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Engineering and chemical thermodynamics

Author: Milo D Koretsky
Publisher: Hoboken, NJ : Wiley, [2013]
Edition/Format:   Print book : English : 2nd editionView all editions and formats
Database:WorldCat
Summary:

Chemical engineers face the challenge of learning the difficult concept and application of entropy and the 2nd Law of Thermodynamics. By following a visual approach and offering qualitative  Read more...

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Additional Physical Format: Online version:
Koretsky, Milo D.
Engineering and chemical thermodynamics.
Hoboken, NJ : John Wiley & Sons, Inc., [2013]
(DLC) 2013002211
Document Type: Book
All Authors / Contributors: Milo D Koretsky
ISBN: 9780470259610 0470259612
OCLC Number: 768071719
Description: xiv, 690 pages : illustrations ; 27 cm
Contents: <p>CHAPTER 1 Measured Thermodynamic Properties and Other BasicConcepts 1 <p>Learning Objectives 1 <p>1.1 Thermodynamics 2 <p>1.2 Preliminary Concepts The Language of Thermo 3 <p>1.3 Measured Thermodynamic Properties 7 <p>1.4 Equilibrium 15 <p>1.6 The PvT Surface and Its Projections for PureSubstances 20 <p>1.7 Thermodynamic Property Tables 26 <p>1.8 Summary 30 <p>1.9 Problems 31 <p>Conceptual Problems 31 <p>Numerical Problems 34 <p>CHAPTER 2 The First Law of Thermodynamics 36 <p>Learning Objectives 36 <p>2.1 The First Law of Thermodynamics 37 <p>2.2 Construction of Hypothetical Paths 46 <p>2.3 Reversible and Irreversible Processes 48 <p>2.4 The First Law of Thermodynamics for Closed Systems 55 <p>2.5 The First Law of Thermodynamics for Open Systems 60 <p>2.6 Thermochemical Data For U and H 67 <p>2.7 Reversible Processes in Closed Systems 92 <p>2.8 Open-System Energy Balances on Process Equipment 95 <p>2.9 Thermodynamic Cycles and the Carnot Cycle 102 <p>2.10 Summary 108 <p>2.11 Problems 110 <p>Conceptual Problems 110 <p>Numerical Problems 113 <p>CHAPTER 3 Entropy and the Second Law Of Thermodynamics127 <p>Learning Objectives 127 <p>3.1 Directionality of Processes/Spontaneity 128 <p>3.2 Reversible and Irreversible Processes (Revisited) and theirRelationship to Directionality 129 <p>3.3 Entropy, the Thermodynamic Property 131 <p>3.4 The Second Law of Thermodynamics 140 <p>3.5 Other Common Statements of the Second Law of Thermodynamics142 <p>3.6 The Second Law of Thermodynamics for Closed and Open Systems143 <p>3.7 Calculation of Ds for an Ideal Gas 151 <p>3.8 The Mechanical Energy Balance and the Bernoulli Equation160 <p>3.9 Vapor-Compression Power and Refrigeration Cycles 164 <p>3.10 Exergy (Availability) Analysis 172 <p>3.11 Molecular View of Entropy 182 <p>3.12 Summary 190 <p>3.13 Problems 191 <p>Conceptual Problems 191 <p>Numerical Problems 195 <p>CHAPTER 4 Equations of State and Intermolecular Forces209 <p>Learning Objectives 209 <p>4.1 Introduction 210 <p>4.2 Intermolecular Forces 211 <p>4.3 Equations of State 232 <p>4.4 Generalized Compressibility Charts 246 <p>4.5 Determination of Parameters for Mixtures 249 <p>4.6 Summary 254 <p>4.7 Problems 255 <p>Conceptual Problems 255 <p>Numerical Problems 257 <p>CHAPTER 5 The Thermodynamic Web 265 <p>Learning Objectives 265 <p>5.1 Types of Thermodynamic Properties 265 <p>5.2 Thermodynamic Property Relationships 267 <p>5.3 Calculation of Fundamental and Derived Properties UsingEquations of State and Other Measured Quantities 276 <p>5.4 Departure Functions 290 <p>5.5 Joule-Thomson Expansion and Liquefaction 298 <p>5.6 Summary 304 <p>5.7 Problems 305 <p>Conceptual Problems 305 <p>Numerical Problems 307 <p>CHAPTER 6 Phase Equilibria I: Problem Formulation 315 <p>Learning Objectives 315 <p>6.1 Introduction 315 <p>6.2 Pure Species Phase Equilibrium 318 <p>6.3 Thermodynamics of Mixtures 334 <p>6.4 Multicomponent Phase Equilibria 367 <p>6.5 Summary 372 <p>6.6 Problems 373 <p>Conceptual Problems 373 <p>Numerical Problems 377 <p>CHAPTER 7 Phase Equilibria II: Fugacity 391 <p>Learning Objectives 391 <p>7.1 Introduction 391 <p>7.2 The Fugacity 392 <p>7.3 Fugacity in the Vapor Phase 396 <p>7.4 Fugacity in the Liquid Phase 414 <p>7.5 Fugacity in the Solid Phase 449 <p>7.6 Summary 450 <p>7.7 Problems 452 <p>Conceptual Problems 452 <p>Numerical Problems 454 <p>CHAPTER 8 Phase Equilibria III: Applications 466 <p>Learning Objectives 466 <p>8.1 Vapor Liquid Equilibrium (VLE) 467 <p>8.2 Liquid 1a2 Liquid 1b2 Equilibrium: LLE 511 <p>8.3 Vapor Liquid 1a2 Liquid 1b2 Equilibrium: VLLE519 <p>8.4 Solid Liquid and Solid Solid Equilibrium: SLEand SSE 523 <p>8.5 Colligative Properties 531 <p>8.6 Summary 538 <p>8.7 Problems 540 <p>Conceptual Problems 540 <p>Numerical Problems 544 <p>CHAPTER 9 Chemical Reaction Equilibria 562 <p>Learning Objectives 562 <p>9.1 Thermodynamics and Kinetics 563 <p>9.2 Chemical Reaction and Gibbs Energy 565 <p>9.3 Equilibrium for a Single Reaction 568 <p>9.4 Calculation of K from Thermochemical Data 572 <p>9.5 Relationship Between the Equilibrium Constant and theConcentrations of Reacting Species 579 <p>9.6 Equilibrium in Electrochemical Systems 589 <p>9.7 Multiple Reactions 599 <p>9.8 Reaction Equilibria of Point Defects in Crystalline Solids612 <p>9.9 Summary 624 <p>9.10 Problems 626 <p>Conceptual Problems 626 <p>Numerical Problems 628 <p>APPENDIX A Physical Property Data 639 <p>APPENDIX B Steam Tables 647 <p>APPENDIX C Lee Kesler Generalized Correlation Tables660 <p>APPENDIX D Unit Systems 676 <p>APPENDIX E ThermoSolver Software 680 <p>APPENDIX F References 685 <p>Index 687
Responsibility: Milo D. Koretsky, School of Chemical, Biological, and Environmental Engineering, Oregon State University.

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