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Crystalline Molecular Complexes and Compounds : Structures and Principles.

Author: Frank H Herbstein
Publisher: Oxford : Oxford University Press, 2005.
Series: International Union of Crystallography monographs on crystallography.
Edition/Format:   eBook : Document : EnglishView all editions and formats
Summary:
This book provides a comprehensive and unified account of the structure and properties of crystalline binary adducts. Perhaps better known as molecular complexes and compounds, these crystals are currently estimated (from molecular recognition studies) to make up one quarter of the world's crystals, providing evidence for some sort of special attraction between the two components. DNA is perhaps the most famous  Read more...
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Genre/Form: Electronic books
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Frank H Herbstein
ISBN: 1280753919 9781280753916 9786610753918 6610753911 0191523577 9780191523571 1429421770 9781429421775 9780191712142 0191712140
OCLC Number: 1059034377
Language Note: English.
Notes: 10.3 The (stereoisomeric) components are enantiomers.
Description: 1 online resource (1310 pages).
Contents: PART I: SOME PRELIMINARIES; 1 Structural principles in the classification of binary adducts; 1.1 Introduction; 1.2 Structural classification of binary adducts; 1.3 Other classifications; 1.4 How many binary adducts are there?; 1.5 Organic and inorganic supramolecular chemistry; References; 2 Historical outline; References; PART II: MOIETIES WITHIN MOLECULES; Introduction to Part II; 3 The enclosure species --
crown ethers, cryptands and related molecules --
as hosts; 3.1 Introduction; 3.2 Doubly bridged cyclophanes and analogous molecules as hosts for intramolecular guests. 5.3 Crystal chemistry of oligonucleotides and oligonucleotide-guest structures5.4 Intercalated hexanucleotide-drug complexes with B-DNA structures; 5.5 Isomorphism and polymorphism of A-DNA octanucleotides and the binding of spermine; 5.6 Minor groove binders; 5.7 General survey of the crystal chemistry of oligonucleotide and oligonucleotide-drug complexes; References; PART III: HOST-GUEST INCLUSION COMPLEXES; Introduction to Part III; 6 Tunnel inclusion complexes formed by hosts of lesser versatility; 6.1 Introduction; 6.2 Tunnel inclusion complexes with directionally bonded hosts. 6.3 Tunnel inclusion complexes with van der Waals bonded hosts6.4 Comparison of the various types of tunnel inclusion complexes; References; 7 Clathrate inclusion complexes formed by hosts of lesser versatility; 7.1 Introduction; 7.2 Directionally bonded hosts; 7.3 Hosts with a combination of directional bonds and van der Waals interactions; 7.4 Van der Waals linked hosts; 7.5 Hexahosts and related compounds; 7.6 Conclusions and a perspective view; References; 8 Inclusion complexes formed by versatile hosts; 8.1 Introduction; 8.2 Tri-o-thymotide and analogs as hosts. 8.3 Trimesic acid and analogs as hosts8.4 The Heilbron complexes; 8.5 Gossypol and its inclusion complexes; 8.6 Tris(5-acetyl-3-thienyl)methane (TATM) as host; 8.7 (5,10,15,20)-Tetraphenylmetalloporphyrins and complexes; References; 9 Intercalation complexes; 9.1 Introduction; 9.2 Intercalation complexes of graphite (GICs); 9.3 Intercalation complexes of inorganic hosts; 9.4 Concluding summary; References; PART IV: PACKING COMPLEXES; Introduction to Part IV; 10 Packing complexes; 10.1 Introduction; 10.2 Components are isomers of various types.
Series Title: International Union of Crystallography monographs on crystallography.
Other Titles: International Union of Crystallography Monographs on Crystallography
IUCr monographs on crystallography vol. 18

Abstract:

This book provides a comprehensive and unified account of the structure and properties of crystalline binary adducts. Such crystals are perhaps better known as molecular compounds and complexes and  Read more...

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'This work is an absolute "must purchase" for every chemical crystallography laboratory. The study of intermolecular assemblies and forces is probably now the number one topic in crystal chemistry Read more...

 
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