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Enthalpy and internal energy : liquids, solutions and vapours

Author: Emmerich Wilhelm; T M Letcher
Publisher: London : Royal Society of Chemistry, 2017.
Edition/Format:   eBook : Document : EnglishView all editions and formats
Summary:
Containing the very latest information on all aspects of enthalpy and internal energy as related to fluids, this book brings all the information into one authoritative survey in this well-defined field of chemical thermodynamics.
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Genre/Form: Electronic books
Additional Physical Format: Print version:
Enthalpy and Internal Energy : Liquids, Solutions and Vapours.
London : Royal Society of Chemistry, ©2017
Material Type: Document, Internet resource
Document Type: Internet Resource, Computer File
All Authors / Contributors: Emmerich Wilhelm; T M Letcher
ISBN: 9781788011969 1788011961 9781788010214 1788010213
OCLC Number: 1004989997
Notes: 6.3.2 Inert Solvents versus Proton Acceptors.
Description: 1 online resource (675 pages)
Contents: Title; Copyright; Contents; Chapter 1 Internal Energy and Enthalpy: Introduction, Concepts and Selected Applications; 1.1 Introduction; 1.2 Thermodynamic Fundamentals; 1.3 More Thermodynamics and Selected Applications; 1.3.1 Properties of Real Fluids; 1.3.2 Property Changes of Mixing; 1.4 Concluding Remarks, Outlook and Acknowledgements; References; Chapter 2 Macroscopic Energy and Entropy Balances in Phase Equilibrium Studies; 2.1 Introduction; 2.2 Derivation of Macroscopic Balances; 2.3 Equations; 2.3.1 Macroscopic Energy Balance; 2.3.2 Macroscopic Mechanical Energy Balance. 2.3.3 Macroscopic Entropy Balance2.4 Application of Macroscopic Balances; 2.4.1 Differential Ebulliometry; 2.5 Macroscopic Balances in Flow Calorimetry; 2.6 Some Useful Derivative Relations; 2.6.1 Limiting Activity Coefficients; 2.6.2 Temperature and Pressure Derivatives; References; Chapter 3 Enthalpy Measurements of Condensed Matter by Peltier-element-based Adiabatic Scanning Calorimetry (pASC); 3.1 Introduction; 3.2 Operational Principle of Adiabatic Scanning Calorimetry; 3.3 Peltier-element-based Adiabatic Scanning Calorimeter (pASC); 3.4 Comparison with DSC. 3.5 The pASC as Adiabatic Heat-step Calorimeter3.6 The pASC as Heat-flux DSC-type Constant-rate Calorimeter; 3.7 The pASC as Power-compensated DSC-type Constant-rate Calorimeter; 3.8 High-resolution pASC Data near the Melting Point of Gallium; 3.8.1 pASC Constant Power Scanning Results; 3.8.2 pASC Heat-step Results; 3.8.3 pASC Heat-flux and Power-compensated DSC-type Scanning Results; 3.9 High-resolution pASC Data near Phase Transitions in Lipid Vesicles; 3.10 High-resolution pASC Data for the Melting of Water; 3.11 High-resolution pASC Data for Phase Transitions in a Liquid Crystal. 5.2 Theoretical Considerations5.3 Calorimetric Determination of the Enthalpy of Vaporization; 5.3.1 Condensation Apparatuses; 5.3.2 Vaporization Calorimetry; 5.3.3 Differential Scanning Calorimetry; 5.3.4 Fast Scanning Calorimeter (FSC); 5.4 Conclusions; References; Chapter 6 Energetic Effects in Hydrogen-bonded Liquids and Solutions; 6.1 Introduction; 6.2 Pure Associated Liquids; 6.2.1 Partitioning of the Heat Capacity of Liquids; 6.2.2 Two-state Association Model; 6.3 Nonaqueous Associated Solutions; 6.3.1 Two-state Behaviour for the Excess Heat Capacity.
Responsibility: edited by Emmerich Wilhelm and Trevor M. Letcher.

Abstract:

Containing the very latest information on all aspects of enthalpy and internal energy as related to fluids, this book brings all the information into one authoritative survey in this well-defined  Read more...

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