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Double photoionisation spectra of molecules

Author: John H D Eland; Raimund Feifel
Publisher: Oxford, United Kingdom : Oxford University Press, 2018. ©2018
Edition/Format:   eBook : Document : English : First editionView all editions and formats
Summary:
This first-ever compendium of double photoionisation spectra covers 70 of the most important small and medium sized molecules. It provides an essential starting point to study the consequences of ionisation by high energy photons and gives a complete non-mathematical description of all the phenomena and pathways in molecular double photoionisation.
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Genre/Form: Electronic books
Additional Physical Format: Print version:
Eland, John H.D., 1941-
Double photoionisation spectra of molecules.
Oxford, United Kingdom : Oxford University Press, 2018
(OCoLC)1022138318
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: John H D Eland; Raimund Feifel
ISBN: 9780191830983 0191830984 9780191093371 0191093378
OCLC Number: 1029252090
Description: 1 online resource
Contents: Cover; Contents; Preface; Acknowledgements; Archive of digital spectra; Introduction; 1 Basis of the TOF-PEPECO technique; 2 Other techniques for spectra of doubly charged ions; 3 Ionisation energies; 4 Orbital configurations and dication states; 5 Ionisation pathways and their effects; 6 How TOF-PEPECO experiments are done; 6.1 Light sources; 6.2 The magnetic bottle TOF spectrometer; 7 Order and format of the spectra; 1 Atomic xenon, Xe; 2 Diatomic molecules; 2.1 Hydrogen bromide, HBr; 2.2 Hydrogen iodide, HI; 2.3 Nitrogen, N2; 2.4 Carbon monoxide, CO; 2.5 Nitric oxide, NO; 2.6 Oxygen, O2 2.7 Bromine, Br22.8 Iodine monochloride, ICl; 2.9 Iodine, I2; 3 Triatomic molecules; 3.1 Water, H2O; 3.2 Hydrogen sulphide, H2S; 3.3 Hydrogen cyanide, HCN; 3.4 Carbon dioxide, CO2; 3.5 Nitrous oxide, N2O; 3.6 Carbonyl sulphide, OCS; 3.7 Carbon disulphide, CS2; 3.8 Bromine and iodine cyanides, BrCN and ICN; 3.9 Mercuric chloride, HgCl2; 3.10 Nitrogen dioxide, NO2; 3.11 Sulphur dioxide, SO2; 4 Molecules with four, five or seven atoms; 4.1 Ammonia, NH3; 4.2 Acetylene (ethyne), C2H2; 4.3 Formaldehyde (methanal), H2CO; 4.4 Cyanogen, C2N2; 4.5 Phosphorus trichloride, PCl3; 4.6 Methane, CH4 4.7 Methyl halides (monohalomethanes), CH3F, CH3Cl, CH3I4.8 Methylene halides (dihalomethanes), CH2Cl2, CH2Br2, CH2I2; 4.9 Carbon tetrahalides, CF4, CCl4, CBr4; 4.10 Germane and germanium halides, GeH4, GeCl4, GeBr4; 4.11 Sulphur hexafluoride, SF6; 5 Conjugated and aromatic molecules; 5.1 Ethylene (ethene), C2H4; 5.2 Butadiene (trans-buta-1,3-diene), C4H6; 5.3 Five-membered rings: pyrrole, furan and thiophene; 5.4 Benzene, C6H6; 5.5 Hexafluorobenzene, C6F6 and toluene, C6H5-CH3; 5.6 Pyridine, C5H5N and the three diazines, C4H4N2; 5.7 Naphthalene and azulene, C10H8 5.8 Quinoline, C9H7N and biphenyl, C12H105.9 Molecules with very low ionisation energies; 6 Mainly aliphatic molecules; 6.1 Monoiodides, CnH2n + 1I; 6.2 Aliphatic alcohols, CnH2n + 1OH; 6.3 Acetonitrile, CH3CN and methyl mercaptan, CH3SH; 6.4 Acetaldehyde, CH3CHO and acetone, CH3COCH3; 6.5 Three larger molecules; 7 Core-core and core-valence double ionisation; 7.1 Core-core double ionisation; 7.1.1 Single-site double core holes in 1s shells; 7.1.2 Single-site double core holes in 2p and other shells; 7.1.3 Two-site double core holes; 7.2 Core-valence double ionisation; generalities 7.3 Core-valence spectrum of ammonia, NH37.4 Core-valence spectra of carbon monoxide, CO; 7.5 Core-valence spectra of CO2, OCS and CS2; 7.6 Core-valence spectra of CF4; 7.7 Core-valence spectra of Si(CH3)4; 7.8 Core-valence spectrum of C6H6; 7.9 Core-valence spectrum of fullerene, C60; Appendix 1 Mechanisms of double photoionisation; Appendix 2 Useful data for calibration; Appendix 3 Theoretical calculation of ionisation energies and spectra; Index
Responsibility: John H.D. Eland and Raimund Feifel.

Abstract:

This first-ever compendium of double photoionisation spectra covers 70 of the most important small and medium sized molecules. It provides an essential starting point to study the consequences of  Read more...

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This book is clear and well illustrated, with ample references. The result is a masterful glimpse into a relatively unknown world. * A.E. Viste, CHOICE *

 
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