-....).; CentraleSupélec (2015-....).; Laboratoire d'énergétique moléculaire et macroscopique, combustion (Gif-sur-Yvette, Essonne).
OCLC Number: 934769285
Notes: Titre provenant de l'écran-titre.
Description: 1 online resource
Responsibility: Jordane Soussi ; sous la direction de Sebastian Volz et de Yann Chalopin.

Abstract:

En médecine, les nanotechnologies permettent le développement de nouvelles techniques de soin comme l'hyperthermie local ou la délivrance ciblée de médicaments. Ces applications impliquent de nouveaux défis scientifiques concernant la conception de nanosystems et les propriétés de leur environnement biologique. Dans cette thèse, nous avons analysé plusieurs aspects de la relaxation thermique de tels systèmes. Nous avons mise en œuvre la fois des simulations de Dynamique Moléculaire et des mesures expérimentales de microscopie d'imagerie en temps de vie de fluorescence. Nous présentons une étude numérique du transfert thermique depuis une nanoparticule en solution aqueuse et montrons qu'attacher un polymère à sa surface permet de réduire la résistance thermique entre la particule et son environnement. Nous avons modélisé des bicouches lipidiques pour calculer leurs propriétés diélectriques et leur viscosité a été étudiée par microscopie de fluorescence. Ces expériences sont réalisées sur des membranes suspendues et des vésicules unilamellaires géantes et démontrent que la viscosité des bicouches lipidiques diminue avec la température et l'application d'une tension transmembranaire induisant un changement de structure.

In medicine, nanotechnologies give the opportunity to create new care practices such as local hyperthermia and targeted drug delivery. These applications imply new scientific challenges concerning the design of nanodevices and the properties of their biological environment. In this thesis, we have analysed several aspects of heat relaxation of such systems. We have used both Molecular Dynamics numerical simulations and Fluorescence-lifetime imaging microscopy experiments. We present a study of heat transfer from a solvated nanoparticle and show that attaching a polymer on its surface reduces the thermal resistance between the particle and its aqueous environment. We have modelled lipid bilayers to compute their dielectric properties and their viscosity have been investigated by fluorescence imaging. The experiments conducted on both suspended lipid membrane and giant unilamellar vesicles show that the viscosity decreases when the temperature increases and when a transmembrane voltage is applied to inducing a structural change.

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Ces exp\u00E9riences sont r\u00E9alis\u00E9es sur des membranes suspendues et des v\u00E9sicules unilamellaires g\u00E9antes et d\u00E9montrent que la viscosit\u00E9 des bicouches lipidiques diminue avec la temp\u00E9rature et l\'application d\'une tension transmembranaire induisant un changement de structure.<\/span>\" ;\u00A0\u00A0\u00A0\nschema:description<\/a> \"In medicine, nanotechnologies give the opportunity to create new care practices such as local hyperthermia and targeted drug delivery. These applications imply new scientific challenges concerning the design of nanodevices and the properties of their biological environment. In this thesis, we have analysed several aspects of heat relaxation of such systems. We have used both Molecular Dynamics numerical simulations and Fluorescence-lifetime imaging microscopy experiments. We present a study of heat transfer from a solvated nanoparticle and show that attaching a polymer on its surface reduces the thermal resistance between the particle and its aqueous environment. We have modelled lipid bilayers to compute their dielectric properties and their viscosity have been investigated by fluorescence imaging. 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<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2881721394#Organization\/universite_paris_saclay_2015_2019<\/a>> # Universit\u00E9 Paris-Saclay (2015-2019).<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Organization<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Universit\u00E9 Paris-Saclay (2015-2019).<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2881721394#Person\/chalopin_yann_1981<\/a>> # Yann Chalopin<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Person<\/a> ;\u00A0\u00A0\u00A0\nschema:birthDate<\/a> \"1981<\/span>\" ;\u00A0\u00A0\u00A0\nschema:deathDate<\/a> \"\" ;\u00A0\u00A0\u00A0\nschema:familyName<\/a> \"Chalopin<\/span>\" ;\u00A0\u00A0\u00A0\nschema:givenName<\/a> \"Yann<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Yann Chalopin<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
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<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2881721394#Person\/le_pioufle_bruno<\/a>> # Bruno Le Pioufle<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Person<\/a> ;\u00A0\u00A0\u00A0\nschema:familyName<\/a> \"Le Pioufle<\/span>\" ;\u00A0\u00A0\u00A0\nschema:givenName<\/a> \"Bruno<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Bruno Le Pioufle<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2881721394#Person\/pansu_robert_1958<\/a>> # Robert Pansu<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Person<\/a> ;\u00A0\u00A0\u00A0\nschema:birthDate<\/a> \"1958<\/span>\" ;\u00A0\u00A0\u00A0\nschema:deathDate<\/a> \"\" ;\u00A0\u00A0\u00A0\nschema:familyName<\/a> \"Pansu<\/span>\" ;\u00A0\u00A0\u00A0\nschema:givenName<\/a> \"Robert<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Robert Pansu<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2881721394#Person\/soussi_jordane_1989<\/a>> # Jordane Soussi<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Person<\/a> ;\u00A0\u00A0\u00A0\nschema:birthDate<\/a> \"1989<\/span>\" ;\u00A0\u00A0\u00A0\nschema:deathDate<\/a> \"\" ;\u00A0\u00A0\u00A0\nschema:familyName<\/a> \"Soussi<\/span>\" ;\u00A0\u00A0\u00A0\nschema:givenName<\/a> \"Jordane<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Jordane Soussi<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2881721394#Person\/volz_sebastian<\/a>> # Sebastian Volz<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Person<\/a> ;\u00A0\u00A0\u00A0\nschema:familyName<\/a> \"Volz<\/span>\" ;\u00A0\u00A0\u00A0\nschema:givenName<\/a> \"Sebastian<\/span>\" ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Sebastian Volz<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
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<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2881721394#Thing\/matiere_molle<\/a>> # Mati\u00E8re molle<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Thing<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Mati\u00E8re molle<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2881721394#Thing\/microscopie_de_fluorescence<\/a>> # Microscopie de fluorescence<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Thing<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Microscopie de fluorescence<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2881721394#Thing\/nanosciences<\/a>> # Nanosciences<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Thing<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Nanosciences<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2881721394#Thing\/transfert_thermique<\/a>> # Transfert thermique<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Thing<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Transfert thermique<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2881721394#Thing\/transition_de_phase<\/a>> # Transition de phase<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Thing<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Transition de phase<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2881721394#Topic\/matiere_molle_physique<\/a>> # Mati\u00E8re molle (physique)<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Intangible<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Mati\u00E8re molle (physique)<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2881721394#Topic\/nanotechnologie<\/a>> # Nanotechnologie<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Intangible<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Nanotechnologie<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/experiment.worldcat.org\/entity\/work\/data\/2881721394#Topic\/thermique<\/a>> # Thermique<\/span>\n\u00A0\u00A0\u00A0\u00A0a \nschema:Intangible<\/a> ;\u00A0\u00A0\u00A0\nschema:name<\/a> \"Thermique<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/id.loc.gov\/vocabulary\/countries\/fr<\/a>>\u00A0\u00A0\u00A0\u00A0a \nschema:Place<\/a> ;\u00A0\u00A0\u00A0\ndcterms:identifier<\/a> \"fr<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/www.theses.fr\/2015SACLC013\/document<\/a>>\u00A0\u00A0\u00A0\nrdfs:comment<\/a> \"Acc\u00E8s au texte int\u00E9gral<\/span>\" ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n
<http:\/\/www.worldcat.org\/title\/-\/oclc\/934769285<\/a>>\u00A0\u00A0\u00A0\u00A0a \ngenont:InformationResource<\/a>, genont:ContentTypeGenericResource<\/a> ;\u00A0\u00A0\u00A0\nschema:about<\/a> <http:\/\/www.worldcat.org\/oclc\/934769285<\/a>> ; # Contribution to the study of heat relaxation in nanostructures of biological interest<\/span>\n\u00A0\u00A0\u00A0\nschema:dateModified<\/a> \"2020-06-15<\/span>\" ;\u00A0\u00A0\u00A0\nvoid:inDataset<\/a> <http:\/\/purl.oclc.org\/dataset\/WorldCat<\/a>> ;\u00A0\u00A0\u00A0\u00A0.\n\n\n<\/div>\n\n

Content-negotiable representations<\/p>\n